Fuel processing of feedstocks having components harmful to hydrodesulfurization

Patent metadata

Field	Value
Publication number	US-9745526-B2
Application number	US-201213416744-A
Country	US
Kind code	B2
Filing date	Mar 9, 2012
Priority date	Aug 3, 2006
Publication date	Aug 29, 2017
Grant date	Aug 29, 2017

Abstract

A reformer system ( 11 ) having a hydrodesulfurizer ( 12 ) provides desulfurized natural gas feedstock to a catalytic steam reformer ( 16 ), the outflow of which is treated by a water gas shift reactor ( 20 ) and optionally a preferential CO oxidizer ( 58 ) to provide reformate gas ( 28, 28 a ) having high hydrogen and moderate carbon dioxide content. To avoid damage to the hydrodesulfurizer from overheating, any deleterious hydrogen reactants, such as the oxygen in peak shave gas or olefins, in the non-desulfurized natural gas feedstock ( 35 ) are reacted ( 38 ) with hydrogen ( 28, 28 a; 71 ) to convert them to alkanes (e.g., ethylene and propylene to ethane and propane) and to convert oxygen to water in a catalytic reactor ( 38 ) having no sulfide sorbent, and cooled ( 46 ), below a temperature which would damage the reactor, by evaporative cooling with pressurized hot water ( 42 ). Hydrogen for the desulfurizer and the hydrogen reactions may be provided as recycle reformate ( 28, 28 a ) or from a mini-CPO ( 67 ), or from other sources.

First claim

The invention claimed is:

1. An apparatus, comprising:
a hydrogenator devoid of sulfide absorbent, connected to a source of hydrogen-containing gas and to a source of hydrocarbon feedstock and configured to catalytically react a substantial portion of any olefins or oxygen in the feedstock to alkanes or water, respectively, wherein the hydrogenator comprises a dual coil heat exchanger having catalyst disposed on surfaces of a primary coil and having a secondary coil with flowing water at pressure to evaporate within a predetermined temperature range; and
a hydrodesulfurizer having a catalyst/absorber bed, which may have or may not have a feedstock heater upstream of the catalyst/absorber bed, the hydrodesulfurizer inlet connected to the outlet of the hydrogenator, either through a heat exchanger or directly, to continuously receive feedstock from the source of feedstock, through the hydrogenator, whether or not the feedstock entering the hydrogenator contains olefins or oxygen.

2. The apparatus according to claim 1 , comprising:
a temperature sensor for sensing the temperature within the hydrogenator;
the source of hydrogen containing gas includes controllable valving; and
a controller responsive to the temperature sensor to cause the controllable valving to provide, within the predetermined range of temperatures, only sufficient hydrogen to convert a predetermined amount of sulfur, and to cause the controllable valving to provide, at temperatures above the predetermined temperature range, additional hydrogen in relation to the temperature.

Assignees

• Vincitore Antonio M
• Foley Peter F
• Foley Nancy P
• Hildreth Derek W
• Preston John L
• Pixton Stephen G
• Davies James A
• Doosan Fuel Cell America Inc

Inventors

• Vincitore Antonio M
• Foley Peter F
• Hildreth Derek W
• Preston John L
• Pixton Stephen G
• Davies James A

Classifications

• C10G65/04 Primary

  including only refining steps · CPC title

• C01B2203/127

  Catalytic desulfurisation · CPC title

• C01B2203/0283

  containing a CO-shift step, i.e. a water gas shift step · CPC title

• C10G2300/1025

  Natural gas · CPC title

• C01B2203/044

  Selective oxidation of carbon monoxide · CPC title