Impact modified polyoxymethylene composition and articles made therefrom that are stable when exposed to ultraviolet light

Patent metadata

Field	Value
Publication number	US-9745467-B2
Application number	US-201314135699-A
Country	US
Kind code	B2
Filing date	Dec 20, 2013
Priority date	Dec 27, 2012
Publication date	Aug 29, 2017
Grant date	Aug 29, 2017

Abstract

A polymer composition is disclosed containing a coupling agent and an impact modifier that renders the composition resistant to ultraviolet light degradation. The polymer composition contains an aliphatic coupling agent, an aliphatic impact modifier, or both an aliphatic coupling agent and an aliphatic impact modifier. The polymer composition is well suited to producing molded articles, especially articles that will later be exposed to substantial amounts of ultraviolet light. For example, molded articles made according to the present disclosure are well suited for use on the interior of vehicles where the parts are not only exposed to ultraviolet light, but are also exposed to repeated thermal cycles.

First claim

What is claimed is:

1. A polymer composition comprising a polyoxymethylene polymer and an impact modifier, the polyoxymethylene polymer being present in the polymer composition in an amount of at least about 40% by weight, the polyoxymethylene polymer containing terminal hydroxyl groups in an amount of at least 15 mmol/kg and less than about 10% by weight of constituents having a molecular weight below about 10,000 Dalton, wherein the impact modifier comprising an aliphatic impact modifier, the aliphatic impact modifier comprising an aliphatic thermoplastic polyurethane elastomer, the aliphatic thermoplastic polyurethane elastomer containing polycarbonate groups, the polymer composition further containing at least one hindered amine light stabilizer, an ultraviolet light absorber, and a coupling agent, the coupling agent comprising an aliphatic isocyanate coupling agent, the polymer composition further containing a coloring agent sufficient for a molded article made from the composition to exhibit a color, the color having an L* value of greater than 25, the polymer composition exhibiting a color difference value (DEcmc) of less than about eight after exposure to five cycles of 280 kJ/m 2 irradiation per cycle in a xenon arc weatherometer operated according to Volkswagen Test PV 1303, the aliphatic isocyanate coupling agent being present in the polymer composition in an amount such that the polymer composition has a formaldehyde emission of less than 7 mg/kg when tested according to VDA 275 and wherein the polymer composition has a Charpy notched impact strength of from about 3 kJ/m 2 to about 25 kJ/m 2 at −30° C. according to ISO Test 179/1eA.

2. A polymer composition as defined in claim 1 , wherein the color has an L* value of greater than about 30.

3. A polymer composition as defined in claim 1 , wherein the ultraviolet light absorber comprises a benzotriazole.

4. A polymer composition as defined in claim 1 , wherein the polymer composition exhibits a green color, a red color, a brown color, a gray color, a purple color, a white color, a black color or a blue color when molded.

5. A polymer composition as defined in claim 1 , wherein the impact modifier is present in the polymer composition in an amount from about 5% to about 40% by weight.

6. A polymer composition as defined in claim 1 , wherein the polymer composition has a Charpy notched impact strength of at least about 4 kJ/m 2 at −30° C.

7. A polymer composition as defined in claim 1 , wherein the polymer composition has a Charpy notched impact strength of at least about 6 kJ/m 2 at 23° C.

8. A polymer composition as defined in claim 1 , wherein the polymer composition exhibits a color difference value (DECMC) of less than about 10 after exposure to ten cycles of 280 kJ/m 2 irradiation per cycle in a xenon arc weatherometer operated according to Volkswagen Test PV 1303.

9. A polymer composition as defined in claim 1 , wherein the polyoxymethylene has a melt flow rate at 190° C. and at a load of 2.16 kg of from about 7 cm 3 /10 minutes to about 30 cm 3 /10 minutes.

10. A polymer composition as defined in claim 1 , wherein the polymer composition exhibits a gray scale value of at least about 3, after exposure to five cycles of 280 kJ/m 2 irradiation per cycle in a xenon arc weatherometer operated according to Volkswagen Test PV 1303.

11. A polymer composition as defined in claim 1 , wherein the impact modifier is present in the polymer composition in an amount from about 15% to about 25% by weight.

12. A polymer composition as defined in claim 1 , wherein the impact modifier comprises a polyester-based thermoplastic polyurethane elastomer.

13. A polymer composition as defined in claim 1 , wherein the polymer composition further comprises a sterically hindered phenolic antioxidant.

14. A polymer composition as defined in claim 1 , wherein the hindered amine light stabilizer comprises Bis(1,2,2,6,6-pentamethyl-4-piperidinyl)-[[3,5-bis(1,1-dimethylethyl)-4-hydroxyphenyl]methyl] butylmalonate.

15. A polymer composition as defined in claim 1 wherein the polyoxymethylene polymer has an initial formaldehyde content of less than about 1,000 ppm.

16. A polymer composition comprising a polyoxymethylene polymer and an impact modifier, the polyoxymethylene polymer being present in the polymer composition in an amount of at least about 40% by weight, the polyoxymethylene polymer containing terminal hydroxyl groups in an amount of at least 15 mmol/kg and less than about 10% by weight of constituent having a molecular weight below about 10,000 Dalton, wherein the impact modifier comprising an aliphatic impact modifier, the aliphatic impact modifier comprising an aliphatic thermoplastic polyurethane elastomer, the polymer composition further containing at least one hindered amine light stabilizer, an ultraviolet light absorber, and a coupling agent, the coupling agent comprising an isocyanate coupling agent, the polymer composition further containing a coloring agent sufficient for a molded article made from the composition to exhibit a color, the color having an L* value of greater than 25, the polymer composition exhibiting a color difference value (DEcmc) of less than about eight after exposure to five cycles of 280 kJ/m 2 irradiation per cycle in a xenon arc weatherometer operated according to Volkswagen Test PV 1303, wherein the ultraviolet light absorber comprises a benzotriazole, the impact modifier being present in the polymer composition in an amount from about 5% to about 45% by weight, the polymer composition has a Charpy notched impact strength of at least about 3 kJ/m 2 and less than about 25 kJ/m 2 at −30° C. according to ISO Test 179/1eA and has an impact strength of at least 10 kJ/m 2 at 23° C., and wherein the polymer composition further comprises a sterically hindered phenolic antioxidant and wherein the hindered amine light stabilizer comprises Bis(1,2,2,6,6-pentamethyl-4-piperidinyl)-[[3,5-bis(1,1-dimethylethyl)-4-hydroxyphenyl]methyl] butylmalonate, the polymer composition having a formaldehyde emission of less than 7 mg/kg when tested according to VDA 275.

17. A molded article produced from a polymer composition comprising a polyoxymethylene polymer, an impact modifier, a coupling agent, and a coloring agent sufficient for the molded article to exhibit a color, the polyoxymethylene polymer being present in the polymer composition in an amount of at least about 40% by weight, the polyoxymethylene polymer containing terminal hydroxyl groups in an amount of at least 15 mmol/kg and less than about 10% by weight of constituents having a molecular weight below about 10,000 Dalton, wherein the impact modifier comprises an aliphatic impact modifier and the coupling agent comprises an aliphatic coupling agent, the polymer composition exhibiting a color difference value (DEcmc) of less than about eight after exposure to five cycles of 280 kJ/m 2 irradiation per cycle in a xenon arc weatherometer operated according to Volkswagen Test PV 1303, the coupling agent comprising an isocyanate, the coupling agent couples the impact modifier to the polyoxymethylene polymer, the coupling agent comprising isophorone diisocyanate trimer, the coupling agent being present in the composition in an amount of 0.3% by weight or less, the polymer composition having a formaldehyde emission of less than 7 mg/kg when tested according to VDA 275 and a Charpy notched impact strength of from about 3 kJ/m 2 to about 25 kJ/m 2 at −30° C. according to ISO Test 179/1eA.

18. An article as defined in claim 17 , wherein the article has been formed thr

Assignees

• Ticona Llc
• Ticona Llc

Inventors

• Mulholland Bruce
• Ziegler Ursula

Classifications

• C08L75/06

  from polyesters · CPC title

• C08L59/04

  Copolyoxymethylenes · CPC title

• C08L59/02

  Polyacetals containing polyoxymethylene sequences only · CPC title

• C08L75/04

  Polyurethanes · CPC title

• C08K3/013

  Fillers, pigments or reinforcing additives · CPC title