Surface modified carbon black to simultaneously improve rolling resistance, wet traction, and wear resistance
US-12116485-B2 · Oct 15, 2024 · US
US9745454B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9745454-B2 |
| Application number | US-201514837588-A |
| Country | US |
| Kind code | B2 |
| Filing date | Aug 27, 2015 |
| Priority date | Sep 25, 2014 |
| Publication date | Aug 29, 2017 |
| Grant date | Aug 29, 2017 |
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Tire having improved wet grip performance and improved resistance to breaking or chipping along with good fuel economy. The tire includes a tire component (preferably, a tire tread) formed of a vulcanized rubber composition. The vulcanized rubber composition is obtained by vulcanizing a specific unvulcanized rubber composition. The unvulcanized rubber composition comprises (a) a rubber component composed of natural rubber, polybutadiene rubber, and two different types of styrene-butadiene rubber, (b) a filler that includes silica, and (c) a silane coupling agent that incorporates a —C(═O)—S— moiety.
Opening claim text (preview).
The invention claimed is: 1. A tire, comprising a tire component formed of a vulcanized rubber composition, the vulcanized rubber composition being obtained by vulcanizing an unvulcanized rubber composition, the unvulcanized rubber composition comprising a rubber component, at least one filler including silica, and a silane coupling agent, wherein the rubber component comprises natural rubber, a first styrene-butadiene rubber that has a styrene content of 35% by mass or more, a second styrene-butadiene rubber that has a styrene content of 30% by mass or less, and polybutadiene rubber, an amount of the natural rubber based on 100% by mass of the rubber component being 5 to 30% by mass, an amount of the first styrene-butadiene rubber based on 100% by mass of the rubber component being 20 to 60% by mass, an amount of the second styrene-butadiene rubber based on 100% by mass of the rubber component being 10 to 30% by mass, an amount of the polybutadiene rubber based on 100% by mass of the rubber component being 5 to 30% by mass, and a combined amount of the first styrene-butadiene rubber and the second styrene-butadiene rubber based on 100% by mass of the rubber component being 30 to 80% by mass, an amount of the filler per 100 parts by mass of the rubber component is 60 parts by mass or more, and the silane coupling agent is a compound of Formula (1) wherein p is an integer of 1 to 3, q is an integer of 1 to 5, and k is an integer of 5 to 12, and wherein an amount of the silane coupling agent per 100 parts by mass of the silica is 0.5 to 20 parts by mass. 2. The tire according to claim 1 , wherein the filler includes at least 55 parts by mass of silica per 100 parts by mass of the rubber component. 3. The tire according to claim 1 , wherein the polybutadiene rubber is a modified polybutadiene rubber containing a functional group that interacts with silica, the functional group being at least one member selected from the group consisting of an amino group, an amido group, an alkoxysilyl group, an isocyanate group, an imino group, an imidazole group, an urea group, an ether group, a carbonyl group, an oxycarbonyl group, a sulfide group, a disulfide group, a sulfonyl group, a sulfinyl group, a thiocarbonyl group, an ammonium group, an imido group, a hydrazo group, an azo group, a diazo group, a carboxy group, a nitrile group, a pyridyl group, an alkoxy group, a hydrocarbon group, a hydroxy group, an oxy group, and an epoxy group. 4. The tire according to claim 1 , wherein the vulcanized rubber composition has vulcanized rubber properties comprising: a tan δ at 0° C. of 0.50 or greater and a tan δ at 70° C. of 0.10 or smaller, as determined by viscoelastic measurement at an initial strain of 10% and a dynamic strain of 2%; and a ratio (EB/TB) of elongation at break (EB) to tensile strength at break (TB) at 30° C. of 15 or greater, as determined in accordance with JIS K 6251. 5. The tire according to claim 1 , wherein the vulcanized rubber composition has vulcanized rubber properties comprising a ratio (EB/TB) of elongation at break (EB) to tensile strength at break (TB) at 80° C. of 30 or greater, as determined in accordance with JIS K 6251. 6. The tire according to claim 1 , wherein the tire component is a tread.
containing sulfur {(C08K5/5477 takes precedence)} · CPC title
Silica · CPC title
containing two or more polymers of the same C08L -group · CPC title
Cross-Sectional Technologies · mapped topic
Copolymers with styrene · CPC title
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