BOPP film having low shrinkage

Patent metadata

Field	Value
Publication number	US-9745431-B2
Application number	US-201415103744-A
Country	US
Kind code	B2
Filing date	Dec 18, 2014
Priority date	Dec 18, 2013
Publication date	Aug 29, 2017
Grant date	Aug 29, 2017

Abstract

The present invention relates to a new biaxially oriented polypropylene (BOPP) film, a process for the preparation of such film as well as the use of a polypropylene for the preparation of such film and an article comprising such film.

First claim

The invention claimed is:

1. A biaxially oriented polypropylene (BOPP) film comprising a propylene homopolymer (H-PP) having a ratio of weight average molecular weight (M w ) to number average molecular weight (M n ) [M w /M n ] of from 10.0 to 15.0 and a melting temperature (T m ) measured by differential scanning calorimetry (DSC) of from 164 to 169° C., wherein the biaxially oriented polypropylene (BOPP) film has a thermal shrinkage measured after 5 min at 120° C. in transverse direction (TD) of ≦0.3%.

2. The biaxially oriented polypropylene (BOPP) film according to claim 1 , wherein propylene homopolymer (H-PP) has a crystallization temperature (T c ) measured by differential scanning calorimetry (DSC) of at least 115° C.

3. The biaxially oriented polypropylene (BOPP) film according to claim 1 , wherein the propylene homopolymer (H-PP) has a melting temperature (T m ) measured by differential scanning calorimetry (DSC) of from 164 to 168° C.

4. The biaxially oriented polypropylene (BOPP) film according to claim 1 , wherein the propylene homopolymer (H-PP) has a melt flow rate MFR 2 (230° C.) measured according to ISO 1133 of ≦7.0 g/10 min.

5. The biaxially oriented polypropylene (BOPP) film according to claim 1 , wherein the propylene homopolymer (H-PP) has a xylene cold soluble fraction (XCS) determined at 25° C. according ISO 16152 of ≦4.0 wt.-%.

6. The biaxially oriented polypropylene (BOPP) film according to claim 1 , wherein the propylene homopolymer (H-PP) has
a) an mmmm pentad concentration of ≧94.0%, as determined by NMR-spectroscopy, and/or
b) 2,1 erythro regio-defects of below 1.0%, as determined by 13 C-NMR spectroscopy.

7. The biaxially oriented polypropylene (BOPP) film according to claim 1 , wherein the propylene homopolymer (H-PP) has a polydispersity index of ≧5.0.

8. The biaxially oriented polypropylene (BOPP) film according to claim 1 , wherein the biaxially oriented polypropylene (BOPP) film comprises a propylene homopolymer (H-PP) having a ratio of weight average molecular weight (M w ) to number average molecular weight (M n ) [M w /M n ] of from 10.0 to 14.0.

9. The biaxially oriented polypropylene (BOPP) film according to claim 1 , wherein the biaxially oriented polypropylene (BOPP) film has a thermal shrinkage measured after 5 min at 120° C.
(a) in transverse direction (TD) of ≦0.2%
and/or
(b) in machine direction (MD) of from 3.0 to 6.0%.

10. The biaxially oriented polypropylene (BOPP) film according to claim 1 , wherein the biaxially oriented polypropylene (BOPP) film has a tensile modulus in machine direction (MD) of at least 2 300 N/mm 2 and/or a tensile modulus in transverse direction (TD) of at least 4 500 N/mm 2 .

11. The biaxially oriented polypropylene (BOPP) film according to claim 2 , wherein the propylene homopolymer (H-PP) has a melting temperature (T m ) measured by differential scanning calorimetry (DSC) of from 164 to 168° C.

12. The biaxially oriented polypropylene (BOPP) film according to claim 2 , wherein the propylene homopolymer (H-PP) has a melt flow rate MFR 2 (230° C.) measured according to ISO 1133 of ≦7.0 g/10 min.

13. The biaxially oriented polypropylene (BOPP) film according to claim 2 , wherein the propylene homopolymer (H-PP) has a xylene cold soluble fraction (XCS) determined at 25° C. according ISO 16152 of ≦4.0 wt.-%.

14. A process for the preparation of a biaxially oriented polypropylene (BOPP) film according to claim 1 , the process comprising at least the steps of
a) providing a propylene homopolymer (H-PP)) having a ratio of weight average molecular weight (M w ) to number average molecular weight (M n ) [M w /M n ] of from 10.0 to 15.0 and a melting temperature (T m ) measured by differential scanning calorimetry (DSC) of from 164 to 169° C., and
b) stretching the polypropylene of step a) in machine direction (MD) and transverse direction (TD), wherein the stretching in machine direction (MD) and transverse direction (TD) is carried out in consecutive steps.

15. The process according to claim 14 , wherein the propylene homopolymer (H-PP) has
a) a drawing temperature (T draw′ ) when drawn in transverse direction in the range of the inequation (II),
Tm− 25 ≦T draw′≦ Tm+ 10  (II),

wherein
T draw′ is the drawing temperature (T draw′ ) in ° C. of the first segment of the drawing zone (DZT) in the oven where the propylene homopolymer (H-PP) is drawn in transverse direction, wherein further this first segment of the drawing zone (DZT) is defined as the zone where the draw ratio of the drawn propylene homopolymer (H-PP) is at least 1.1; and
Tm is the melting temperature (T m ) of the propylene homopolymer (H-PP) in ° C.;
and optionally
b) a drawing temperature (T draw″ ) when drawn in transverse direction in the range of the inequation (III),
Tm≦T draw″≦ Tm+ 18  (III),

wherein
T draw″ is the drawing temperature (T draw″ ) in ° C. of the heating zone (HZT) in the oven where the propylene homopolymer (H-PP) is drawn in transverse direction, wherein further the heating zone (HZT) is the zone upstream to the drawing zone (DZT); and
Tm is the melting temperature (T m ) of the propylene homopolymer (H-PP) in ° C.

16. The process according to claim 14 , wherein the propylene homopolymer (H-PP) has drawing temperature (T draw ) when stretched in machine direction in the range of the inequation (I)
Tm− 50≦ T draw≦ Tm− 15  (I),

wherein
T draw is the drawing temperature (T draw ) in ° C., wherein the drawing temperature (T draw ) is defined as the temperature (in ° C.) of the first roll (R1) of two successive rolls (R1, R2) of all rolls in the oven consecutively arranged in machine direction where the propylene homopolymer (H-PP) is drawn in machine direction, wherein further said two successive rolls (R1, R2) when locking in machine direction have as the first pair of successive rolls for the first time a roll speed difference of at least 20 m/min; and
Tm is the melting temperature (T m ) of the propylene homopolymer (H-PP) in ° C.

17. The process according to claim 14 , wherein step b) is carried out in that the propylene homopolymer (H-PP) of step a) is stretched
a) in machine direction (MD) with a draw ratio of ≧3.0, and/or
b) in transverse direction (TD) with a draw ratio of ≧6.0.

18. An article comprising a biaxially oriented polypropylene (BOPP) film as defined in claim 1 .

Assignees

• Borealis Ag

Inventors

• Potter Gregory
• Gloger Dietrich
• Horill Thomas

Classifications

• C08F110/06

  Propene · CPC title

• C08J2323/12

  Polypropene · CPC title

• B29C55/14

  successively · CPC title

• C08F2500/03

  Narrow molecular weight distribution, i.e. Mw/Mn < 3 · CPC title

• C08F2500/12

  Melt flow index or melt flow ratio · CPC title