Translucent glazing comprising at least one pattern that is preferably transparent

Patent metadata

Field	Value
Publication number	US-9745221-B2
Application number	US-201314414308-A
Country	US
Kind code	B2
Filing date	Jul 11, 2013
Priority date	Jul 13, 2012
Publication date	Aug 29, 2017
Grant date	Aug 29, 2017

Abstract

A glazing, which may be translucent, includes at least one design, which may be transparent. The glazing includes a substrate having two main outer surfaces, at least one of which is a textured surface, made of a dielectric material having a refractive index n1 and at least a part of the textured surface of the substrate is coated with a sol-gel layer made of a dielectric material having a refractive index n2.

First claim

The invention claimed is:

1. A glazing comprising a substrate having two main outer surfaces, at least one of which is a textured surface, consisting of a dielectric material having a refractive index n 1 , wherein:
at least a part of the textured surface of the substrate is coated with a sol-gel layer consisting of a dielectric material having a refractive index n 2 , and
the absolute value of the difference in refractive index at 589 nm between constituent dielectric materials of the substrate and the sol-gel layer is less than or equal to 0.020, and
wherein the part of the textured surface of the substrate comprising the sol-gel layer has a transmission haze of less than 5% and a lightness of greater than 93%.

2. The glazing as claimed in claim 1 , wherein the substrate has two main outer surfaces, at least one of which is a textured surface and the other is a smooth surface.

3. The glazing as claimed in claim 1 , wherein the textured surface of the substrate has a roughness parameter Ra of at least 0.5 μm.

4. The glazing as claimed in claim 1 , wherein the part of the textured surface of the substrate comprising a sol-gel layer defines a transparent design.

5. The glazing as claimed in claim 1 , wherein the thickness of the sol-gel layer is greater than or equal to the peak-to-valley height of the textured surface of the substrate.

6. The glazing as claimed in claim 1 , wherein the textured surface of the substrate coated with a sol-gel layer has a roughness parameter Ra of less than 0.1 μm.

7. The glazing as claimed in claim 1 , wherein the sol-gel layer comprises a silica-based organic/inorganic hybrid matrix.

8. The glazing as claimed in claim 6 , wherein the sol-gel layer also comprises particles of at least one metal oxide or of at least one chalcogenide.

9. The glazing as claimed in claim 7 , wherein the silica-based organic/inorganic hybrid matrix also comprises at least one metal oxide.

10. The glazing as claimed in claim 8 , wherein the metal oxide comprises a metal chosen from titanium, zirconium, zinc, niobium, aluminum and molybdenum.

11. The glazing as claimed in claim 1 , wherein the sol-gel layer comprises an organic/inorganic hybrid matrix of silica and of zirconium oxide in which are dispersed titanium dioxide particles.

12. The glazing as claimed in claim 1 , wherein the part of the textured surface of the substrate not comprising a sol-gel layer has a transmission haze of greater than 15% and/or a lightness of less than 90%.

13. The glazing as claimed in claim 1 , wherein the substrate is a glass or vitroceramic substrate.

14. A process for manufacturing a glazing as claimed in claim 1 , comprising:
providing a substrate comprising a textured surface of refractive index n 1 ,
depositing on at least a part of the textured surface of the substrate a sol-gel layer consisting of a dielectric material having a refractive index n 2 , for which the absolute value of the difference in refractive index at 589 nm between constituent dielectric materials of the substrate and of the sol-gel layer is less than or equal to 0.020.

15. The process as claimed in claim 14 , wherein the absolute value of the difference in refractive index at 589 nm is less than or equal to 0.015.

16. The glazing as claimed in claim 1 , wherein the substrate is a polymer substrate.

17. The glazing as claimed in claim 1 , wherein the sol-gel layer is based on hydrolysis and condensation of at least one organosilane of general formula R n SiX (4-n) in which:
n is equal to 1, 2, 3,
groups X, which are identical or different, represent hydrolyzable groups selected from the group consisting of alkoxy, acyloxy and halide groups, and
groups R, which are identical or different, represent non-hydrolyzable organic groups bonded to silicon via a carbon atom.

Assignees

• Saint Gobain

Inventors

• Ehrensperger Marie-Virginie
• Guillemot François

Classifications

• C23C18/1229

  Composition of the substrate · CPC title

• C03C2217/44

  characterized by the composition of the continuous phase · CPC title

• C23C18/122

  Inorganic polymers, e.g. silanes, polysilazanes, polysiloxanes · CPC title

• C03C17/009 Primary

  Mixtures of organic and inorganic materials, e.g. ormosils and ormocers · CPC title

• C23C18/1216

  Metal oxides (C23C18/1212 takes precedence) · CPC title