Silver powder and method for producing same

Patent metadata

Field	Value
Publication number	US-9744593-B2
Application number	US-201314382375-A
Country	US
Kind code	B2
Filing date	Feb 27, 2013
Priority date	Mar 7, 2012
Publication date	Aug 29, 2017
Grant date	Aug 29, 2017

Abstract

A method for producing silver powder wherein a silver solution containing a silver complex and a reductant solution are continuously mixed to provide a reaction liquid, the method including: a step of preparing a silver nucleus solution wherein a silver solution for nucleation which contains a silver complex, a solution containing a strong reductant, and a dispersant are mixed to provide the silver nucleus solution; a step of preparing a reductant solution containing nuclei wherein the silver nucleus solution obtained and a weak reductant having a standard electrode potential higher than that of the strong reductant are mixed to obtain the reductant solution containing nuclei; and a step of growing particles wherein the reductant solution containing nuclei and a silver solution for particle growth containing a silver complex are continuously mixed to provide a reaction solution, in which the silver complex is reduced to thereby grow silver particles.

First claim

The invention claimed is:

1. A method for producing silver powder wherein a silver solution containing a silver complex and a reductant solution are continuously mixed to provide a reaction liquid, in which the silver complex is reduced to obtain a silver particle slurry, and then, silver powder is produced via steps of filtration, washing, and drying, the method comprising:
a step of preparing a silver nucleus solution wherein a silver solution for nucleation containing a silver complex, a solution containing a strong reductant, and a dispersant are mixed to obtain the silver nucleus solution;
a step of preparing a reductant solution containing nuclei wherein the silver nucleus solution obtained and a weak reductant having a standard electrode potential higher than that of the strong reductant are mixed to obtain the reductant solution containing nuclei; and
a step of growing particles wherein the reductant solution containing nuclei and a silver solution for particle growth containing a silver complex are continuously mixed to provide a reaction solution, in which the silver complex is reduced to thereby grow silver particles.

2. The method for producing silver powder according to claim 1 , wherein the equivalent of the strong reductant is 2.0 or more and less than 4.0 with respect to the amount of silver in the silver solution for nucleation.

3. The method for producing silver powder according to claim 1 , wherein the standard electrode potential of the strong reductant is 0.056 V or less.

4. The method for producing silver powder according to claim 1 , wherein the difference of the standard electrode potentials between the strong reductant and the weak reductant is 1.0 V or more.

5. The method for producing silver powder according to claim 1 , wherein the strong reductant is hydrazine monohydrate and the weak reductant is ascorbic acid.

6. The method for producing silver powder according to claim 1 , wherein the silver concentration of the silver solution for nucleation is 0.1 to 6.0 g/L.

7. The method for producing silver powder according to claim 6 , wherein the silver concentration of the silver solution for nucleation is 0.1 to 1.0 g/L, and the silver concentration of the silver solution for particle growth is 20 to 90 g/L.

8. The method for producing silver powder according to claim 1 , wherein the silver complex is a silver ammine complex obtained by dissolving silver chloride in ammonia water.

9. The method for producing silver powder according to claim 8 , wherein the molar ratio of the amount of ammonia with respect to the amount of silver in the silver solution for nucleation is 20 to 100.

10. The method for producing silver powder according to claim 1 , wherein the amount of the dispersant to be mixed is 1 to 30% by mass with respect to the amount of silver in the silver solution for particle growth after mixing of the reductant solution containing nuclei and the silver solution for particle growth.

11. The method for producing silver powder according to claim 1 , wherein the dispersant is at least one selected from the group consisting of polyvinyl alcohol, polyvinyl pyrrolidone, modified silicone oil surfactants, and polyether surfactants.

12. The method for producing silver powder according to claim 1 , wherein, in mixing of the reductant solution containing nuclei and the silver solution for particle growth, each solution is separately supplied into a reaction tube and mixed by using a static mixer arranged in the tube.

Assignees

• Sumitomo Metal Mining Co

Inventors

• Nishimoto Masamu
• Okabe Yoshihiro
• Kanada Satoshi

Classifications

• B22F1/05

  Metallic powder characterised by the size or surface area of the particles · CPC title

• B22F1/00

  Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties · CPC title

• Y10T428/12014

  having metal particles · CPC title

• B22F9/24 Primary

  starting from liquid metal compounds, e.g. solutions · CPC title

• B22F1/0003

  Operations & Transport · mapped topic