Regeneration of clay catalysts for alkylation of aromatic rings

Patent metadata

Field	Value
Publication number	US-9744531-B2
Application number	US-201614995250-A
Country	US
Kind code	B2
Filing date	Jan 14, 2016
Priority date	Mar 3, 2015
Publication date	Aug 29, 2017
Grant date	Aug 29, 2017

Abstract

Catalysts, in particular clay catalysts, use in alkylation reaction of aromatic compounds, e.g., aromatic amines, that have lost activity during use, are regenerated by contacting the used catalyst with a mixture of a minor amount of an acid, in a mixture with water and an organic solvent. The regeneration process is readily incorporated into an alkylation process for aromatic amines.

First claim

What is claimed:

1. A process for treating a clay catalyst that has lost at least a portion of its catalytic activity due to use in an alkylation reaction of an aromatic compound, said process comprising providing a clay catalyst that has lost at least a portion of its catalytic activity due to use in an alkylation reaction of an aromatic compound, contacting said clay catalyst with a regeneration mixture comprising from 0.1 to 20 wt % of an acid, 1 to 45 wt % of water, and 35 to 98.9 wt % of an organic solvent, in an amount that is at least sufficient to fully wet the catalyst, at a temperature of from 25 to 200° C., for from 0.5 to 36 hours, during which time the clay catalyst has regained at least a portion of its lost activity resulting in a regenerated clay catalyst, and then separating the regenerated clay catalyst from the regeneration mixture.

2. The process according to claim 1 , wherein the regeneration mixture comprises from 0.5 to 10 wt % of the acid, 1 to 20 wt % of the water, and 70 to 98.5 wt % of the organic solvent.

3. The process according to claim 1 , wherein the acid comprises an inorganic acid.

4. The process according to claim 1 , wherein the acid comprises an organic acid.

5. The process according to claim 1 , wherein the organic solvent comprises an alcohol, ketone, ether or hydrocarbon.

6. The process according to claim 1 , wherein the organic solvent comprises methanol, ethanol, propanol, isopropanol, butanol, isobutanol, sec-butanol, tert-butanol, amyl alcohol, iso amyl alcohol, sec-amyl alcohol, tert-amyl alcohol, acetone, ethyl methyl ketone, toluene, xylene or mesitylene.

7. The process according to claim 2 , wherein the organic solvent comprises an alcohol, ketone, ether or hydrocarbon.

8. The process according to claim 1 , wherein the clay catalyst that has lost at least a portion of its catalytic activity due to use in an alkylation reaction of an aromatic compound is an acidic clay catalyst that has lost at least a portion of its catalytic activity due to use in a reaction for alkylating an aromatic amine.

9. The process according to claim 8 , wherein the acidic clay catalyst is a bentonite clay.

10. The process according to claim 8 , further comprising reintroducing the regenerated clay catalyst to a reaction for alkylating an aromatic amine.

11. The process according to claim 10 comprising:
A) passing a mixture comprising one or more olefins and an aromatic amine through an acidic clay catalyst in a fixed bed reactor to yield an alkylation product;
B) discontinuing passage of the one or more olefins and aromatic amine through the acidic clay catalyst;
C) contacting the acid clay catalyst with a regeneration mixture comprising from 0.1 to 20 wt % of an acid, 1 to 45 wt % of water, and 35 to 98.9 wt % of an organic solvent, in an amount that is at least sufficient to fully wet the catalyst, at a temperature of from 25 to 200° C., for from 0.5 to 36 hours, during which time the clay catalyst has regained at least a portion of its lost activity resulting in a regenerated clay catalyst, and then separating the regenerated clay catalyst from the regeneration mixture, and
D) resuming passage of the one or more olefins and aromatic amine through the regenerated clay catalyst.

12. The process according to claim 11 wherein B) further comprises, after discontinuing passage of the one or more olefins and aromatic amine through the acidic clay catalyst, flushing the acidic clay catalyst with organic or aqueous solvent, mixtures of solvents, and/or air or an inert gas.

13. The process according to claim 11 wherein C) further comprises flushing the regenerated acidic clay catalyst with organic or aqueous solvent, mixtures of solvents, and/or air or an inert gas, drying the regenerated clay catalyst using heat and/or reduced pressure.

14. The process according to claim 12 wherein C) further comprises flushing the regenerated acidic clay catalyst with organic or aqueous solvent, mixtures of solvents, and/or air or an inert gas, drying the regenerated clay catalyst using heat and/or reduced pressure.

15. The process according to claim 11 wherein the process is carried out without removing the clay catalyst from the reactor.

16. The process according to claim 11 wherein the aromatic amine is diphenylamine, dinaphthylamine or N-phenyl-N-naphthyl amine.

17. The process according to claim 11 wherein the one or more olefins comprise isobutylene, di-isobutylene, tri-isobutylene, di-propylene, tri-propylene or tetra-propylene.

Assignees

• Chemtura Corp
• Lanxess Solutions Us Inc

Inventors

• True Alan B

Classifications

• B01J38/52

  oxygen-containing · CPC title

• Y02P20/584

  Recycling of catalysts · CPC title

• B01J21/16 Primary

  Clays or other mineral silicates · CPC title

• B01J21/20

  Regeneration or reactivation · CPC title

• B01J38/62

  organic · CPC title