Safely ingestible batteries

Patent metadata

Field	Value
Publication number	US-9741975-B2
Application number	US-201414774984-A
Country	US
Kind code	B2
Filing date	Mar 5, 2014
Priority date	Mar 13, 2013
Publication date	Aug 22, 2017
Grant date	Aug 22, 2017

Abstract

A battery for use in electronic devices and which is safely ingested into a body and a related method of making the battery. The battery includes an anode, a cathode and a quantum tunneling composite coating. The quantum tunneling composite coating covers at least a portion of at least one of the anode or the cathode and provides pressure sensitive conductive properties to the battery including a compressive stress threshold for conduction. The compressive stress threshold may be greater than a pre-determined applied stress in a digestive tract of the body in order to prevent harm if the battery is ingested. The battery may include a waterproof seal that extends between the quantum tunneling composite coating and a gasket separating the anode and cathode to inhibit the battery from short circuiting in a conductive fluid below the compressive stress threshold.

First claim

We claim:

1. A battery for use in electronic devices and which is safely ingested into a body that exerts a pre-determined applied stress in a digestive tract of the body, the battery comprising:
an anode;
a cathode;
a pressure-sensitive coating that comprises a quantum tunneling composite covering at least one of the anode and the cathode and providing pressure sensitive conductive properties including a compressive stress threshold such that, when a stress above the compressive stress threshold is applied to the quantum tunneling composite coating, the quantum tunneling composite coating is placed in a conductive state in which electrons are able to tunnel through the quantum tunneling composite coating; and
wherein the compressive stress threshold is greater than the pre-determined applied stress associated with the digestive tract of the body.

2. The battery of claim 1 , wherein, when no stress or a stress below the compressive stress threshold is applied to the quantum tunneling composite coating, the quantum tunneling composite coating is in an insulating state in which electrons are unable to quantum tunnel through the quantum tunneling composite coating.

3. The battery of claim 1 , wherein the quantum tunneling composite coating comprises a polymer matrix with conductive microparticles suspended therein that collectively provide the pressure sensitive conductive properties for the quantum tunneling composite coating.

4. The battery of claim 3 , wherein the polymer matrix comprises a silicone rubber and the conductive microparticles comprise silver.

5. The battery of claim 3 , wherein the conductive microparticles include a surface with a nanoscale roughness that enhances an electric field gradient such that, when the conductive microparticles are less than 1-5 nm apart, electrons are able to tunnel through the polymer matrix, thereby conducting current therethrough.

6. The battery of claim 1 , wherein the quantum tunneling composite coating is disc-shaped and constructed from a quantum tunneling composite sheet.

7. The battery of claim 1 , further comprising a gasket that insulates and separates the anode and the cathode.

8. The battery of claim 7 , further comprising a waterproof seal extending between the pressure-sensitive coating and the gasket, thereby inhibiting the battery from short circuiting in a conductive fluid below the compressive stress threshold.

9. The battery of claim 8 , wherein the waterproof seal is impermeable to water and comprises a poly-dimethyl siloxane material and a cross-linking agent.

10. The battery of claim 7 , wherein the pressure-sensitive coating is a water-impermeable coating extending to the gasket and fully covering the at least one of the anode and the cathode to leave no exposed surfaces.

11. The battery of claim 1 , wherein the battery is safely ingestible into the body because the pre-determined applied stress associated with the digestive tract of the body is below the compressive stress threshold of the pressure-sensitive coating, thereby inhibiting damage to intestinal tissue and inhibiting release of harmful contents of the battery into the body.

12. The battery of claim 1 , wherein the compressive stress threshold in order for the pressure-sensitive coating to conduct is at least twice the pre-determined applied stress associated with the digestive tract of the body.

13. The battery of claim 1 , further comprising a conductive adhesive positioned between the pressure-sensitive coating and the at least one of the anode and the cathode on which the pressure-sensitive coating is received, in which the conductive adhesive comprises a conductive silver material.

14. The battery of claim 1 , wherein the pressure-sensitive coating also provides a continuous and waterproof layer over at least one of the anode and the cathode.

15. The battery of claim 1 , wherein the compressive stress threshold has a value between 15.5 N/cm 2 and 19.4 N/cm 2 .

16. The battery of claim 1 , wherein the pressure-sensitive coating is a pressure-gated coating.

17. The battery of claim 1 , wherein the battery is a button battery.

18. A battery for use in electronic devices and which is safely ingested into a body that exerts a pre-determined applied stress in a digestive tract of the body, the battery comprising:
an anode;
a cathode;
a pressure-sensitive coating that comprises a quantum-tunneling composite coating covering at least one of the anode and the cathode and providing pressure sensitive conductive properties including a compressive stress threshold, the compressive stress threshold being greater than the pre-determined applied stress associated with the digestive tract of the body; and
a gasket separating a part of the anode and the cathode;
wherein the pressure-sensitive coating provides at least a portion of a water-impermeable coating extending to the gasket and fully covering the at least one of the anode and the cathode to leave no exposed surfaces thereby inhibiting the battery from short circuiting in a conductive fluid.

19. The battery of claim 18 , further comprising a waterproof seal further extending between the pressure-sensitive coating and the gasket.

20. The battery of claim 18 , wherein the compressive stress threshold is at least twice the pre-determined applied stress associated with the digestive tract of the body.

21. The battery of claim 18 , wherein, when a stress above the compressive stress threshold is applied to the quantum tunneling composite coating, the quantum tunneling composite coating is in a conductive state in which electrons are able to quantum tunnel through the quantum tunneling composite coating and, wherein, when no stress or a stress below the compressive stress threshold is applied to the quantum tunneling composite coating, the quantum tunneling composite coating is in an insulating state in which electrons are unable to quantum tunnel through the quantum tunneling composite coating.

22. The battery of claim 21 , wherein the quantum tunneling composite coating comprises a polymer matrix with conductive microparticles suspended therein that collectively provide the pressure sensitive conductive properties for the quantum tunneling composite coating.

23. The battery of claim 22 , wherein the polymer matrix comprises a silicone rubber and the conductive microparticles comprise silver.

24. The battery of claim 22 , wherein the conductive microparticles include a surface with a nanoscale roughness that enhances an electric field gradient such that, when the conductive microparticles are less than 1-5 nm apart, electrons are able to tunnel through the polymer matrix thereby conducting current therethrough.

25. The battery of claim 22 , wherein the polymer matrix of the quantum tunneling composite coating provides a continuous and waterproof layer.

26. The battery of claim 18 , wherein the waterproof seal is impermeable to water and comprises a poly-dimethyl siloxane material and a cross-linking agent.

27. The battery of claim 18 , wherein the battery is safely ingestible into the body because the pre-determined applied stress associated with the digestive tract of the body is below the compressive stress threshold of the pressure-sensitive coating, thereby inhibiting damage to intestinal tissue and inhibiting release of harmful contents of the battery into the body.

28. The battery of clai

Assignees

• Brigham And Women'S Hospital Inc
• Massachusetts Inst Technology

Inventors

• Laulicht Bryan
• Freilich Janet
• Karp Jeffrey M
• Langer Robert

Classifications

• H01M2220/00

  Batteries for particular applications · CPC title

• H01M2200/00

  Safety devices for primary or secondary batteries · CPC title

• H01M2220/30

  Batteries in portable systems, e.g. mobile phone, laptop · CPC title

• H01M10/4235

  Safety or regulating additives or arrangements in electrodes, separators or electrolyte (H01M10/4242 takes precedence) · CPC title

• H01M50/593

  Spacers; Insulating plates · CPC title