System, methods, and apparatus for production coatings of low-emissivity glass

Patent metadata

Field	Value
Publication number	US-9739915-B2
Application number	US-201314144915-A
Country	US
Kind code	B2
Filing date	Dec 31, 2013
Priority date	Mar 13, 2013
Publication date	Aug 22, 2017
Grant date	Aug 22, 2017

Abstract

Disclosed herein are systems, methods, and apparatus for forming low emissivity panels. In some embodiments, a partially fabricated panel may be provided that includes a substrate, a reflective layer formed over the substrate, and a barrier layer formed over the reflective layer such that the reflective layer is formed between the substrate and the barrier layer. The barrier layer may include a partially oxidized alloy of three or more metals. A first interface layer may be formed over the barrier layer. A top dielectric layer may be formed over the first interface layer. The top dielectric layer may be formed using reactive sputtering in an oxygen containing environment. The first interface layer may prevent further oxidation of the partially oxidized alloy of the three or more metals when forming the top dielectric layer. A second interface layer may be formed over the top dielectric layer.

First claim

What is claimed is:

1. A method of forming a low emissivity panel, the method comprising:
providing a partially fabricated panel,
the partially fabricated panel comprising a substrate, a reflective layer formed over the substrate, and a barrier layer formed over the reflective layer such that the reflective layer is formed between the substrate and the barrier layer;

forming a first interface layer over the barrier layer;
forming a top dielectric layer over the first interface layer; and
forming a second interface layer over the top dielectric layer,
the first interface layer and the second interface layer directly interfacing the top dielectric layer and having same composition,
each of the first interface layer and the second interface layer comprising at least one of one of zinc oxide, titanium oxide, or tantalum oxide,
the barrier layer comprising a partially oxidized alloy of three or more metals,
the top dielectric layer being formed using reactive sputtering in an oxygen containing environment, and
the first interface layer substantially preventing further oxidation of the partially oxidized alloy of the three or more metals when forming the top dielectric layer.

2. The method of claim 1 , wherein the barrier layer comprises nickel, titanium, and niobium.

3. The method of claim 1 , wherein the barrier layer has a thickness of between about 5 Angstroms and 30 Angstroms.

4. The method of claim 1 , wherein a concentration of oxygen in the barrier layer is less than 30 atomic % after forming the top dielectric layer.

5. The method of claim 1 , wherein a concentration of oxygen in the barrier layer varies throughout a thickness of the barrier layer such that substantially no oxygen is present at a surface of the barrier layer interfacing with the reflective layer.

6. The method of claim 1 , wherein a concentration of titanium in the barrier layer is between about 5 atomic % and 20 atomic %, wherein a concentration of nickel in the barrier layer is between about 20 atomic % and 50 atomic %, and wherein a concentration of niobium is between about 20 atomic % and 50 atomic %.

7. The method of claim 1 , wherein the first interface layer directly interfaces the barrier layer.

8. The method of claim 1 , wherein the top dielectric layer comprises one of tin oxide, zinc tin oxide, aluminum tin oxide, magnesium tin oxide, bismuth tin oxide, or niobium tin oxide.

9. The method of claim 1 , wherein a material included in the first interface layer and a material included in the second interface layer are at least about 25% amorphous.

10. The method of claim 1 , wherein the first interface layer and the second dielectric layer comprise tantalum oxide.

11. The method of claim 1 , wherein the first interface layer has a thickness of between about 2 nanometers and 8 nanometers.

12. The method of claim 1 , further comprising:
forming a top diffusion layer over the second interface layer using nitrogen plasma,
wherein the second interface layer is disposed between the top diffusion layer and the top dielectric layer,
wherein the second interface layer prevents nitrogen migration into the top dielectric layer while forming the top diffusion layer, and
wherein the top diffusion layer comprises silicon nitride.

13. The method of claim 12 , further comprising, after forming the top diffusion layer, heat treating the partially fabricated panel comprising the first interface layer, the second interface layer, and the top diffusion layer.

14. The method of claim 1 , wherein the second interface layer has a thickness of between about 2 nanometers and 8 nanometers.

15. The method of claim 1 , wherein the first interface layer and the second interface layer comprise zinc oxide.

16. The method of claim 1 , wherein the partially fabricated panel further comprises a bottom diffusion layer formed between the substrate and the reflective layer, a bottom dielectric layer formed between the bottom diffusion layer and the substrate, and a seed layer formed between the bottom dielectric layer and the reflective layer, wherein the bottom diffusion layer comprises silicon nitride.

17. A method of forming a low emissivity panel, the method comprising:
providing a substrate;
forming a bottom diffusion layer over the substrate;
forming a first interface layer over the bottom diffusion layer;
forming a bottom dielectric layer over the first interface layer;
forming a second interface layer over the bottom dielectric layer;
forming a seed layer over the second interface layer;
forming a reflective layer over the seed layer;
forming a barrier layer over the reflective layer;
forming a third interface layer over the barrier layer;
forming a top dielectric layer over the third interface layer; and
forming a fourth interface layer over the top dielectric layer,
the reflective layer comprising silver,
the barrier layer comprising a partially oxidized alloy of at least nickel, titanium, and niobium,
the first interface layer, the second interface layer, the third interface layer, and the fourth interface layer having same composition and each comprising one of zinc oxide, titanium oxide, or tantalum oxide,
the first interface layer and the second interface layer directly interfacing the top dielectric layer and having same composition,
the top dielectric layer comprising one of tin oxide, zinc tin oxide, aluminum tin oxide, magnesium tin oxide, bismuth tin oxide, or niobium tin oxide,
the top dielectric layer being formed using reactive sputtering in an oxygen containing environment, and
the third interface layer substantially preventing further oxidation of the partially oxidized alloy of the at least nickel, titanium, and niobium.

18. The method of claim 12 , wherein a ratio of silicon to nitrogen in the top diffusion layer is between 0.8 and 1.0.

19. The method of claim 1 , wherein the first interface layer and the second dielectric layer comprise titanium oxide.

20. The method of claim 1 , wherein the barrier layer comprises nickel and chromium, and wherein a weight ratio of nickel to chromium in the barrier layer is between 3 and 5.

Assignees

• Guardian Industries

Inventors

• Ding Guowen
• Cheng Jeremy
• Imran Muhammad
• Le Minh Huu
• Schweigert Daniel
• Xu Yongli
• Zhang Guizhen

Classifications

• C03C17/3681

  the multilayer coating being used in glazing, e.g. windows or windscreens · CPC title

• E06B9/24

  Screens or other constructions affording protection against light, especially against sunshine; Similar screens for privacy or appearance; {Slat blinds}(operating, guiding or securing devices or arrangements for roll-type closures E06B9/56; free-hanging flexible screens A47H23/00) · CPC title

• C03C17/36 Primary

  at least one coating being a metal · CPC title

• Y10T428/265

  1 mil or less · CPC title

• C03C23/007

  by thermal treatment · CPC title