Method of transforming biomass into hydrocarbon

Patent metadata

Field	Value
Publication number	US-9738909-B1
Application number	US-201615049272-A
Country	US
Kind code	B1
Filing date	Feb 22, 2016
Priority date	Feb 22, 2016
Publication date	Aug 22, 2017
Grant date	Aug 22, 2017

Abstract

A method is provided to transform biomass. Non-food biomass is preprocessed. Then, fermentation is processed to generate ethanol. Ethanol is dehydrated through a catalyst to generate ethylene. After the dehydration, oligomerization is processed with a catalyst to transform ethylene into olefins having 6˜20 carbon atoms (C 6 ˜C 20 ). The olefins are hydrotreated into alkanes. Thus, C 6 ˜C 20 hydrocarbons having long carbon chains are formed. The hydrocarbons having 6˜10 carbon atoms can be used as gasoline; those having 8˜16 carbon atoms, jet fuel; and those having 16˜20 carbon atoms, diesel. On generating ethanol, byproducts of lignin may be generated. The byproducts can be processed through depolymerization/deoxygenation to generate aromatic hydrocarbons or can be gasified to generate methanol or dimethyl ether. By further processing dehydration, aromatic hydrocarbons are generated to be mixed into gasoline, jet fuel or diesel. Or, the lignin byproducts are gasified to generate syngas.

First claim

What is claimed is:

1. A method of transforming biomass into hydrocarbons, comprising steps of:
preprocessing a non-grain biomass and fermenting said biomass into ethanol and lignin;
processing said ethanol through dehydration with a catalyst to obtain ethylene; transforming said ethylene into olefin having 6˜20 carbon atoms through oligomerization with a catalyst; and hydrotreating said olefin into alkanes having long carbon chains of C 6 ˜C 20 , wherein said alkanes having 6˜10 carbon atoms form gasoline; said alkanes having 8˜16 carbon atoms form jet fuel; and said alkanes having 16˜20 carbon atoms form diesel fuel;
processing said lignin through depolymerization/deoxygenation to obtain aromatic hydrocarbon;
processing said lignin through gasification to obtain syngas; and
processing said syngas through a synthesis reaction to obtain one or both of methanol and dimethyl ether which is then dehydrated with a catalyst to obtain aromatic hydrocarbon and blended into gasoline/jet fuel/diesel and/or processing the syngas through a water-gas shift reaction to obtain hydrogen which is then used in hydrogenation reactions of olefins.

2. The method according to claim 1 , wherein said non-grain biomass is selected from a group consist of a fiber material and a mixture of fiber materials and said fiber material is selected from a group consist of straw, bagasse, miscanthus , bamboo, hardwood, softwood, sunflower stalk and Pennisetum.

3. The method according to claim 1 , wherein a selectivity of said ethylene is higher than 90%.

4. The method according to claim 1 , comprising using an acidic catalyst to process said oligomerization of ethylene to lengthen carbon chains.

5. The method according to claim 1 , wherein a selectivity of said hydrocarbon having 6˜10 carbon atoms is greater than 60%.

Assignees

• Inst Nuclear Energy Res Atomic Energy Council Executive Yuan Roc

Inventors

• Liang Kuo-Chao
• Ye Feng-Mei
• Wu cheng-gang

Classifications

• C12P5/02

  acyclic {(C12P5/007 takes precedence)} · CPC title

• C12P5/023

  Methane · CPC title

• C12P5/005 Primary

  aromatic (naphthacene C12P29/00) · CPC title

• C07C2/08

  Catalytic processes · CPC title

• Y02E50/10

  Biofuels, e.g. bio-diesel · CPC title