Fluid injection nozzle for fluid bed reactors

Patent metadata

Field	Value
Publication number	US-9738836-B2
Application number	US-201514812363-A
Country	US
Kind code	B2
Filing date	Jul 29, 2015
Priority date	Aug 28, 2014
Publication date	Aug 22, 2017
Grant date	Aug 22, 2017

Abstract

The liquid feed nozzle assemblies for a circulating fluid bed reactor comprise (i) a throttle body premixer to combine liquid feed with atomization steam to form a liquid feed/steam mixture comprising gas bubbles in liquid; (ii) a conduit connected to the premixer and to a discharge nozzle to convey a flow of the liquid/steam mixture created by the premixer to the nozzle body; (iii) a discharge nozzle connected to the flow conduit to shear the liquid feed/steam mixture to create liquid feed droplets of reduced size and (iv) a disperser at the outlet of the discharge nozzle to provide a spray jet of liquid feed having an increased surface area relative to a cylindrical jet. The nozzle assembles are particularly useful in fluid coking units using heavy oil feeds such a tar sands bitumen.

First claim

The invention claimed is:

1. A circulating fluid bed reactor having a reactor wall of circular cross section about a vertical axis, a lower inlet for fluidizing gas and feed injection nozzle assemblies for a liquid heavy oil feed and atomization steam above the lower fluidizing gas inlet and around the reactor wall, the nozzle assemblies each extending through the reactor wall into the reactor with a discharge orifice within the reactor and a feed inlet for the liquid heavy oil feed at the end remote from the discharge orifice; each feed injection nozzle assembly comprising:
a premixer section to combine the liquid heavy oil feed with atomization steam to form a liquid feed/steam mixture comprising gas bubbles in liquid, the premixer section comprising successive converging and diverging zones with a plurality of radial steam inlet ports located at the entry of the converging zone;
a flow conduit section following and connected to the outlet of the premixer section, extending from the premixer section to a discharge nozzle, to convey a flow of the liquid/steam mixture created by the premixer to the discharge nozzle;
a discharge nozzle having a convergent entry following and connected to the flow conduit section to shear the liquid feed/steam mixture and create liquid feed droplets of reduced size upon exit from the discharge nozzle.

2. A circulating fluid bed reactor according to claim 1 in which the premixer section includes a central cylindrical throat section connecting the converging and diverging zones.

3. A circulating fluid bed reactor according to claim 1 in which the nozzle assembly has a flow conduit section comprising successive convergence and divergence zones to reduce the size of the gas bubbles in the liquid feed/steam mixture from the premixer.

4. A circulating fluid bed reactor according to claim 3 further comprising a disperser in which the disperser has a body comprising a central flow passage of circular cross-section and a plurality of lobes in the body, the wall of each lobe defining a segment of a hollow cone with the axes of the hollow cones intersecting symmetrically with the central axis of the disperser to define an increasing multilobe exit passage of increasing cross-sectional area in the disperser body.

5. A fluid coking reactor according to claim 4 in which the premixer section includes a central cylindrical throat section connecting the converging and diverging zones.

6. A fluid coking reactor according to claim 5 further comprising a disperser in which the disperser has a body comprising a central flow passage of circular cross-section and a plurality of lobes in the body, the wall of each lobe defining a segment of a hollow cone with the axes of the hollow cones intersecting symmetrically with the central axis of the disperser to define an increasing multilobe exit passage of increasing cross-sectional area in the disperser body.

7. A fluid coking reactor according to claim 4 in which the nozzle body has a flow conduit section comprising successive convergence and divergence zones to reduce the size of the gas bubbles in the liquid feed/steam mixture from the premixer.

8. A fluid coking reactor according to claim 4 in which the nozzle assembly has a flow conduit section comprising tandem convergence zones separated by a diffusion zone.

9. A fluid coking reactor according to claim 4 in which the feed injection nozzles each comprise a multilobe disperser at the outlet of the discharge nozzle to generate a correspondingly shaped liquid jet plume having an increased surface area relative to a cylindrical jet.

10. A circulating fluid bed reactor according to claim 1 in which the nozzle assembly has a flow conduit section comprising tandem convergence zones separated by a diffusion zone.

11. A circulating fluid bed reactor according to claim 1 which comprises a multilobe disperser at the outlet of the discharge nozzle to generate a correspondingly shaped liquid jet plume having an increased surface area relative to a cylindrical jet.

12. A fluid coking reactor having a reactor wall of circular cross section about a vertical axis, a lower inlet for fluidizing gas and feed injection nozzle assemblies for a liquid heavy oil feed and atomization steam above the lower fluidizing gas inlet and around the reactor wall, the nozzle assemblies each extending through the reactor wall into the reactor with a discharge nozzle orifice within the reactor and an inlet for the liquid heavy oil feed at the end remote from the discharge nozzle; each feed injection nozzle assembly comprising:
a premixer section to combine the liquid heavy oil feed with atomization steam to form a liquid feed/steam mixture comprising gas bubbles in liquid, the premixer section comprising successive converging and diverging zones and a central throat section connecting the converging and diverging zones, with a plurality of radial steam inlet ports located at an entry of the converging zone;
a flow conduit section following and connected to the outlet of the premixer section, extending from the premixer section to a discharge nozzle, to convey a flow of the liquid/steam mixture created by the premixer to the discharge nozzle;
a discharge nozzle having a convergent entry following and connected to the flow conduit section to shear the liquid feed/steam mixture and create liquid feed droplets of reduced size upon exit from the discharge nozzle.

13. A fluid coking unit having a fluidized bed coking reactor which comprises:
a reaction section of circular cross section about a vertical axis and confined by a reactor wall,
a base region below the dense bed reaction section at which fluidizing gas in injected to fluidize a dense bed of finely-divided solid coke particles in the dense bed reaction section,
a plurality of heavy oil inlets located around the periphery of the reactor wall at multiple elevations above the base region,
a scrubber section above the reaction section and separated from the dense bed reaction section,
at least one cyclone at the top of the dense bed reaction section, each cyclone having an inlet for gas and coke particles exiting the reaction section, a cyclone gas outlet exhausting into the scrubber section and a cyclone dipleg for returning coke particles separated from the gas in the cyclone into the dense bed reaction section,
a stripping section at the base region of the reactor,
feed injection nozzle assemblies each extending through the reactor wall into the reactor with a discharge orifice within the reactor and an inlet for liquid heavy oil feed at the end remote from the discharge nozzle; each feed injection nozzle assembly comprising:
a premixer section to combine the liquid heavy oil feed with the atomization steam to form a liquid feed/steam mixture comprising gas bubbles in liquid, the premixer section comprising successive converging and diverging zones with a plurality of radial steam inlet ports located at an entry of the converging zone;
a flow conduit section following and connected to the outlet of the premixer section, extending from the premixer section to a discharge nozzle, to convey a flow of the liquid/steam mixture created by the premixer to the discharge nozzle;
a discharge nozzle having a convergent entry following and connected to the flow conduit section to shear the liquid feed/steam mixture and create liquid feed droplets of reduced size upon exit from the discharge nozzle.

14. A fluid coking reactor according to claim 13 in which the premixer section includes a central cylindrical throat section connecting the converging and diverging zones.

15. A fluid coking unit

Assignees

• Reid Kevin
• Mcmillan Jennifer
• Pougatch Konstantin
• Salcudean Martha E
• Exxonmobil Res & Eng Co

Inventors

• Reid Kevin
• Mcmillan Jennifer
• Pougatch Konstantin
• Salcudean Martha E

Classifications

• B01J2208/00902

  Nozzle-type feeding elements · CPC title

• C10G2300/107

  Atmospheric residues having a boiling point of at least about 538 °C · CPC title

• C10B55/10

  according to the "fluidised bed" technique · CPC title

• B01J2208/00911

  Sparger-type feeding elements · CPC title

• C10G9/005 Primary

  Coking (in order to produce liquid products mainly) · CPC title