Process for performing a fischer tropsch reaction

Patent metadata

Field	Value
Publication number	US-9738835-B2
Application number	US-201514837887-A
Country	US
Kind code	B2
Filing date	Aug 27, 2015
Priority date	Dec 28, 2009
Publication date	Aug 22, 2017
Grant date	Aug 22, 2017

Abstract

The invention relates to a process for performing a Fischer Tropsch reaction in a reactor comprising at least two reactor tubes, a coolant chamber, and a gas distribution system below the coolant chamber, whereby at least two reactor tubes extend through the coolant chamber and one or more highly porous catalysts, said catalyst(s) having a size of at least 1 mm and comprising a porous body and a catalyst material, whereby the porous body has a porosity within the range of between 50 and 98 volume %.

First claim

What is claimed is:

1. A process for performing a Fischer Tropsch reaction in a reactor comprising at least two reactor tubes, a coolant chamber, a space below the coolant chamber, a space above the coolant chamber and a gas distribution system in the space below the coolant chamber, whereby at least two reactor tubes extend through the coolant chamber such that the space below the cooling chamber is fluidly connected with the space above the cooling chamber and one or more highly porous catalysts, said catalyst(s) having a size of at least 1 mm and comprising a porous body and a catalyst material, whereby the porous body has a porosity within the range of between 50 and 98 volume %, said process comprising the following steps:
providing syngas to each of the reactor tubes individually at the bottom of each of the reactor tubes;
transporting liquid hydrocarbons from above the coolant chamber to below the coolant chamber and allowing liquid hydrocarbons to move from below the cooling chamber through at least one of the reactor tubes to above the cooling chamber; and
removing Fischer Tropsch product from the reactor.

2. A process according to claim 1 , wherein Fischer Tropsch product is removed from the reactor below the coolant chamber.

3. A process according to claim 1 , wherein the Fischer-Tropsch reaction is preferably carried out at a temperature in the range from 125 to 400 °C.

4. A process according to claim 1 , wherein the Fischer-Tropsch reaction is carried out at a pressure ranging from 5 to 150 bar.

5. A process according to claim 1 , wherein the gaseous hourly space velocity may vary from 500 to 10000 Nl/l/h.

6. A process according to claim 1 , wherein the Fischer-Tropsch reaction is performed in a reactor comprising a reactor shell, inlets for introducing reactants and coolant into the reactor shell, outlets for removing product and coolant from the reactor shell, at least two reactor tubes, a coolant chamber, and a gas distribution system below the coolant chamber having an outlet placed inside each reactor tube, whereby at least two reactor tubes extend through the coolant chamber to enable fluid communication between a space below the coolant chamber and a space above the coolant chamber, said reactor comprising one or more highly porous catalysts, said catalyst(s) having a size of at least 1 mm and comprising a porous body and a catalyst material, whereby the porous body has a porosity within the range of between 50 and 98 volume %.

7. A process according to claim 1 , wherein the reactor comprises a hydrocarbon fluid which is present in an amount sufficiently large to have the one or more highly porous catalysts in the reactor tubes immersed in liquid.

8. A process according to claim 7 , wherein the step of removing Fischer Tropsch product from the reactor is executed such that hydrocarbon fluid is removed as the product from the reactor in case the level of the hydrocarbon fluid in the reactor reaches a predetermined level in the reactor.

9. A process according to claim 1 , wherein the provision of syngas to each of the reactor tubes individually is such that the syngas is provided directly into the reactor tube.

10. A process according to claim 1 , wherein the one or more highly porous catalysts remain within the reactor tubes during the process.

Assignees

• Shell Oil Co

Inventors

• Schrauwen Franciscus Johannes Maria

Classifications

• B01J2208/00212

  Plates; Jackets; Cylinders · CPC title

• C10G2/33 Primary

  characterised by the catalyst used · CPC title

• C10G2/341

  with stationary catalyst bed · CPC title

• B01J8/067

  Heating or cooling the reactor (B01J8/062 takes precedence) · CPC title

• C10G2/34

  Apparatus, reactors · CPC title