Non-calcium geopolymer stabilizer

Patent metadata

Field	Value
Publication number	US-9738830-B2
Application number	US-201514920074-A
Country	US
Kind code	B2
Filing date	Oct 22, 2015
Priority date	Oct 23, 2014
Publication date	Aug 22, 2017
Grant date	Aug 22, 2017

Abstract

Geopolymers are one type of aluminosilicate materials formed through the polymerization of silicate and aluminate tetrahedrons. Geopolymer is used as a non-calcium-based stabilizer to mix with sulfate-rich soils. The stabilized soils were exposed to deionized water for 7 days until the volume of soil samples reached constant. Volumetric expansion of the sulfate-rich soil samples stabilized with metakaolin based geopolymer was 7 times lower than those stabilized with lime while the mechanical strength of stabilized soil samples were significantly improved.

First claim

The invention claimed is:

1. A method of stabilizing ground bearing surfaces, comprising:
synthesizing a geopolymer, the geopolymer being a non-calcium geopolymer;
combining the synthesized geopolymer with sulfate rich soil in to generate a soil combination having improved mechanical properties, the geopolymer including aluminosilicate materials formed by the polymerization and polycondensation of aluminate and silicate tetrahedrons by sharing oxygen atoms,
wherein the geopolymer has the form M n {(—SiO 2 ) z —AlO 2 —} n , where M is a cation to balance the negative charge of (AlO 2 ) −1 ) and the z value is the Si to Al molar ratio; and
compacting the generating soil combination to a maximum capacity compaction.

2. The method of claim 1 wherein the geopolymer is a metakaolin based geopolymer (MKG).

3. The method of claim 1 wherein combining further includes soil having at least 1000 ppm gypsum concentrations and metakaolin concentration between 8% and 13%.

4. The method of claim 1 wherein the mechanical properties are based on binding soil particles rather than ion exchanging.

5. The method of claim 1 wherein the geopolymer is cured at a temperature in a range of 25° C. to 80° C.

6. The method of claim 5 wherein synthesis of the geopolymer includes forming a geopolymer precursor in a paste form, further comprising mixing the geopolymer with the soil in a concentration between 8% and 13% of MKG (metakaolin based geopolymer).

7. The method of claim 1 wherein the combining occurs in and result in an absence of ettringite.

8. The method of claim 1 wherein synthesizing the geopolymer includes synthesizing from a waste stream having aluminum and silicon based materials.

9. The method of claim 8 wherein the waste stream is derived from at least one of fly ash, furnace slag and red mud.

10. A method of stabilizing ground bearing surfaces, comprising:
synthesizing a geopolymer, the geopolymer being a non-calcium geopolymer;
combining the synthesized geopolymer with sulfate rich soil to generate a soil combination having improved mechanical properties; and
compacting the generating soil combination to a maximum capacity compaction further comprising combining the sulfate rich soil with gypsum to achieve at least a 10,000 ppm gypsum content and combining with MKG (metakaolin based geopolymer) in a range between 8% and 13% for generating a soil combination exhibiting only negative expansion (shrinkage) during a curing time of 28 days.

11. The method of claim 10 wherein the soil combination exhibits a failure strain in a range between 2.5% and 3.0%.

12. The method of claim 10 wherein the soil combination yields a UCS (unconfined compressive strength) of a range between 3.0 and 5.0 MPa (Megapascals).

13. A stabilized weight bearing soil combination, comprising:
sulfate rich soil;
synthesized geopolymer in a ratio of between 8% and 13% of a volume of the weight bearing soil, the geopolymer including aluminosilicate materials formed by the polymerization and polycondensation of aluminate and silicate tetrahedrons by sharing oxygen atoms,
wherein the geopolymer has the form Mn{(—SiO2)z—AlO2—}n, where M is a cation to balance the negative charge of (AlO2)−1) and the z value is the Si to Al molar ratio; and
gypsum in a concentration of between 1000 and 10,000 ppm.

14. The soil combination of claim 13 wherein the geopolymer is a synthesized metakaolin based geopolymer (MKG).

15. The soil combination of claim 13 wherein the MKG (metakaolin based geopolymer) is synthesized using a geopolymer precursor in a paste form, wherein the combined geopolymer has a soil concentration between 8% and 13% of MKG (metakaolin based geopolymer).

16. A stabilized weight bearing soil combination, comprising:
sulfate rich soil;
synthesized geopolymer in a ratio of between 8% and 13% of the soil volume; and
gypsum in a concentration of between 1000 and 10,000 ppm wherein the sulfate rich soil has at least a 10,000 ppm gypsum content and an MKG (metakaolin based geopolymer) content in a range between 8% and 13% for generating a soil combination exhibiting only negative expansion (shrinkage) during a curing time of at least 28 days.

17. The soil combination of claim 16 wherein the soil combination exhibits a failure strain in a range between 2.5% and 3.0%.

18. The soil combination of claim 17 wherein the soil combination yields a UCS (unconfined compressive strength) of a range between 3.0 and 5.0 MPa (Megapascals).

Assignees

• Tao Mingjiang
• Zhang Mo
• Worcester Polytech Inst

Inventors

• Tao Mingjiang
• Zhang Mo

Classifications

• C09K17/08 Primary

  Aluminium compounds, e.g. aluminium hydroxide · CPC title

• E02D3/123

  and compacting the soil (E02D3/126 takes precedence) · CPC title

• C04B28/006

  containing mineral polymers, e.g. geopolymers of the Davidovits type · CPC title

• Y02P40/10

  Production of cement, e.g. improving or optimising the production methods; Cement grinding · CPC title

• Y02W30/91

  Use of waste materials as fillers for mortars or concrete · CPC title