Polymer blends

Patent metadata

Field	Value
Publication number	US-9738784-B2
Application number	US-201113878582-A
Country	US
Kind code	B2
Filing date	Oct 11, 2011
Priority date	Oct 11, 2010
Publication date	Aug 22, 2017
Grant date	Aug 22, 2017

Abstract

The present invention provides, among other things, extruded blends of aliphatic polycarbonates and polyolefins. In one aspect, provided blends comprise aliphatic polycarbonates such as poly(propylene carbonate) and a lesser amount of a crystalline or semicrystalline polymer. In certain embodiments, provided blends are characterized in that they exhibit unexpected improvements in their elongation properties. In another aspect, the invention provides methods of making such materials and applications of the materials in applications such as the manufacture of consumer packaging materials.

First claim

What is claimed is:

1. An extruded polymer blend comprising at least 70 weight percent aliphatic polycarbonate and at least one polyolefin, wherein:
the aliphatic polycarbonate comprises a blend of two or more aliphatic polycarbonates having a different average molecular weight and having greater than 90% carbonate linkages and less than 10% ether linkages;
the aliphatic polycarbonate is selected from the group consisting of poly(propylene carbonate), poly(ethylene carbonate), poly(propylene carbonate)-co-poly(ethylene carbonate), a poly(propylene carbonate) co-polymer with one or more additional aliphatic polycarbonates, a poly(ethylene carbonate) co-polymer with one or more additional aliphatic polycarbonates, a physical blend of any two or more of the above, and a copolymer comprising any of the above.

2. The extrude polymer blend of claim 1 , wherein the aliphatic polycarbonate comprises a copolymer of carbon dioxide and one or more epoxides.

3. The extruded polymer blend of claim 1 , comprising polypropylene carbonate).

4. The extruded polymer blend from claim 1 , comprising poly(ethylene carbonate).

5. The extruded polymer blend of claim 1 , wherein the polyolefin is selected from the group consisting of polyethylene, polypropylene, poly(alpha olefins), and mixtures or copolymers of any two or more of these.

6. The extruded polymer blend of claim 1 , wherein the polyolefin is selected from the group consisting of LDPE, LLDPE, HDPE, polypropylene, or any combination of the above.

7. The extruded polymer blend of claim 1 , wherein the polyolefin comprises polyethylene.

8. The extruded polymer blend of claim 1 , wherein the polyolefin comprises polypropylene.

9. The extruded polymer blend of claim 1 , further comprising at least one compatibilizer.

10. The extruded polymer blend of claim 1 , comprising at least 80 weight percent aliphatic poly carbonate.

11. The extruded polymer blend of claim 1 , comprising at least 85 weight percent aliphatic poly carbonate.

12. The extruded polymer blend of claim 1 , comprising at least 90 weight percent aliphatic poly carbonate.

13. The extruded polymer blend of claim 1 , comprising at least 95 weight percent aliphatic poly carbonate.

14. The extruded polymer blend of claim 10 , wherein the polyolefin represents between about 5% and about 30% of the blend.

15. The extruded polymer blend of claim 10 , wherein the polyolefin represents between about 10% and about 25% of the blend.

16. The extruded polymer blend of claim 1 , wherein the blend has been extruded at a temperature above 160° C.

17. The extruded polymer blend of claim 16 , wherein the blend has been extruded at a temperature above 170° C.

18. The extruded polymer blend of claim 16 , wherein the blend has been extruded at a temperature above 180° C.

19. The extruded polymer blend of claim 16 , wherein the blend has been extruded at a temperature above 200° C.

20. A plastic film comprising an extruded polymer blend of claim 1 .

21. The plastic film of claim 20 , wherein the film has been stretched and that the elongation before break value as measured using ASTM D882, prior to stretching is less than 50% and that the elongation before break value as measured using ASTM D882 after stretching is greater than 100%.

Assignees

• Allen Scott D
• Naik Sanjeev
• Novomer Inc

Inventors

• Allen Scott D
• Naik Sanjeev

Classifications

• C08L23/12

  Polypropene · CPC title

• B29C48/0018

  combined with shaping by orienting, stretching or shrinking, e.g. film blowing (B29C48/0017 takes precedence) · CPC title

• C08L23/10

  Homopolymers or copolymers of propene · CPC title

• C08J5/18

  Manufacture of films or sheets · CPC title

• Y10T428/31507

  Of polycarbonate · CPC title