Vacuum distillation method for easily polymerizable compound and method for producing acrylic acid

Patent metadata

Field	Value
Publication number	US-9738586-B2
Application number	US-201615134980-A
Country	US
Kind code	B2
Filing date	Apr 21, 2016
Priority date	Oct 29, 2013
Publication date	Aug 22, 2017
Grant date	Aug 22, 2017

Abstract

An object of the present invention is to provide a method in which, when a steam ejector is used as a decompression apparatus for a vacuum distillation process for an easily polymerizable compound, the steam ejector is prevented from being occluded due to polymerization of the easily polymerizable compound. Another object of the present invention is to provide a method for manufacturing an acrylic acid that is an easily polymerizable compound, using the above-described method. The above object is accomplished by a method for manufacturing an acrylic acid, which comprises a step of executing vacuum distillation, using a steam ejector, on an acrylic acid resulting from gas-phase catalytic oxidation using propane, propylene, or acrolein as a material, wherein the vacuum distillation step includes a step of heating an outer surface of the steam ejector.

First claim

The invention claimed is:

1. A method for manufacturing an acrylic acid, comprising:
executing vacuum distillation, using a steam ejector, on an acrylic acid resulting from gas-phase catalytic oxidation using propane, propylene, or acrolein as a material,
wherein an outer surface of the steam ejector is heated during the vacuum distillation, and
the vacuum distillation is executed such that the driving steam discharged through the outlet of the steam ejector has a pressure of from 0.5 to 2 MPaG.

2. The method according to claim 1 , wherein the outer surface of the steam ejector is heated by using a steam trace.

3. The method according to claim 1 , wherein the outer surface of the steam ejector is heated by using an electro-thermal heater.

4. The method according to claim 1 , wherein the outer surface of the steam ejector is heated to 50° C. or higher.

5. The method according to claim 1 , wherein the steam ejector has a multistage configuration.

6. The method according to claim 1 , wherein a liquid seal vacuum pump is arranged downstream of the steam ejector.

7. A method for vacuum distillation of an easily polymerizable compound using a steam ejector, comprising:
heating an outer surface of the steam ejector; and
controlling a pressure of the driving steam discharged through the outlet of the steam ejector to be from 0.5 to 2 MPaG.

8. The method according to claim 7 , wherein the easily polymerizable compound is an acrylic acid or an acrylic ester.

9. The method according to claim 8 , wherein the easily polymerizable compound is an acrylic acid resulting from gas-phase catalytic oxidation using propane, propylene, or acrolein as a material.

10. The method according to claim 7 , wherein the outer surface of the steam ejector is heated by using a steam trace.

11. The method according to claim 7 , wherein the outer surface of the steam ejector is heated by using an electro-thermal heater.

12. The method according to claim 7 , wherein the outer surface of the steam ejector is heated to 50° C. or higher.

13. The method according to claim 7 , wherein the steam ejector has a multistage configuration.

14. The method according to claim 7 , wherein a liquid seal vacuum pump is arranged downstream of the steam ejector.

15. The method according to claim 7 , wherein the heating and the controlling are simultaneously carried out.

16. The method according to claim 1 , wherein the steam ejector is heated to 50° C. or higher and lower than 150° C.

17. The method according to claim 1 , wherein the steam ejector is heated to 70° C. or higher and 130° C. or lower.

18. The method according to claim 1 , wherein gas entering the inlet port of the steam ejector consists of an exhaust gas from a condenser positioned upstream of the steam ejector.

19. The method according to claim 1 , further comprising:
introducing gas comprising the easily polymerizable compound to the inlet port of the steam ejector such that the gas entering the inlet port consists of an exhaust gas from a condenser positioned upstream of the steam ejector.

20. The method according to claim 8 , wherein the outer surface of the steam ejector is heated to 50° C. or higher.

Assignees

• Mitsubishi Chem Corp

Inventors

• Ogawa Yasushi

Classifications

• F04F5/20

  for evacuating · CPC title

• C07C51/445 Primary

  by steam distillation · CPC title

• C07C57/04

  Acrylic acid; Methacrylic acid · CPC title

• B01D3/38

  Steam distillation · CPC title

• B01D3/10

  Vacuum distillation (B01D3/12 takes precedence) · CPC title