Apparatus for producing ethylene and a producing method thereof

Patent metadata

Field	Value
Publication number	US-9738575-B2
Application number	US-201314397967-A
Country	US
Kind code	B2
Filing date	May 15, 2013
Priority date	May 16, 2012
Publication date	Aug 22, 2017
Grant date	Aug 22, 2017

Abstract

An apparatus for producing ethylene includes: a reactor; a first separation column, connected to the reactor; a second separation column, the upper part of the second separation column being connected to the bottom of the first separation column, and the top of the second separation column being connected to the lower part of the first separation column; a first condenser, an inlet of the first condenser being connected to the top of the first separation column, and an outlet of the first condenser being connected to the upper part of the first separation column; and a third separation column, used for receiving a second part of a first condensate from the condenser and separating the received part. A method for producing ethylene using the aforementioned apparatus is also described.

First claim

The invention claimed is:

1. An apparatus for producing ethylene, comprising:
a reactor, configured for dehydrating ethanol and obtaining an ethylene stream including ethane, ethanol, ethyl ether and by-products containing three or more carbon atoms;
a first separation column, connected to said reactor, configured for separating said ethylene stream including ethane, ethanol, ethyl ether and by-products containing three or more carbon atoms from said reactor to obtain a first light components containing ethylene at the top of said first separation column and a first heavy components containing ethylene at the bottom of said first separation column;
a second separation column, the upper part of said second separation column being connected to the bottom of said first separation column, the top of said second separation column being connected to a lower part of said first separation column, said second separation column configured for receiving and separating the first heavy components containing ethylene from the bottom of said first separation column to obtain a second light components containing ethylene at the top of said second separation column and a second heavy components at the bottom of said second separation column, wherein the second light components are returned to the lower part of said first separation column and the second heavy components are exhausted;
a first condenser, an inlet of said first condenser being connected to the top of said first separation column, and an outlet of said first condenser being connected to an upper part of said first separation column, said first condenser configured for condensing the first light components containing ethylene from the top of said first separation column to obtain a first condensate, wherein a first part of said first condensate is returned to the upper part of said first separation column; and
a third separation column, configured for receiving and separating a second part of said first condensate from said first condenser to obtain a liquid ethylene at the bottom of said third separation column and a third light components at the top of said third separation column.

2. The apparatus according to claim 1 , wherein said apparatus further comprises:
a second condenser, connected to the top of said third separation column, configured for receiving and condensing the third light components from the top of said third separation column to obtain a second condensate; and
a first reflux tank, connected to said second condenser and said third separation column respectively, configured for receiving a second condensate from said second condenser and returning said second condensate to an upper part of said third separation column.

3. The apparatus according to claim 1 wherein said apparatus further comprises:
a quenching column, connected between said reactor and said first separation column, configured for receiving and water quenching the ethylene stream including ethane, ethanol, ethyl ether and by-products containing three or more carbon atoms from said reactor to obtain a quenched ethylene stream at the top of said quenching column and organic wastewater including ethane, ethanol, ethyl ether and by-products containing three or more carbon atoms at the bottom of said quenching column, wherein the quenched ethylene stream is fed to said first separation column; and
a fourth separation column, connected to the bottom of said quenching column, for receiving and separating the organic wastewater including ethane, ethanol, ethyl ether and by-products containing three or more carbon atoms from the bottom of said quenching column to obtain a water stream at the bottom of said fourth separation column and a fourth light components including ethane, ethanol, ethyl ether and by-products containing three or more carbon atoms at the top of said fourth separation column.

4. The apparatus according to claim 3 , wherein said apparatus further comprises:
a third condenser, connected to the top of said fourth separation column, for receiving and condensing a fourth light components from the top of said fourth separation column to obtain a third condensate; and
a second reflux tank, connected to said third condenser and said fourth separation column respectively, configured for receiving a third condensate from said second condenser, wherein a first part of said third condensate is returned to an upper part of said fourth separation column, and a second part of said third condensate is exhausted.

5. The apparatus according to claim 1 wherein an operating temperature of said first separation column ranges from −35° C. to 30° C., an operating pressure thereof ranges from 1.3 MPaG to 4.5 MPaG, and a theoretical plate number thereof ranges from 50 to 140.

6. The apparatus according to claim 1 wherein an operating temperature of said second separation column ranges from −15° C. to 80° C., an operating pressure thereof ranges from 1.0 MPaG to 4.0 MPaG, and a theoretical plate number thereof ranges from 2 to 50.

7. The apparatus according to claim 1 wherein an operating temperature of said third separation column ranges from −45° C. to −10° C., an operating pressure thereof ranges from 1.2 MPaG to 4.3 MPaG, and a theoretical plate number thereof ranges from 2 to 60.

8. The apparatus according to claim 1 wherein an operating temperature of said third separation column ranges from 30° C. to 210° C., an operating pressure thereof ranges from 0 MPaG to 1.0 MPaG, and a theoretical plate number thereof ranges from 2 to 98.

9. A method for producing ethylene using the apparatus according claim 1 , comprising:
1) feeding ethanol to the reactor to dehydrate said ethanol to obtain an ethylene stream including ethane, ethanol, ethyl ether and by-products containing three or more carbon atoms;
2) feeding said ethylene stream including ethane, ethanol, ethyl ether and by-products containing three or more carbon atoms obtained in step 1) to said first separation column and separating the ethylene stream to obtain a first light components containing ethylene at the top of said first separation column and a first heavy components containing ethylene at the bottom of said first separation column;
3) feeding the first heavy components containing ethylene obtained in step 2) to an upper part of said second separation column, and separating the first heavy components in said second separation column to obtain a second light components containing ethylene at the top of said second separation column and a second heavy components at the bottom of said second separation column, wherein the second light components are returned to the lower part of said first separation column and the second heavy components are exhausted; at the same time, feeding the first light components containing ethylene obtained in step 2) to said first condenser to obtain a first condensate, wherein the first part of the first condensate is returned to the upper part of said first separation column; and
4) feeding the second part of said first condensate to a third separation column to obtain a liquid ethylene at the bottom of said third separation column and a third light components at the top of said third separation column.

10. The method according to claim 9 , wherein said method further comprises:
5) feeding said third light components obtained in step 4) to a second condenser to obtain a second condensate; and
6) feeding said second condensate obtained in step 5) to a first reflux tank, and then the second condensate is returned to an upper part of said third separation column through said first reflux tank.

11. The method according to claim 9 wherein said method further comprises:
before feed

Assignees

• China Petroleum & Chem Corp
• Shanghai Res Inst Of Petrochemical Tech Sinopec

Inventors

• Shao Baixiang
• Shen Wei
• He Zhi
• Wu Yiming

Classifications

• C07C2521/04

  Alumina · CPC title

• C07C11/04

  Ethene · CPC title

• C10G2400/20

  C2-C4 olefins · CPC title

• C07C7/09

  by fractional condensation · CPC title

• C07C7/005 Primary

  Processes comprising at least two steps in series · CPC title