Electroless nickel plating of a high temperature power feedthrough for corrosion inhabitance

Patent metadata

Field	Value
Publication number	US-9738555-B2
Application number	US-201313904123-A
Country	US
Kind code	B2
Filing date	May 29, 2013
Priority date	May 29, 2013
Publication date	Aug 22, 2017
Grant date	Aug 22, 2017

Abstract

A method of making an electrode assembly for a furnace includes providing a heating element within the furnace. The method further includes providing a power feedthrough having an end portion that extends into the furnace to couple with the heating element. The power feedthrough includes a conductive member for transmitting electricity to the heating element. The method includes cleaning an exterior surface of the conductive member proximate the end portion of the power feedthrough. The method further includes a step of applying an electroless nickel plating to the exterior surface of the conductive member for preventing corrosion of the conductive member within the furnace. The method also includes connecting the end portion of the power feedthrough to the heating element.

First claim

What is claimed is:

1. A method of making an electrode assembly for a furnace, comprising
providing a heating element within the furnace;
providing a power feedthrough having an end portion that extends into the furnace to couple with the heating element, wherein the power feedthrough includes a conductive member for transmitting electricity to the heating element, said conductive member of said power feedthrough including a shaft and being at least partially within the furnace;
cleaning at least an exterior surface of the conductive member adjacent to the proximate the end portion of the conductive member of the power feedthrough that is constructed to be situated within the furnace, said cleaning step comprising applying to the exterior surface at least one of:
(i) a chemical solution comprising: at least one of hydroxycarboxylic acid or salt, surfactant, a reducing agent;
(ii) a copper flash; and

applying an electroless nickel plating to the cleaned exterior surface of the conductive member for preventing corrosion of the conductive member within the furnace and pre-treating the exterior surface of the conductive member before depositing the electroless nickel plating wherein pre-treating includes applying an electrolytic sulfamate nickel plating to the exterior surface of the shaft; and
connecting the end portion of the power feedthrough to the heating element.

2. The method of claim 1 , wherein the shaft is a copper shaft.

3. The method of claim 2 , wherein the copper shaft has a cylindrical shape, and wherein the electrolytic sulfamate nickel plating includes a thickness between 0.0002 and 0.0004 inches.

4. The method of claim 1 , wherein the conductive member includes a copper shaft, and wherein cleaning the exterior surface of the conductive member includes applying a copper flash to the exterior surface.

5. The method of claim 1 , wherein cleaning the exterior surface of the conductive member includes applying a chemical solution to the exterior surface.

6. The method of claim 1 , wherein the electroless nickel plating comprises a high phosphorous nickel having a phosphorus content between 11 and 13 percent.

7. The method of claim 1 , wherein the electroless nickel plating includes a thickness between 2 and 3 millimeters.

8. The method of claim 1 , wherein the end portion of the power feedthrough includes a threaded end and the heating element includes a threaded receptacle for coupling with the threaded end.

9. A method of making a power feedthrough for a furnace, comprising:
providing a copper shaft having an exterior surface, a distal end with an axial cavity, and a proximal end configured to couple with a heating element within the furnace;
cleaning at least the exterior surface of the conductive member proximate the proximal end to provide a clean surface, said cleaning step comprising applying to the exterior surface at least one of:
(i) a chemical solution comprising: at least one of: hydroxycarboxylic acid or salt, surfactant, a reducing agent;
(ii) a copper flash; and

treating the exterior surface of the conductive member by applying an electrolytic sulfamate nickel plating to the clean surface; and
after the treating step applying an electroless high phosphorus nickel plating to the clean surface for preventing corrosion of the copper shaft within the furnace.

10. The method of claim 9 , wherein the sulfamate nickel plating includes a thickness between 0.0001 and 0.0005 inches.

11. The method of claim 9 , wherein cleaning includes applying a copper flash to the exterior surface of the copper shaft.

12. The method of claim 9 , wherein cleaning includes applying a chemical solution to the exterior surface of the copper shaft.

13. The method of claim 9 , wherein the electroless high phosphorous nickel plating includes a generally consistent thickness that is greater than 2 millimeters, and wherein the axial cavity is configured to receive a liquid coolant for cooling the copper shaft.

14. The method of claim 9 , wherein the electroless high phosphorous nickel plating has a phosphorus content between 10 and 15 percent.

Assignees

• Corning Inc

Inventors

• Taft Terry Lee
• Womer Kim E

Classifications

• Y10T29/49083

  Heater type · CPC title

• C03B5/1672 Primary

  Use of materials therefor · CPC title

• H05B3/03

  Electrodes · CPC title

• C03B5/027

  by passing an electric current between electrodes immersed in the glass bath, i.e. by direct resistance heating · CPC title