Carbon nanostructures from pyrolysis of organic materials

Patent metadata

Field	Value
Publication number	US-9738524-B2
Application number	US-201514733019-A
Country	US
Kind code	B2
Filing date	Jun 8, 2015
Priority date	Mar 26, 2009
Publication date	Aug 22, 2017
Grant date	Aug 22, 2017

Abstract

Methods and apparatus to generate carbon nanostructures from organic materials are described. Certain embodiments provide solid waste materials into a furnace, that pyrolyzes the solid waste materials into gaseous decomposition products, which are then converted to carbon nanostructures. Methods and apparatuses described herein provide numerous advantages over conventional methods, such as cost savings, reduction of handling risks, optimization of process conditions, and the like.

First claim

What is claimed is:

1. A method of synthesizing a carbon nanostructure, comprising:
pyrolyzing an organic material in a first furnace set at a temperature to obtain one or more gaseous decomposition products;
mixing the one or more gaseous decomposition products with an oxidizing agent to obtain a pre-mixed fuel-rich flame; and
contacting one or more effluents of the fuel-rich flame with a supported catalyst in a second furnace to form the carbon nanostructure.

2. The method of claim 1 , wherein the pyrolyzing step is carried out in an inert atmosphere.

3. The method of claim 1 , further comprising adding hydrogen, oxygen, water vapor, sulfur-containing compound, or combinations thereof to promote activation of the supported catalyst.

4. The method of claim 3 , wherein the hydrogen, oxygen, water vapor, sulfur-containing compound, or combinations thereof is added from about 0.0001% to about 80% by volume.

5. The method of claim 1 , wherein the organic material comprises a solid plastic.

6. The method of claim 1 , wherein the organic material comprises a liquid.

7. The method of claim 1 , wherein the supported catalyst comprises a waste material.

8. The method of claim 1 , further comprising adding an inert gas during the mixing step.

9. The method of claim 1 , wherein the mixing step is carried out in a venturi section of the first furnace.

10. The method of claim 1 , further comprising passing said one or more effluents of the fuel-rich flame through a filter prior to said contacting.

11. The method of claim 10 , wherein the one or more effluents of the fuel-rich flame is passed through multiple filters.

12. A method of obtaining a carbon nanostructure, comprising:
pyrolyzing an organic material in a first furnace at a temperature greater than 600° C. to obtain a feedstock which comprises one or more gaseous decomposition products;
passing the feedstock through a filter to obtain a filtered gas; and
providing the filtered gas to a carbon nanostructure manufacturing process in a second furnace to form a carbon nanostructure; wherein the organic material comprises a liquid.

13. The method of claim 12 , further comprising mixing the one or more gaseous decomposition products with an inert gas.

14. The method of claim 12 , wherein the pyrolyzing step is carried out in an inert atmosphere.

15. The method of claim 12 , wherein the providing the feedstock in a carbon nanostructure manufacturing process comprises contacting the filtered gas with a supported catalyst to form the carbon nanostructure.

16. The method of claim 12 , wherein the carbon nanostructure manufacturing process comprises a chemical vapor deposition process.

17. The method of claim 12 , wherein the second furnace is at a temperature ranging from 600° C. to 1500° C.

18. The method of claim 12 , wherein the filter comprises ceramic.

Assignees

• Univ Northeastern
• Nano-C Inc

Inventors

• Levendis Yiannis
• Richter Henning
• Zhuo Chuanwei

Classifications

• B82Y40/00

  Manufacture or treatment of nanostructures · CPC title

• C01B2202/34

  Length · CPC title

• Y10S977/842

  for carbon nanotubes or fullerenes · CPC title

• C01B2202/06

  Multi-walled nanotubes · CPC title

• C01B32/16 Primary

  Preparation · CPC title