Electrochromic devices

Patent metadata

Field	Value
Publication number	US-9738140-B2
Application number	US-201514815030-A
Country	US
Kind code	B2
Filing date	Jul 31, 2015
Priority date	Aug 4, 2014
Publication date	Aug 22, 2017
Grant date	Aug 22, 2017

Abstract

An electrochromic device includes a first substantially transparent substrate having an electrically conductive material associated therewith, a second substantially transparent substrate having an electrically conductive material associated therewith, an electrochromic composition contained within a chamber positioned between the first and second substrates that includes at least one anodic electroactive material, at least one cathodic electroactive material, and at least one solvent, wherein at least one of the anodic electroactive and cathodic electroactive materials is electrochromic, and wherein the electrochromic device exhibits a contrast ratio of at least 20,000:1, a darkening time less than about 30 seconds, and a clearing time of less than about 150 seconds.

First claim

What is claimed is:

1. An electrochromic device comprising:
a first substantially transparent substrate;
second substantially transparent substrate substantially parallel to the first substantially transparent substrate and spaced apart therefrom; and
an electrochromic medium disposed between the first substantially transparent substrate and the second substantially transparent substrate;
wherein:
the electrochromic device is configured to exhibit a contrast ratio of at least 20,000:1, a darkening time less than about 30 seconds, and a clearing time of less than about 150 seconds; and
the electrochromic medium comprises:
an anodic electroactive material; and
a cathodic electroactive material comprising a N,N′-dialkyldipyridinium compound.

2. The electrochromic device of claim 1 , wherein the contrast ratio is from about 20,000:1 to about 500,000:1.

3. The electrochromic device of claim 1 , wherein the contrast ratio is at least 40,000:1.

4. The electrochromic device of claim 1 , wherein the contrast ratio is at least 60,000:1.

5. The electrochromic device of claim 1 , wherein the clearing time is about 20 seconds to about 60 seconds.

6. The electrochromic device of claim 1 , wherein the darkening time is about 5 seconds to about 30 seconds.

7. The electrochromic device of claim 1 , wherein the anodic electroactive material is present in the medium at a concentration of at least 5 mM.

8. The electrochromic device of claim 1 , wherein the anodic electroactive material is present in the medium at a concentration of about 5 mM to about 7 mM.

9. The electrochromic device of claim 1 , wherein the cathodic electroactive material is present in the medium at a concentration of at least 50 mM.

10. The electrochromic device of claim 1 , wherein the cathodic electroactive material is present in the medium at a concentration of about 60 mM to about 100 mM.

11. The electrochromic device of claim 1 , wherein the first substantially transparent substrate and the second substantially transparent substrate are spaced apart by a distance of about 150 μm to about 500 μm.

12. The electrochromic device of claim 1 , wherein the first substantially transparent substrate and the second substantially transparent substrate are spaced apart by a distance of about 200 μm to about 300 μm.

13. The electrochromic device of claim 1 , wherein the anodic electroactive material comprises a 2,7-dialkyl-5,10-dialkyl-5,10-dihydrophenazine compound, and at least one alkyl of the 5,10-dialkyl groups has at least four carbon atoms, and is void of any β hydrogen atoms; and at least one alkyl group of the 2,7-dialkyl comprises at least four carbon atoms.

14. The electrochromic device of claim 13 , wherein at least one alkyl group of the 5,10-dialkyl comprises a substituted or unsubstituted neopentyl group; and at least one alkyl group of the 2,7-dialkyl comprises a substituted or unsubstituted isopropyl, isobutyl, (2-ethylbutyl), or (2-propylpentyl) group.

15. The electrochromic device of claim 1 , wherein at least one alkyl of the N,N′-dialkyldipyridinium compound comprises at least four carbon atoms, and includes less than two β hydrogen atoms.

16. The electrochromic device of claim 1 , wherein the electrochromic medium comprises at least three different anodic electroactive materials.

17. An aircraft window system comprising:
a housing for containing a first substantially transparent interior substrate, a second substantially transparent exterior substrate, and a variable transmission electrochromic window positioned between the interior and exterior substrates, the variable transmission electrochromic window comprising:
a third substantially transparent substrate having an electrically conductive material associated therewith;
a fourth substantially transparent substrate having an electrically conductive material associated therewith, the fourth substantially transparent substrate positioned parallel to and spaced apart from the third substantially transparent substrate; and
an electrochromic medium disposed between the third and fourth substantially transparent substrates and contacting the electrically conductive material associated with third substrate and the electrically conductive material associate with the fourth substrate

wherein:
the electrochromic medium comprises:
an anodic electroactive material;
a cathodic electroactive material comprising a N,N′-dialkyldipyridinium compound; and
a solvent;

at least one of the anodic electroactive and cathodic electroactive materials is electrochromic;
the variable transmission electrochromic window exhibits a contrast ratio of at least 20,000:1;
the variable transmission electrochromic window exhibits a darkening time less than about 30 seconds; and
the variable transmission electrochromic window exhibits a clearing time of less than about 150 seconds.

18. The aircraft window composition of claim 17 , wherein the window maintains a M ce (T) of less than 1 for all the intermediate transmission values of the window.

19. The aircraft window composition of claim 17 , wherein the window maintains a M ce (T) of less than 0.7 for all the intermediate transmission values of the window.

Assignees

• Gentex Corp

Inventors

• Ash Kevin L
• Baumann Kelvin L
• Franz Sue F

Classifications

• G02F2001/15145

  the electrochromic layer comprises a mixture of anodic and cathodic compounds · CPC title

• G02F1/15 Primary

  based on an electrochromic effect · CPC title

• B60J3/04 Primary

  adjustable in transparency · CPC title

• G02F2001/1512

  Physics · mapped topic

• G02F1/1516

  comprising organic material · CPC title