Monophosphite ligands having a tert-butyloxycarbonyl group
US-9221850-B2 · Dec 29, 2015 · US
Process for catalytic preparation of aldehydes from olefins using monophosphite mixtures
US9737884B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9737884-B2 |
| Application number | US-201514716437-A |
| Country | US |
| Kind code | B2 |
| Filing date | May 19, 2015 |
| Priority date | May 20, 2014 |
| Publication date | Aug 22, 2017 |
| Grant date | Aug 22, 2017 |
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Abstract
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The catalytic preparation of an aldehyde from an olefin proceeds in the presence of a monophosphite mixture.
First claim
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The invention claimed is: 1. A mixture, which comprises a mixture of compounds 1 and 2: 2. A complex mixture, comprising: are according to claim 1 , and a metal atom selected from the group consisting of Rh, Ru, Co, and Ir. 3. The complex mixture according to claim 2 , wherein said metal atom is Rh. 4. A process for hydroformylation of an olefin, comprising: a) initially charging an olefin, b) adding a mixture according to claim 1 c) adding a compound comprising one of the following metals: Rh, Ru, Co, or Ir, to obtain a reaction mixture, c) feeding H 2 and CO into the reaction mixture, d) heating the reaction mixture, to convert the olefin to an aldehyde, wherein the additions in process steps b) and c) can also be effected in one step through the addition of a corresponding complex mixture. 5. The process according to claim 4 , wherein the olefin is a mono-olefin having 2 to 24 carbon atoms, and having a terminal or an internal C≡C double bond. 6. The process according to claim 4 , wherein the olefin is an α-olefin, terminally branched, internal and internally branched olefin. 7. The process according to claim 4 , wherein a terminally hydroformylated olefin is obtained.
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Classifications
- B01J31/185Primary
Phosphites ((RO)3P) , their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof · CPC title
with hydroxyaryl compounds · CPC title
- B01J31/2295Primary
Cyclic compounds, e.g. cyclopentadienyls · CPC title
Rhodium · CPC title
Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen · CPC title
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- What does patent US9737884B2 cover?
- The catalytic preparation of an aldehyde from an olefin proceeds in the presence of a monophosphite mixture.
- Who is the assignee on this patent?
- Dyballa Katrin Marie, Franke Robert, Fridag Dirk, and 4 more
- What technology area does this patent fall under?
- Primary CPC classification B01J31/185. Mapped technology areas include Operations & Transport.
- When was this patent published?
- Publication date Tue Aug 22 2017 00:00:00 GMT+0000 (Coordinated Universal Time) (B2). Legal status and post-grant events are not shown on this page.
- What related patents are in patentsdb?
- We list 8 related publications on this page (citations in our corpus or others sharing the same primary CPC).