Method for fabricating core-shell particles supported on carrier and core-shell particles supported on carrier fabricated by the same

Patent metadata

Field	Value
Publication number	US-9735432-B2
Application number	US-201314383049-A
Country	US
Kind code	B2
Filing date	Apr 22, 2013
Priority date	May 11, 2012
Publication date	Aug 15, 2017
Grant date	Aug 15, 2017

Abstract

The present invention provides a method for fabricating core-shell particles supported on a carrier, the method including: forming a solution by adding a first metal supported on a carrier to a solvent; adjusting a pH of the solution from 7 to 14 and adding a metal salt of a second metal thereto; and forming core-shell particles by adding a reducing agent to the solution and forming a shell including the second metal on a surface of a core particle including the first metal, and core-shell particles fabricated by the method.

First claim

What is claimed is:

1. A method for fabricating core-shell particles supported on a carrier, the method comprising:
forming a solution by adding a first metal supported on a carrier to a solvent;
adjusting a pH of the solution from 10 to 12 and adding a metal salt of a second metal thereto; and
forming core-shell particles by adding a reducing agent to the solution after the metal salt of a second metal has been added and forming a shell including the second metal on a surface of a core particle including the first metal;
wherein the metal salt of the second metal is represented by the following Formula 1:
XA m B n

in Formula 1,
X is different from the first metal, and is selected from the group consisting of platinum (Pt) and palladium (Pd),
A is (NH 3 ), (CH 3 NH 2 ) or (H 2 O),
B is NO 3 —, NO 2 — or OH—,
m is 2, 4 or 6, and n is an integer from 1 to 7, and
wherein throughout the method of fabricating core-shell particles the temperature of the solution is maintained between 4° C. and 35° C.,
the first metal is nickel (Ni), and
wherein in the adding of the metal salt of the second metal to the solution, the metal salt of the second metal is added such that a molar ratio of the first metal to the second metal in the solution is from 1:1 to 10:1.

2. The method of claim 1 , wherein the carrier is a carbon-based material or an inorganic fine particle.

3. The method of claim 1 , wherein the solvent includes water.

4. The method of claim 1 , wherein no surfactant is used in the method.

5. The method of claim 1 , wherein the pH of the solution is adjusted by adding a base solution.

6. The method of claim 1 , wherein the reducing agent has a standard reduction potential of −0.23 V or less.

7. The method of claim 1 , wherein the core-shell particles have an average particle diameter from 2 nm to 300 nm.

8. The method of claim 1 , wherein a particle diameter of the core is from 1 nm to 200 nm and a thickness of the shell is from 0.5 nm to 50 nm.

Assignees

• Lg Chemical Ltd

Inventors

• Cho Jun Yeon
• Kim Sang Hoon
• Hwang Gyo Hyun

Classifications

• B01J35/45

  Nanoparticles · CPC title

• B01J35/0013

  Operations & Transport · mapped topic

• B01J37/0244

  Coatings comprising several layers · CPC title

• H01M4/8657 Primary

  layered · CPC title

• Y10S977/81

  Of specified metal or metal alloy composition · CPC title