Ion trap with parallel bar-electrode arrays

Patent metadata

Field	Value
Publication number	US-9735001-B2
Application number	US-201514829454-A
Country	US
Kind code	B2
Filing date	Aug 18, 2015
Priority date	Apr 29, 2006
Publication date	Aug 15, 2017
Grant date	Aug 15, 2017

Abstract

The invention “Ion Trap Array (ITA)” pertains generally to the field of ion storage and analysis technologies, and particularly to the ion storing apparatus and mass spectrometry instruments which separate ions by its character such as mass-to-charge ratio. The aim of this invention is providing an apparatus for ion storage and analysis comprising at least two or more rows of parallel placed electrode array wherein each electrode array includes at least two or more parallel bar-shaped electrodes, by applying different phase of alternating current voltages on different bar electrodes to create alternating electric fields inside the space between two parallel electrodes of different rows of electrode arrays, multiple linear ion trapping fields paralleled constructed in the space between the different rows of electrode arrays which are open to adjacent each other without a real barrier. This invention also provides a method for ion storage and analysis involving with the trapping, cooling and mass-selected analyzing of ions by this apparatus mentioned which constructs multiple conjoint linear ion trapping fields in the space between the different rows of electrode arrays.

First claim

The invention claimed is:

1. An apparatus for ion storage and analysis comprising:
at least first and second parallel spaced-apart electrode arrays, the first electrode array comprising a first row of at least two first bar electrodes, the second electrode array comprising a second row of at least two second bar electrodes, the first bar electrodes of the first electrode array being in corresponding arrangement with and facing the second bar electrodes of the second electrode array to establish a plurality of paired facing bar electrodes;
a power supply for applying phases of alternating current voltages to the first and second bar electrodes to create alternating electric fields in spaces between the first and second bar electrodes of the paired facing bar electrodes, wherein the first bar electrodes of the first electrode array and the second bar electrodes of the second electrode array are configured to alternate between a positive phase voltage and a negative phase voltage;
parallel linear ion trapping regions formed in the spaces between the corresponding first and second bar electrodes of the paired facing bar electrodes, the ion trapping regions being adjacent to one another, wherein the adjacent ion trapping regions are in communication with one another,
an ion detector for detecting ions ejected from the apparatus; and
a reticulate electrode,
wherein at least one of said first and second bar electrodes is provided with an opening through which ions may be ejected from the apparatus, and wherein the reticulate electrode is between the ion detector and the opening.

2. The apparatus of claim 1 further comprising boundary electrodes disposed at opposite ends of the first and second electrode arrays.

3. The apparatus of claim 2 wherein the boundary electrodes has a potential equal to a median of the potentials of the corresponding first and second bar electrodes.

4. The apparatus of claim 1 wherein the alternating current voltages comprise a high frequency voltage component and a low frequency voltage component, the low frequency voltage component being below 1000 Hz.

5. The apparatus of claim 1 further comprising electric switches for creating high or low frequency voltages.

6. The apparatus of claim 2 wherein at least one of said boundary electrodes is provided with an opening through which ions may be ejected from the apparatus.

7. The apparatus of claim 1 further comprising a voltage generator and coupling equipment for creating dipole fields between the first and second electrode arrays.

8. The apparatus of claim 1 wherein at least one of said electrode array is formed out of a Printed Circuit Board.

9. The apparatus of claim 1 wherein there is an unobstructed passageway between said ion trapping regions.

10. The apparatus of claim 1 wherein the opening is a slit.

11. A method for ion storage and analysis comprising the steps of:
providing an apparatus for ion storage and analysis, the apparatus comprising at least first and second parallel spaced-apart electrode arrays, the first electrode array comprising a first row of at least two first bar electrodes, the second electrode array comprising a second row of at least two second bar electrodes, each of the first bar electrodes facing a corresponding one of the second bar electrodes of the second electrode array to establish a plurality of paired facing bar electrodes, the apparatus further comprising boundary electrodes disposed at opposite edges of the first and second electrode arrays;
assigning alternating current voltages to the first and second bar electrodes to create alternating electric fields in spaces between the first and second bar electrodes of the paired facing bar electrodes, wherein the first bar electrodes of the first electrode array and the second bar electrodes of the second electrode array are configured to alternate between a positive phase voltage and a negative phase voltage; and;
forming parallel linear ion trapping regions in the spaces between the corresponding first and second bar electrodes of the paired facing bar electrodes;
trapping and cooling ions in the ion trapping regions;
ejecting ions from the apparatus based on mass to charge ratio differences of the ions; and
detecting and analyzing the ejected ions with an ion detector,
wherein at least one of said first and second bar electrodes is provided with an opening through which the ions may be ejected from the apparatus, and wherein a reticulate electrode is between the ion detector and the opening.

12. The method of claim 11 wherein the opening is a slit.

Assignees

• Univ Fudan

Inventors

• Ding Chuanfan
• Ding Li

Classifications

• H01J49/4225 Primary

  Multipole linear ion traps, e.g. quadrupoles, hexapoles · CPC title

• H01J49/065

  having stacked electrodes, e.g. ring stack, plate stack · CPC title

• H01J49/4235

  Stacked rings or stacked plates · CPC title

• H01J49/004

  Combinations of spectrometers, tandem spectrometers, e.g. MS/MS, MSn · CPC title