Dilution into a transfer line between valves for mass spectrometry

Patent metadata

Field	Value
Publication number	US-9733158-B1
Application number	US-201514830052-A
Country	US
Kind code	B1
Filing date	Aug 19, 2015
Priority date	Aug 19, 2014
Publication date	Aug 15, 2017
Grant date	Aug 15, 2017

Abstract

A system can include a sampler assembly configured to collect a viscous sample at a first location. In implementations, the viscous sample includes concentrated sulfuric acid (e.g., greater than about 75% H 2 SO 4 ). The system can also include a valve coupled with the sampler assembly for receiving the viscous sample. The valve is configured to couple with a source of a diluent and a sample transfer line. The system further includes a pump coupled with the valve for injecting the diluent into the sample transfer line along with the viscous sample to dilute the viscous sample and transport the diluted sample to a second location remote from the first location via the sample transfer line. In implementations, the sample transfer line is at least approximately two meters in length.

First claim

What is claimed is:

1. A system comprising:
a sampler assembly configured to collect a sample of concentrated sulfuric acid at a first location;
a valve coupled with the sampler assembly for receiving the sample of concentrated sulfuric acid, the valve further coupled with a source of a diluent and with a sample transfer line, the sample transfer line having an internal diameter of about 0.8 millimeters;
a pump coupled with the valve for injecting the diluent into the sample transfer line along with the sample of concentrated sulfuric acid to dilute the sample to furnish a fully liquid diluted sample and transport the fully liquid diluted sample to a second location remote from the first location via the sample transfer line having a length of at least two meters.

2. The system as recited in claim 1 , wherein the sample of concentrated sulfuric acid includes sulfuric acid having a concentration of greater than about 75% sulfuric acid.

3. The system as recited in claim 1 , wherein the sample of concentrated sulfuric acid includes sulfuric acid having a concentration of about 98% sulfuric acid.

4. The system as recited in claim 1 , wherein the valve is located within about one meter from a source of the concentrated sulfuric acid from which the sampler assembly collects the sample of the concentrated sulfuric acid at the first location.

5. The system as recited in claim 1 , further comprising:
a valve at the second location coupled to the sample transfer line, the valve at the second location configured to receive the fully liquid diluted sample via the sample transfer line.

6. The system as recited in claim 5 , further comprising:
a power line configured to supply power between the sampling assembly and the valve at the second location.

7. The system as recited in claim 6 , wherein at least a portion of the power line is coupled to the sample transfer line.

8. The system as recited in claim 1 , wherein the system is configured to receive an internal standard added using a syringe.

9. The system as recited in claim 1 , wherein the system is configured to receive a standard spike added using a syringe.

10. A method comprising:
collecting a sample of concentrated sulfuric acid at a first location with a sampler assembly;
receiving a diluent and the sample of concentrated sulfuric acid with a valve assembly;
injecting the diluent and the sample of concentrated sulfuric acid into a sample transfer line to dilute the sample of concentrated sulfuric acid to furnish a fully liquid diluted sample, the sample transfer line having an internal diameter of about 0.8 millimeters; and
transferring the fully liquid diluted sample from the first location to a second location via the sample transfer line having a length of at least two meters.

11. The method as recited in claim 10 , wherein the sample of concentrated sulfuric acid includes sulfuric acid having a concentration of greater than about 75% sulfuric acid.

12. The method as recited in claim 10 , wherein the sample of concentrated sulfuric acid includes sulfuric acid having a concentration of about 98% sulfuric acid.

13. The method as recited in claim 10 , wherein the valve assembly is located within about one meter from a source of the concentrated sulfuric acid at the first location.

14. The method as recited in claim 10 , further comprising:
receiving the fully liquid diluted sample with a valve at the second location via the sample transfer line.

15. The method as recited in claim 14 , further comprising:
supplying power between the sampling assembly and the valve at the second location via a power line.

16. The method as recited in claim 15 , wherein at least a portion of the power line is coupled to the sample transfer line.

17. A system comprising:
a sampler assembly configured to collect a sample of concentrated sulfuric acid at a first location, the concentrated sulfuric acid having a concentration of greater than about 75% sulfuric acid;
a valve coupled with the sampler assembly for receiving the sample of concentrated sulfuric acid, the valve further coupled with a source of a diluent and with a sample transfer line, the sample transfer line having an internal diameter of about 0.8 millimeters, the valve positioned within about one meter from a source of the concentrated sulfuric acid from which the sampler assembly collects the sample of the concentrated sulfuric acid at the first location;
a pump coupled with the valve for injecting the diluent into the sample transfer line along with the sample of concentrated sulfuric acid to dilute the sample to furnish a fully liquid diluted sample and transport the fully liquid diluted sample to a second location remote from the first location via the sample transfer line having a length of at least two meters.

18. The system as recited in claim 17 , wherein the sample of concentrated sulfuric acid includes sulfuric acid having a concentration of about 98% sulfuric acid.

19. The system as recited in claim 17 , further comprising:
a valve at the second location coupled to the sample transfer line, the valve at the second location configured to receive the fully liquid diluted sample via the sample transfer line.

20. The system as recited in claim 19 , further comprising:
a power line configured to supply power between the sampling assembly and the valve at the second location, wherein at least a portion of the power line is coupled to the sample transfer line.

Assignees

• Elemental Scientific Inc

Inventors

• Wiederin Daniel R
• Schultz Austin

Classifications

• G01N1/14 Primary

  Suction devices, e.g. pumps; Ejector devices · CPC title

• G01N35/1097 Primary

  characterised by the valves (valves in general F16K) · CPC title

• G01N21/73

  using plasma burners or torches · CPC title

• G01N1/38

  Diluting, dispersing or mixing samples · CPC title