Process of preparing a chemically pre-formed (cpf) iron negative electrode with oxidizing compounds
US-2015060740-A1 · Mar 5, 2015 · US
US9732409B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9732409-B2 |
| Application number | US-201414478990-A |
| Country | US |
| Kind code | B2 |
| Filing date | Sep 5, 2014 |
| Priority date | Sep 5, 2013 |
| Publication date | Aug 15, 2017 |
| Grant date | Aug 15, 2017 |
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Provided is a process for preparing an electrode comprising an iron active material. The process comprises first fabricating an electrode comprising an iron active material, and then treating the electrode with a gaseous oxidant to thereby create an oxidized surface. The resulting iron electrode is preconditioned prior to any charge-discharge cycle to have the assessable surface of the iron active material in the same oxidation state as in discharged iron negative electrodes active material.
Opening claim text (preview).
What is claimed is: 1. A process for preparing an electrode comprising an iron active material, which comprises: i) fabricating an electrode comprising an iron active material, and ii) treating the electrode with a gaseous oxidant to thereby create an oxidized surface prior to any charge-discharge cycle. 2. The process of claim 1 , therein the oxidant comprises ozone, chlorine, or nitrous oxide. 3. The process of claim 2 , wherein the oxidant comprises ozone. 4. The process of claim 1 , wherein the electrode surface has been treated with a gaseous oxidant prior to any charge-discharge cycle to have the accessible surface of the iron material in the same oxidation state as discharged iron negative electrode active material. 5. The process of claim 4 , wherein the oxidation state of the oxidized iron active material is +2, +2/+3, +3 or +4. 6. The process of claim 1 , wherein the electrode further comprises a binder. 7. The process of claim 1 , wherein the electrode further comprises sulfur. 8. The process of claim 1 , wherein the electrode further comprises a conductive additive. 9. The process of claim 8 , wherein the conductive additive comprises nickel, or copper or carbon black. 10. The process of claim 1 , wherein the electrode comprises an iron active material comprising about: 50-90 wt % iron powder 5-30 wt % nickel powder 0.5-5.0 w % binder, and 0.25-2.0 w % sulfur. 11. The process of claim 1 , wherein the electrode comprise a single layer of conductive substrate coated on at least one side with a coating comprising the iron active material. 12. The process of claim 11 , wherein the substrate is comprised of nickel plated steel. 13. The process of claim 1 , wherein the porosity of the electrode is in the range of about 15-50%. 14. The process of claim 1 , wherein the electrode surface is treated with the gaseous oxidant by exposing the surface of the electrode to the gaseous oxidant in a closed environment.
Physical characteristics, e.g. porosity, surface area · CPC title
in the form of layers, e.g. coatings · CPC title
Metal or alloys, e.g. alloy coatings (H01M4/669 take precedence) · CPC title
Electric conductive fillers · CPC title
Binders · CPC title
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