Process for the production of a gasoline with a low sulfur content
US-9222036-B2 · Dec 29, 2015 · US
US9732289B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9732289-B2 |
| Application number | US-201414317660-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jun 27, 2014 |
| Priority date | Jun 27, 2014 |
| Publication date | Aug 15, 2017 |
| Grant date | Aug 15, 2017 |
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An integrated process and apparatus for conversion of gas oil and heavy oil is described. The process includes passing a gas oil feed to a fluid catalytic cracking (FCC) zone to obtain a FCC effluent; separating the FCC effluent in a separation zone into at least two fractions comprising a clarified slurry oil fraction and an overhead fraction; passing the clarified slurry oil fraction to a slurry hydrocracking zone forming at least a naphtha stream; and recycling at least a portion of the slurry hydrocracking naphtha stream to the FCC zone.
Opening claim text (preview).
What is claimed is: 1. An integrated process for conversion of vacuum gas oil and heavy oil comprising: passing a gas oil feed to a fluid catalytic cracking (FCC) zone to obtain a FCC effluent; separating the FCC effluent in a separation zone into at least two fractions comprising a clarified slurry oil fraction and an overhead fraction; passing the clarified slurry oil fraction to a slurry hydrocracking zone forming at least a naphtha stream; and recycling at least a portion of the slurry hydrocracking naphtha stream to the FCC zone. 2. The process of claim 1 further comprising: forming a gas oil stream in the slurry hydrocracking zone; and recycling the slurry hydrocracking gas oil stream to the FCC zone. 3. The process of claim 1 further comprising combining the clarified slurry oil fraction with a vacuum residue fraction before passing the clarified slurry oil fraction to the slurry hydrocracking zone. 4. The process of claim 1 further comprising: forming a distillate stream in the slurry hydrocracking zone; and recovering the distillate stream. 5. The process of claim 1 further comprising: separating the overhead fraction into at least two portions, a first portion comprising at least one of butenes and pentenes and a second portion; passing the first portion to an oligomerization zone to produce an oligomerization effluent; recycling the oligomerization effluent to the FCC zone. 6. The process of claim 5 wherein the FCC zone comprises at least two FCC risers, and: wherein passing the gas oil feed to the FCC zone comprises passing the gas oil feed to the first FCC riser; wherein recycling the oligomerization effluent to the FCC zone comprises recycling the oligomerization effluent to the first FCC riser. 7. The process of claim 1 wherein the FCC zone comprises at least two FCC risers, and: wherein passing the gas oil feed to the FCC zone comprises passing the gas oil feed to the first FCC riser; and wherein recycling at least the portion of the slurry hydrocracking naphtha stream to the FCC zone comprises recycling at least the portion of the slurry hydrocracking naphtha stream to the second FCC riser. 8. The process of claim 1 wherein the FCC zone comprises at least two FCC risers, and wherein the FCC effluent comprises an FCC effluent from the first FCC riser and an FCC effluent from the second FCC riser. 9. The process of claim 1 further comprising hydrotreating the gas oil feed before passing the gas oil feed to the FCC zone. 10. The process of claim 1 further comprising separating the overhead fraction into at least one of a fuel gas fraction, a C 6+ fraction, a C 3 -C 4 fraction, a C 3 fraction, a C 4 fraction, a C 5 fraction, a propane fraction, and a propylene fraction. 11. The process of claim 10 further comprising: forming a light ends stream in the slurry hydrocracking zone; and combining the slurry hydrocracking light ends stream with at least a portion of the overhead fraction. 12. The process of claim 10 wherein the FCC zone comprises at least two FCC risers, and wherein passing the gas oil feed to the FCC zone comprises passing the gas oil feed to the first FCC riser, and wherein the overhead stream is separated into at least one of the C 4 fraction, or C 5 fraction; and further comprising: recycling the C 4 fraction, or the C 5 fraction, or both to the second FCC riser. 13. The process of claim 1 wherein separating the FCC effluent in the separation zone into the at least two fractions comprises separating the FCC effluent in the separation zone into the clarified slurry oil fraction, the overhead fraction, and at least one of a gasoline fraction and a light cycle oil fraction. 14. The process of claim 1 further comprising: forming a pitch stream in the slurry hydrocracking zone; and passing the pitch stream to a pitch deasphalting unit to produce a high grade asphalt product. 15. The process of claim 1 wherein separating the FCC effluent in the separation zone into the at least two fractions comprises separating the FCC effluent in the separation zone into the clarified slurry oil fraction, the overhead fraction, and a C 6+ fraction, and further comprising: combining at least a portion of the C 6+ fraction with at least the portion of the slurry hydrocracking naphtha stream; and wherein recycling at least the portion of the slurry hydrocracking naphtha stream to the FCC zone comprises recycling the combined stream to the FCC zone. 16. The process of claim 15 wherein the FCC zone comprises at least two FCC risers, and wherein passing the gas oil feed to the FCC zone comprises passing the gas oil feed to the first FCC riser, and wherein recycling the combined stream to the FCC zone comprises recycling the combined stream to the second FCC riser. 17. The process of claim 1 wherein separating the FCC effluent in the separation zone into the at least at least two fractions comprises separating the FCC effluent in the separation zone into the clarified slurry oil fraction, the overhead fraction, and a FCC heavy naphtha fraction, and further comprising: passing at least a portion of the FCC heavy naphtha fraction to an extractive distillation zone to form an aromatics stream. 18. An integrated process for conversion of gas oil and heavy oil comprising: hydrotreating a gas oil feed; passing the hydrotreated gas oil feed to a fluid catalytic cracking (FCC) zone to obtain a FCC effluent; separating the FCC effluent in a separation zone into at least two fractions comprising a clarified slurry oil fraction and an overhead fraction; combining the clarified slurry oil fraction with a vacuum residue fraction; passing the combined clarified slurry oil fraction and vacuum residue fraction to a slurry hydrocracking zone forming at least a naphtha stream, and a gas oil stream; recycling at least a portion of the slurry hydrocracking naphtha stream to the FCC zone; recycling the slurry hydrocracking gas oil stream to the FCC zone; separating the overhead fraction into at least one of a fuel gas fraction, a C 6+ fraction, a C 3 -C 4 fraction, a C 3 fraction, a C 4 fraction, a C 5 fraction, a propane fraction, and a propylene fraction. 19. The process of claim 18 wherein separating the overhead fraction into at least one of a fuel gas fraction, a C 6+ fraction, the C 3 -C 4 fraction, the C 3 fraction, the C 4 fraction, the C 5 fraction, the propane fraction, and the propylene fraction comprises separating the overhead fraction into at least one of the C 4 fraction and the C 5 fraction; and further comprising: passing at least a portion of at least one of the C 4 fraction and the C 5 fraction to an oligomerization zone to produce an oligomerization effluent; and recycling the oligomerization effluent to the FCC zone.
Recycling aspects · CPC title
with polymerisation · CPC title
Vacuum distillates · CPC title
suspended in the oil, e.g. slurries · CPC title
polymerisation, e.g. oligomerisation · CPC title
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