Adhesive for laminated sheets

Patent metadata

Field	Value
Publication number	US-9732260-B2
Application number	US-201414518029-A
Country	US
Kind code	B2
Filing date	Oct 20, 2014
Priority date	Apr 23, 2012
Publication date	Aug 15, 2017
Grant date	Aug 15, 2017

Abstract

An adhesive for laminated sheets comprising a urethane resin obtainable by mixing an acrylic polyol with an isocyanate compound. The acrylic polyol is obtained by polymerizing a mixture including a first monomer having a hydroxyl group and acrylonitrile. The isocyanate compound includes both an isocyanate compound having no aromatic ring and an isocyanate compound having an aromatic ring. Also cured reaction products of the adhesive and films laminated using the adhesive.

First claim

What is claimed is:

1. An adhesive for laminated sheets, consisting of:
a urethane resin obtained by mixing an acrylic polyol with an isocyanate compound, wherein
the acrylic polyol is a polyol having a glass transition temperature of from −20 to 20° C., which polyol is obtained by polymerizing a mixture selected from the group consisting of a first monomer having a hydroxyl group, optionally a different second monomer and acrylonitrile; and
the isocyanate compound includes both an isocyanate compound having no aromatic ring selected from an aliphatic isocyanate compound and an alicyclic isocyanate compound and an isocyanate compound having an aromatic ring
wherein an equivalent ratio of the isocyanate groups derived from the isocyanate having an aromatic ring to the hydroxyl groups derived from the acrylic polyol is 0.5 or more and an equivalent ratio of the isocyanate groups derived from all isocyanates to the hydroxyl groups derived from the acrylic polyol is in the range of 1.5 to 2.5; and

optionally other components selected from the group consisting of ultraviolet absorber, hindered phenol based compound, antioxidant, hindered amine based compound, light stabilizer, catalyst, tackifier resin, pigment, plasticizer, flame retardant, wax, solvent.

2. The adhesive for laminated sheets according to claim 1 , wherein the polyol is obtained by polymerizing the mixture comprising the first monomer having a hydroxyl group, the different second monomer and acrylonitrile.

3. The adhesive for laminated sheets according to claim 1 , wherein the different second monomer has an ethylenic double bond.

4. The adhesive for laminated sheets according to claim 1 , wherein the acrylic polyol has a hydroxyl value of from 0.5 to 45 mgKOH/g.

5. The adhesive for laminated sheets according to claim 1 , wherein the second monomer includes a (meth)acrylic acid ester.

6. The adhesive for laminated sheets according to claim 1 , wherein an equivalent ratio of the isocyanate groups derived from the isocyanate having an aromatic ring to the hydroxyl groups derived from the acrylic polyol is 1.5:1 to 2.5:1.

7. The adhesive for laminated sheets according to claim 1 , wherein the acrylic polyol is obtained by polymerizing the mixture comprising the first monomer having a hydroxyl group and 1 to 40 parts by weight of acrylonitrile based on 100 parts by weight of the mixture.

8. The adhesive for laminated sheets according to claim 1 , wherein the isocyanate is selected from 1,6-diisocyanatohexane (HDI), isophorone diisocyanate, tolylene diisocyanate (TDI) and combinations thereof.

9. The adhesive for laminated sheets according to claim 1 , wherein the isocyanate is selected from 1,6-diisocyanatohexane (HDI) in isocyanurate form, isophorone diisocyanate in isocyanurate form, tolylene diisocyanate (TDI) as an adduct with trimethylolpropane and combinations thereof.

10. The adhesive for laminated sheets according to claim 1 , wherein the isocyanate compound includes both the alicyclic isocyanate compound and the isocyanate compound having an aromatic ring.

11. The adhesive for laminated sheets according to claim 1 , wherein the isocyanate compound includes the aliphatic isocyanate compound, the alicyclic isocyanate compound and the isocyanate compound having an aromatic ring.

12. The adhesive for laminated sheets according to claim 1 , including the ultraviolet absorber.

13. Cured reaction products of the adhesive of claim 1 .

14. A laminated sheet comprising a first film bonded to a second film by the adhesive of claim 1 .

15. The laminated sheet of claim 14 wherein at least one of the first film or second film is a metal film.

16. A solar battery backsheet comprising a first film bonded to a second film by the adhesive of claim 1 .

17. An outdoor material including a laminated sheet comprising the adhesive for laminated sheets according to claim 1 .

Assignees

• Henkel Ag & Co Kgaa

Inventors

• Yamada Yasushi
• Ito Shoko
• Kamai Noriyoshi
• Matsuki Yuichi

Classifications

• Y10T428/31605

  Next to free metal · CPC title

• B32B2307/712

  Weather resistant · CPC title

• C08G18/6262

  Polymers of nitriles derived from alpha-beta ethylenically unsaturated carboxylic acids · CPC title

• B32B7/12

  using interposed adhesives or interposed materials with bonding properties · CPC title

• C09J133/12

  Homopolymers or copolymers of methyl methacrylate · CPC title