Latexes and associated ink-jet inks

Patent metadata

Field	Value
Publication number	US-9732244-B2
Application number	US-201214426572-A
Country	US
Kind code	B2
Filing date	Sep 14, 2012
Priority date	Sep 14, 2012
Publication date	Aug 15, 2017
Grant date	Aug 15, 2017

Abstract

The present disclosure provides ink-jet inks and associated methods. In one example, an ink jet ink can comprise an ink vehicle, a wax emulsion, and a latex particulate. The latex particulate can comprise multiple intermingled discrete polymer strands, including: a low Tg polymer strand having a Tg below 50° C. and a high Tg polymer strand having a Tg at 50° C. or above. Additionally, the Tg of the high Tg polymer strand can be at least 50° C. greater than the Tg of the low Tg polymer strand.

First claim

What is claimed is:

1. An ink-jet ink, comprising:
an ink vehicle;
a wax emulsion present in the ink at a concentration ranging from 0.2 wt % to 5 wt %, wherein the wax emulsion has wax particles with sizes ranging from 50 nm to 600 nm; and
a latex particulate that does not have a core/shell structure, comprising multiple intermingled discrete polymer strands, including:
low Tg polymer strands and
high Tg polymer strands intermingled with the low Tg polymer strands;

wherein the Tg of the high Tg polymer strands is at least 50° C. greater than the Tg of the low Tg polymer strands, and
wherein the Tg of the low Tg polymer strands is below 20° C. and the Tg of the high Tg polymer strands is at 90° C. or above.

2. The ink-jet ink of claim 1 , wherein the wax emulsion comprises a wax having a melting point ranging from 60° C. to 110° C.

3. The ink-jet ink of claim 1 , wherein the wax emulsion is present in the ink at a concentration ranging from 0.5 wt % to 1.5 wt % and wherein the wax emulsion has wax particles with sizes ranging from 200 nm to 300 nm.

4. The ink-jet ink of claim 1 , wherein the average homopolymer refractive index of monomers of the low Tg polymer strands is within 1% of the average homopolymer refractive index of monomers of the high Tg polymer strands.

5. The ink-jet ink of claim 1 , wherein the ink vehicle includes water and co-solvent having a boiling point from 160° C. to 250° C., the co-solvent present in an amount of 1 wt % to 40 wt %; and wherein the ink vehicle includes no more than 3 wt % non-volatile co-solvent having a boiling point greater than 250° C. and no more than 5 wt % volatile co-solvent having a boiling point lower than 160° C.

6. The ink-jet ink of claim 1 , wherein the low Tg polymer strands are prepared from multiple co-monomers and the high Tg polymer strands are prepared from the same multiple co-monomers at a different ratio.

7. The ink-jet ink of claim 6 , wherein the multiple co-monomers are selected so that the average homopolymer refractive index of the monomers of the low Tg polymer strands is within 1% of the average homopolymer refractive index of the monomers of the high Tg polymer strands.

8. The ink-jet ink of claim 1 , wherein the Tg of the high Tg polymer strands is at least 100° C. above the Tg of the low Tg polymer strands.

9. The ink-jet ink of claim 1 , wherein the monomers of the low Tg polymer strands and the monomers of the high Tg polymer strands are selected from the group of acrylates, methacrylates, vinyls, styrenes, ethylene, vinyl chloride, vinylidene chloride, maleate esters, fumarate esters, itaconate esters combinations thereof, and mixtures thereof.

10. The ink-jet ink of claim 1 , further comprising a colorant, wherein the colorant is a pigment.

11. A method of making an ink-jet ink, comprising
dispersing a wax emulsion and a latex particulate in an ink vehicle;
wherein the wax emulsion is present in the ink-jet ink at a concentration ranging from 0.2 wt % to 5 wt %, wherein the wax emulsion has wax particles with sizes ranging from 50 nm to 600 nm;
wherein the latex particulate does not have a core/shell structure and comprises multiple intermingled discrete polymer strands, including:
low Tg polymer strands having a Tg below 50° C., and
high Tg polymer strands having a Tg at 50° C. or above intermingled with the low Tg polymer strands; and

wherein the Tg of the high Tg polymer strand is at least 50° C. greater than the Tg of the low Tg polymer strand, and
wherein the method further comprises manufacturing the latex particulate by polymerizing a first ratio of multiple co-monomers to form low Tg polymer strands; and polymerizing a second ratio of the same co-monomers to form high Tg polymer strands, to form the latex particulate including the high Tg polymer strands that are discrete and intermingled with the low Tg polymer strands.

12. The method of claim 11 , wherein the wax has a melting point ranging from 60° C. to 110° C. and a particle size ranging from 50 nm to 600 nm.

13. An ink-jet ink, comprising:
an ink vehicle;
a wax emulsion; and
a latex particulate, comprising multiple intermingled discrete polymer strands, including:
a low Tg polymer strand having a Tg below 50° C., and
a high Tg polymer strand having a Tg at 50° C. or above;

wherein the Tg of the high Tg polymer strand is at least 50° C. greater than the Tg of the low Tg polymer strand, and wherein the low Tg polymer strand is prepared from multiple co-monomers and the high Tg polymer strand is prepared from the same multiple co-monomers at a different ratio.

14. A method of making the ink-jet ink of claim 13 , comprising:
manufacturing the latex particulate by polymerizing a first ratio of multiple co-monomers to form low Tg polymer strands having a Tg below 50° C. and polymerizing a second ratio of the same co-monomers to form high Tg polymer strands having a Tg at 50° C. or above, wherein the Tg of the high Tg polymer strands is at least 50° C. greater than the Tg of the low Tg polymer strands, to form the latex particulate including the high Tg polymer strands that are discrete and intermingled with the low Tg polymer strands; and
dispersing the wax emulsion and the latex particulate in an ink vehicle.

15. An ink-jet ink, comprising:
an ink vehicle;
a wax emulsion present in the ink at a concentration ranging from 0.2 wt % to 5 wt %, wherein the wax emulsion has wax particles with sizes ranging from 50 nm to 600 nm; and
a latex particulate that does not have a core/shell structure, comprising multiple intermingled discrete polymer strands, including:
a low Tg polymer strand having a Tg below 50° C., and
a high Tg polymer strand having a Tg at 50° C. or above;

wherein the Tg of the high Tg polymer strand is at least 50° C. greater than the Tg of the low Tg polymer strand, and wherein the average homopolymer refractive index of monomers of the low Tg polymer strand is within 1% of the average homopolymer refractive index of monomers of the high Tg polymer strand.

Assignees

• Ingle Jr David Michael
• Cagle Phillip C
• Bruinsma Paul Joseph
• Yen Max
• Hewlett Packard Development Co Lp

Inventors

• Ingle Jr David Michael
• Cagle Phillip C
• Bruinsma Paul Joseph
• Yen Max

Classifications

• C09D11/107

  from unsaturated acids or derivatives thereof · CPC title

• C09D11/30 Primary

  Inkjet printing inks · CPC title

• C09D11/36

  based on non-aqueous solvents · CPC title

• C09D11/106

  containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds · CPC title

• C09D11/10

  based on artificial resins · CPC title