Polymers and polymer blends with enhanced gloss level

Patent metadata

Field	Value
Publication number	US-9732220-B2
Application number	US-201414773888-A
Country	US
Kind code	B2
Filing date	Mar 11, 2014
Priority date	Mar 13, 2013
Publication date	Aug 15, 2017
Grant date	Aug 15, 2017

Abstract

The present invention provides a polycarbonate composition containing hydroxy aluminum hydroxide which exhibits increased gloss level. This effect is seen in polycarbonate blend or blends of polycarbonate and polyesters. This additive is effective in increasing the gloss level of polymer or polymer blend with gloss levels lower than 80 at 20 degree incident angle.

First claim

What is claimed is:

1. A thermoplastic molding composition comprising:
A) 50 to 98 wt. % aromatic poly(ester) carbonate having a weight-average molecular weight of at least 25,000;
B) a flame retardant;
C) 1 to 20 wt. % of a graft (co)polymer having a core-shell morphology, including a grafted shell that contains polymerized alkyl(meth)acrylate and a composite rubber core that contains interpenetrated and inseparable polyorganosiloxane and poly(meth)alkyl acrylate components, wherein said core is in the form of particles having median particle size of 0.05 to 5 microns and glass transition temperature below 0° C., and wherein weight ratio of polyorganosiloxane/poly(meth)alkylacrylate/rigid shell is 5-90/5-90/5-15;
D) greater than zero wt. % to 7.0 wt. % aluminum oxide particles having a particle size (d 50 ) of 25 μm to 150 μm,

wherein the sum of the wt. %, totals 100 and wherein the composition exhibits an increased gloss level at 20 degrees over that of a similar composition not containing aluminum oxide.

2. The composition according to claim 1 further including from greater than zero wt. % to 10.0 wt. % of glass fibers.

3. The composition according to claim 1 , wherein the polycarbonate is linear.

4. The composition according to claim 1 , wherein the polycarbonate is branched.

5. The composition according to claim 1 wherein the composite rubber core comprises butylacrylate.

6. The composition according to claim 1 further containing at least one member selected from the group consisting of lubricant, mold-release agent, nucleating agent, antistatic, thermal stabilizer, hydrolytical stabilizer, light stabilizer, colorant, pigment, filler, reinforcing agent, flameproofing agent other than component E), and flameproofing synergist.

7. The composition according to claim 1 further including 1 wt. % to 30 wt. % of a thermoplastic polyester.

8. The composition according to claim 7 , wherein the thermoplastic polyester is selected from the group consisting of polyethylene terephthalate, polybutylene terephthalate, polyethylene naphthalate, polybutylene naphthalate, polytrimethylene terephthalate, poly(1,4-cyclohexylenedimethylene 1,4-cyclohexanedicarboxylate), poly(1,4-cyclohexylenedimethylene terephthalate), poly(cyclohexylenedimethylene-co-ethylene terephthalate), or a combination thereof.

9. The composition according to claim 1 further including a boron compound.

10. The composition according to claim 9 , wherein the boron compound is zinc borate.

Assignees

• Bayer Materialscience Llc
• Covestro Llc

Inventors

• Li Xiangyang

Classifications

• C08L9/00

  Compositions of homopolymers or copolymers of conjugated diene hydrocarbons · CPC title

• C08K2003/387

  Borates · CPC title

• C08K2003/2227

  of aluminium · CPC title

• C08L83/04

  Polysiloxanes · CPC title

• C08L51/085

  on to polysiloxanes · CPC title