Block copolymer composition, and sheet

Patent metadata

Field	Value
Publication number	US-9732215-B2
Application number	US-201314399128-A
Country	US
Kind code	B2
Filing date	May 2, 2013
Priority date	May 8, 2012
Publication date	Aug 15, 2017
Grant date	Aug 15, 2017

Abstract

A block copolymer composition with a good balance of physical properties suitable for various types of packaging such as food product containers, beverage containers, industrial containers and blister packs, having excellent transparency, gloss, strength, rigidity and formability, having excellent anti-blocking properties and anti-sticking properties, and excelling in the aforementioned properties even when used in mixture with vinyl aromatic hydrocarbon-type polymers is offered. A block copolymer composition of a vinyl aromatic hydrocarbon and a conjugated diene, wherein a block copolymer component (I) having a molecular weight peak in the range of molecular weight 150,000 to 300,000 and comprising tapered blocks has a conjugated diene content of 10 to 20 mass %; a block copolymer component (II) having a molecular weight peak in the range of molecular weight 50,000 to 140,000 and comprising tapered blocks has a conjugated diene content of 30 to 50 mass %; and a ratio (I)/(II) between molecular weight peak areas occupied by block copolymer component (I) and block copolymer component (II) in the block copolymer composition is 20/80 to 80/20.

First claim

The invention claimed is:

1. A block copolymer composition, comprising a block copolymer component (I) and a block copolymer component (II),
wherein the block copolymer component (I) and the block copolymer component (II) both comprise a vinyl aromatic hydrocarbon and a conjugated diene,
the block copolymer component (I) and the block copolymer component (II) both comprise a tapered block wherein the component ratios of the vinyl aromatic hydrocarbon and the conjugated diene change from one end to the other end of the block, and a vinyl aromatic hydrocarbon polymer block,
the block copolymer component (I) has a molecular weight peak in the range of molecular weight 150,000 to 300,000 in terms of molecular weight distribution obtained by gel permeation chromatography,
the block copolymer component (II) has a molecular weight peak in the range of molecular weight 50,000 to 140,000 in terms of molecular weight distribution obtained by gel permeation chromatography,
the content of the conjugated diene in the block copolymer component (I) is 10 to 20 mass %,
the content of the conjugated diene in the block copolymer component (II) is 30 to 50 mass %, and
the ratio (I)/(II) between molecular weight peak areas occupied by block copolymer component (I) and block copolymer component (II) in the block copolymer composition obtained by gel permeation chromatography is 20/80 to 80/20.

2. The block copolymer composition of claim 1 , wherein block copolymer component (I) has a molecular weight peak in the range of molecular weight 180,000 to 290,000 and the conjugated diene content in block copolymer component (I) is 10 to 15 mass %; block copolymer component (II) has a molecular weight peak in the range of molecular weight 50,000 to 140,000 and the conjugated diene content in block copolymer component (II) is 30 to 50 mass %; and the ratio (I)/(II) between molecular weight peak areas occupied by block copolymer component (I) and block copolymer component (II) in the block copolymer composition is 40/60to 60/40.

3. The block copolymer composition of claim 1 , wherein the molecular weight range of the vinyl aromatic hydrocarbon polymer block in the block copolymer component (I) is 80,000 to 150,000; and the molecular weight range of the vinyl aromatic hydrocarbon polymer block in the block copolymer component (II) is 5,000 to 40,000.

4. The block copolymer composition of claim 1 , comprising a total amount of 0.03 to 1.0 mass % in the block copolymer composition of a single hydrocarbon wax, or at least one chosen from among hydrocarbon waxes, stearyl stearate, stearic acid monoglyceride, erucamide and behenamide.

5. The block copolymer composition of claim 4 , wherein the hydrocarbon wax is a microcrystalline wax, a synthetic wax, or a mixture of a microcrystalline wax and a synthetic wax having a melting point of 60 to 120° C., and is contained in the block copolymer composition in an amount of 0.03 to 0.5 mass %.

6. The block copolymer composition of claim 5 , wherein the hydrocarbon wax has a melting point of 80 to 110° C.

7. The block copolymer composition of claim 4 , comprising a total amount of 0.03 to 0.5 mass % in the block copolymer composition of a lubricant chosen from among stearyl stearate, stearic acid monoglyceride, erucamide and behenamide.

8. A resin composition comprising the block copolymer composition of claim 1 and a vinyl aromatic hydrocarbon polymer at a mass ratio of 30/70 to 100/0.

9. A sheet comprising the block copolymer composition of claim 1 .

10. A sheet comprising the resin composition of claim 8 .

11. A container comprising the block copolymer composition of claim 1 .

12. A container comprising the resin composition of claim 8 .

13. A container comprising the sheet of claim 9 .

14. A resin composition comprising the block copolymer composition of claim 4 and a vinyl aromatic hydrocarbon polymer at a mass ratio of 30/70 to 100/0.

Assignees

• Denki Kagaku Kogyo Kk
• Denka Company Ltd

Inventors

• Sawasato Tadashi
• Sato Eiji
• Nakazawa Hitoshi
• Uekusa Shinya

Classifications

• C08K5/20

  Carboxylic acid amides · CPC title

• B32B2307/546

  Flexural strength; Flexion stiffness · CPC title

• Y10T428/1328

  Shrinkable or shrunk [e.g., due to heat, solvent, volatile agent, restraint removal, etc.] · CPC title

• C08L2201/10

  Transparent films; Clear coatings; Transparent materials · CPC title

• C08L2205/03

  containing three or more polymers in a blend · CPC title