Hydrogenated block copolymer and method for producing same
US-2015197588-A1 · Jul 16, 2015 · US
US9732179B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9732179-B2 |
| Application number | US-201615189233-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jun 22, 2016 |
| Priority date | Jun 23, 2015 |
| Publication date | Aug 15, 2017 |
| Grant date | Aug 15, 2017 |
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Disclosed herein are highly active dilithio initiators prepared from high molecular weight dienes (C≧6) and methods for the preparation of such compounds. These dilithio initiators result in greater control over polymer microstructure and provide useful polymers and oligomers with low vinyl incorporation.
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What is claimed is: 1. A composition comprising: lithium, a solvent or solvent mixture, and a compound represented by the following formula I: wherein n is 1 or 2. 2. The composition of claim 1 , wherein the composition further comprises a catalyst. 3. The composition of claim 1 , wherein the solvent is a nonpolar hydrocarbon solvent. 4. The composition of claim 1 , wherein the solvent mixture is a blend of a nonpolar hydrocarbon solvent and a polar solvent. 5. The composition of claim 4 , wherein the solvent mixture comprises about 0.5% by weight to about 5% by weight of the polar solvent. 6. The composition of claim 1 , wherein the lithium is lithium metal. 7. The composition of claim 2 , wherein the catalyst is naphthalene. 8. The composition of claim 7 , wherein the catalyst further comprises a lithium alcoholate. 9. The composition of claim 8 , wherein the lithium alcoholate is lithium 2-butanolate. 10. The composition of claim 1 , wherein formula I is beta-farnesene. 11. The composition of claim 1 , wherein formula I is beta-myrcene.
Polymerisation using regulators, e.g. chain terminating agents {, e.g. telomerisation} · CPC title
with conjugated dienes · CPC title
Butadiene · CPC title
Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds; Compositions of derivatives of such polymers (C08L45/00 takes precedence; of conjugated diene rubbers C08L9/00 - C08L21/00) · CPC title
Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds; Adhesives based on derivatives of such polymers (C09J145/00 takes precedence; based on conjugated diene rubbers C09J109/00 - C09J121/00) · CPC title
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