Production of aromatics from methanol and co-feeds

Patent metadata

Field	Value
Publication number	US-9732013-B2
Application number	US-201514829399-A
Country	US
Kind code	B2
Filing date	Aug 18, 2015
Priority date	Sep 30, 2014
Publication date	Aug 15, 2017
Grant date	Aug 15, 2017

Abstract

Methods are provided for improving the yield of aromatics during conversion of oxygenate feeds. An oxygenate feed can contain a mixture of oxygenate compounds, including one or more compounds with a hydrogen index of less than 2, so that an effective hydrogen index of the mixture of oxygenates is between about 1.4 and 1.9. Methods are also provided for converting a mixture of oxygenates with an effective hydrogen index greater than about 1 with a pyrolysis oil co-feed. The difficulties in co-processing a pyrolysis oil can be reduced or minimized by staging the introduction of pyrolysis oil into a reaction system. This can allow varying mixtures of pyrolysis oil and methanol, or another oxygenate feed, to be introduced into a reaction system at various feed entry points.

First claim

What is claimed is:

1. A method for converting oxygenates to aromatics comprising:
exposing an oxygenate feed comprising oxygenates and having an effective hydrogen index of about 1.5 to about 1.8 to an aromatization catalyst under effective conversion conditions to convert the oxygenates in the feed to one or more aromatic compounds to form a conversion effluent, wherein the oxygenate feed contains 5 wt. % or less of carbon-containing compounds different from CO and CO 2 that have a hydrogen index of 1 or less, and wherein said aromatization catalyst comprises a ZSM-5 zeolite having a ratio of silicon to aluminum of 0.05 to 0.5 and at least one metal from Groups 8-14 of the Periodic Table.

2. The method of claim 1 , wherein the oxygenate feed consists essentially of ketones, alcohols, C 3 + aldehydes, and combinations thereof.

3. The method of claim 2 , wherein the alcohols consist essentially of methanol, ethanol, propanol, n-butanol, and combinations thereof.

4. The method of claim 1 , wherein the feed contains 1 wt. % or less of carbon-containing compounds different from CO and CO 2 that have a hydrogen index of 1 or less.

5. The method of claim 1 , wherein the feed comprises acetone, n-butanol, and ethanol.

6. The method of claim 1 , wherein the feed consists essentially of acetone, n-butanol, and ethanol.

7. The method of claim 1 , wherein the feed is substantially free of carboxylic acids.

8. The method of claim 1 , wherein the at least one element from Groups 8-14 is selected from the group consisting of Zn, Ga, Ag and combinations thereof.

Assignees

• Exxonmobil Chemical Patents Inc

Inventors

• Buchanan John S
• Brown Stephen H
• Decaul Lorenzo C
• Loveless Brett T
• Vijay Rohit
• Mccarthy Stephen J
• Daage Michel
• Shekhar Mayank

Classifications

• C07C1/20 Primary

  starting from organic compounds containing only oxygen atoms as heteroatoms · CPC title

• C07C1/2076

  by a transformation in which at least one -C(=O)- moiety is eliminated · CPC title

• C10G3/49

  containing crystalline aluminosilicates, e.g. molecular sieves · CPC title

• C10G2400/30

  Aromatics · CPC title

• C07C15/00

  Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts · CPC title