Integrated process for the preparation of olefins

Patent metadata

Field	Value
Publication number	US-9732011-B2
Application number	US-201314412697-A
Country	US
Kind code	B2
Filing date	Jul 1, 2013
Priority date	Jul 5, 2012
Publication date	Aug 15, 2017
Grant date	Aug 15, 2017

Abstract

The present invention provides an integrated process for the preparation of olefins, which process comprises the steps of:
(a) reacting an oxygenate and/or olefinic feed in a reactor to form an effluent which comprises olefins; (b) fractionating at least part of the effluent into two olefinic product fractions; (c) subjecting a hydrocarbon feedstock in a reactor to a steam cracking process to form an effluent which comprises olefins including butadiene; (d) combining at least part of the first olefinic product fraction as obtained in step (b) and at least part of the second effluent which comprises olefins as obtained in step (c) to form a combined olefinic product stream comprising at least ethylene, propylene and butadiene; and (e) separating at least part of the combined olefinic product stream as obtained in step (d) to form a fraction comprising ethylene and/or propylene and a fraction that comprises butadiene.

First claim

That which is claimed is:

1. An integrated process for the preparation of olefins, which process comprises the steps of:
(a) reacting an oxygenate feed in a first reactor in the presence of a molecular sieve catalyst to form a first effluent which comprises olefins;
(b) fractionating at least part of the first effluent into a first olefinic product fraction comprising at least ethylene and propylene and a second olefinic product fraction which comprises olefins containing 4 or more carbon atoms;
(c) subjecting a paraffin-containing hydrocarbon feedstock in a second reactor to a steam cracking process to form a second effluent which comprises olefins, including butadiene;
(d) combining at least part of the first olefinic product fraction as obtained in step (b) and at least part of the second effluent which comprises olefins as obtained in step (c) to form a combined olefinic product stream comprising at least ethylene, propylene and a C4 hydrocarbon fraction comprising butadiene; and
(e) subjecting at least part of the combined olefinic product stream as obtained in step (d) to one or more product separation treatments to form at least a product fraction which comprises ethylene and/or propylene and a C4 hydrocarbon product fraction that comprises butadiene wherein the first effluent as obtained in step (a) comprises less than 6.0 wt % butadiene, based on the total weight of hydrocarbons containing 4 carbon atoms present in the first effluent.

2. The process according to claim 1 , wherein step (b) is carried out by passing the first effluent to separation section comprising a depropaniser unit and the first olefinic product fraction is retrieved as the top fraction of the depropaniser unit.

3. The process according to claim 1 , wherein at least part of the second olefinic product fraction is recycled to step (a).

4. The process according to claim 1 , wherein at least part of the second olefinic product fraction is provided to an olefin cracking process.

5. The process according to claim 1 , wherein the C4 hydrocarbon product fraction that comprises butadiene as obtained in step (e) is subjected to a butadiene extraction treatment to form a butadiene-enriched product stream and butadiene-depleted product stream.

6. The process according to claim 1 , wherein the C4 hydrocarbon product fraction that comprises butadiene as obtained in step (e) contains in the range of from 30 to 60 wt % butadiene, based on the total weight of hydrocarbons containing 4 carbon atoms present in the product fraction that comprises butadiene.

7. The process according to claim 1 , wherein the molecular sieve catalyst in step (a) comprises a MFI or MEL zeolite.

8. The process according to claim 1 , wherein the oxygenate feed in step (a) comprises methanol and/or dimethylether.

9. The process according to claim 1 , wherein the paraffin-containing hydrocarbon feedstock comprises at least one of ethane, propane, butane and/or at least one of a naphtha, kerosene, gasoil or hydrowax.

10. The process according to claim 1 , wherein the reaction in step (a) is conducted at a temperature from 350 to 750° C. Previously.

11. The process according to claim 1 , wherein the steam cracking process in step (c) is conducted at a temperature from 750 to 920° C.

12. The process according to claim 1 , wherein the first effluent as obtained in step (a) comprises less than 5.0 wt % butadiene, based on the total weight of hydrocarbons containing 4 carbon atoms present in the first effluent.

Assignees

• Shell Oil Co

Inventors

• Ramesh Rajaram

Classifications

• Y02P20/125

  Cross-Sectional Technologies · mapped topic

• C07C11/06

  Propene · CPC title

• C07C2529/40

  of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 · CPC title

• C07C1/20 Primary

  starting from organic compounds containing only oxygen atoms as heteroatoms · CPC title

• C10G3/49

  containing crystalline aluminosilicates, e.g. molecular sieves · CPC title