Methods and apparatuses for regenerating catalyst particles

Patent metadata

Field	Value
Publication number	US-9731287-B2
Application number	US-201414470840-A
Country	US
Kind code	B2
Filing date	Aug 27, 2014
Priority date	Aug 27, 2014
Publication date	Aug 15, 2017
Grant date	Aug 15, 2017

Abstract

Apparatuses and methods are provided for regenerating catalyst particles. In one embodiment, a method for regenerating catalyst particles includes passing the catalyst particles through a halogenation zone and a drying zone. The method feeds drying gas to the drying zone and passes a first portion of the drying gas from the drying zone to the halogenation zone. The method includes removing a second portion of the drying gas from the drying zone and injecting a halogen gas into the second portion of the drying gas. Further, the method includes delivering the halogen gas and the second portion of the drying gas to the halogenation zone. In the method, substantially all of the drying gas fed to the drying zone enters the halogenation zone.

First claim

What is claimed is:

1. A method for regenerating catalyst particles, the method comprising the steps of:
passing the catalyst particles through a halogenation zone and a drying zone, the halogenation zone and the drying zone being located in a vessel;
feeding drying gas to the drying zone;
passing a first portion of the drying gas from the drying zone to the halogenation zone;
removing a second portion of the drying gas from the drying zone;
passing the second portion of the drying gas through an external tunnel, outside of the vessel, and reconnecting to the vessel at the halogenation zone;
injecting a halogen gas into the external tunnel into the second portion of the drying gas; and
delivering the halogen gas and the second portion of the drying gas from the external tunnel to the halogenation zone, wherein substantially all of the drying gas fed to the drying zone enters the halogenation zone.

2. The method of claim 1 , wherein removing the second portion of the drying gas from the drying zone comprises removing the second portion of the drying gas from the vessel.

3. The method of claim 2 wherein delivering the halogen gas and the second portion of the drying gas to the halogenation zone comprises delivering the halogen gas and the second portion of the drying gas to the vessel.

4. The method of claim 1 wherein the external tunnel is formed with an elbow forming an acute angle, and wherein passing the second portion of the drying gas through the external tunnel comprises mixing the second portion of the drying gas and the halogen gas by passing the second portion of the drying gas and the halogen gas through the elbow.

5. The method of claim 1 wherein the external tunnel is formed with an elbow forming an angle of less than about 60 degrees, and wherein passing the second portion of the drying gas through the external tunnel comprises mixing the second portion of the drying gas and the halogen gas by passing the second portion of the drying gas and the halogen gas through the elbow.

6. The method of claim 3 wherein:
removing the second portion of the drying gas comprises removing the second portion of the drying gas from the vessel at a removal location;
delivering the halogen gas and the second portion of the drying gas comprises delivering the halogen gas and the second portion of the drying gas to the vessel at a delivery location distanced from the removal location by a first distance (D), and
the method comprises passing the second portion of the drying gas through an external tunnel from the removal location to the delivery location, wherein the external tunnel has a flow path length (L) less than about 2 times the first distance (L<2D).

7. The method of claim 3 wherein:
removing the second portion of the drying gas comprises removing the second portion of the drying gas from the vessel at a removal location;
delivering the halogen gas and the second portion of the drying gas comprises delivering the halogen gas and the second portion of the drying gas to the vessel at a delivery location distanced from the removal location by a first distance (D), and
the method comprises passing the second portion of the drying gas through an external tunnel from the removal location to the delivery location, wherein the external tunnel has a flow path length (L) less than about 4 times the first distance (L<4D).

8. The method of claim 1 wherein:
passing the first portion of the drying gas from the drying zone to the halogenation zone comprises passing about 5 to about 20 wt. % of the drying gas from the drying zone to the halogenation zone; and
removing the second portion of the drying gas from the drying zone comprises removing about 80 to about 95 wt. % of the drying gas from the drying zone.

9. The method of claim 1 wherein:
passing the first portion of the drying gas from the drying zone to the halogenation zone comprises passing about 10 wt. % of the drying gas from the drying zone to the halogenation zone; and
removing the second portion of the drying gas from the drying zone comprises removing about 90 wt. % of the drying gas from the drying zone.

10. The method of claim 1 further comprising:
passing the drying gas through the drying zone at a first flow rate; and
passing the drying gas and halogen gas through the halogenation zone at a second flow rate, wherein the second flow rate: first flow rate ratio is less than about 1.

11. The method of claim 1 wherein injecting the halogen gas into the second portion of the drying gas comprises injecting organic chloride into the second portion of the drying gas.

12. The method of claim 1 wherein injecting the halogen gas into the second portion of the drying gas comprises injecting organic chloride at a temperature of about 150° C. to about 400° C. into the second portion of the drying gas.

Assignees

• Uop Llc

Inventors

• Lok Ka
• Ozmen Jennifer J
• Yanez William
• Wier Mary
• Gaicki Richard

Classifications

• B01J8/125

  with multiple sections one above the other separated by distribution aids, e.g. reaction and regeneration sections · CPC title

• B01J38/44 Primary

  and adding simultaneously or subsequently free oxygen; using oxyhalogen compound · CPC title

• B01J8/28

  the one above the other · CPC title

• B01J38/18

  with subsequent reactive gas treating · CPC title

• B01J27/13

  Platinum group metals · CPC title