Means for manufacturing micro-beads comprising thermoplastic polymer micro-particles

Patent metadata

Field	Value
Publication number	US-9731260-B2
Application number	US-201214239029-A
Country	US
Kind code	B2
Filing date	Jul 24, 2012
Priority date	Aug 15, 2011
Publication date	Aug 15, 2017
Grant date	Aug 15, 2017

Abstract

The present invention relates to means for manufacturing micro-beads (polymer micro-particles) comprising thermoplastic polymer and having the average particle size of 10 μm or less, and extending into the nano-range. An original filament comprising a thermoplastic polymer is passed through an orifice under an air pressure (P1) and guided to a spray chamber under a pressure (P2; where P1>P2). The original filament having passed through the orifice is heated and melted under irradiation by an infrared beam, and is sprayed in microparticulate form from the orifice by the flow of air generated by the pressure differential between P1 to P2, whereby micro-beads comprising thermoplastic polymer micro-particles having an average particle size of 10 μm or less, and even less than 1 μm are manufactured.

First claim

What is claimed is:

1. A method of manufacturing micro-beads comprising thermoplastic micro-particles with an average particle size of 10 μm or smaller, the method comprising:
transferring an original filament comprising a thermoplastic polymer under a pressure P1
through an orifice and into a spray chamber under a pressure P2, wherein P1>P2;
irradiating the original filament that passed through the orifice in the spray chamber using an infrared beam; and
spraying the melted filament into microparticles using a gas flow generated by the pressure differential between P1 and P2, wherein the micro-beads have an average particle size of less than 1 μm.

2. The method according to claim 1 , wherein the original filament is heat treated while the original filament is introduced into the orifice.

3. A method of manufacturing micro-beads comprising thermoplastic micro-particles with an average particle size of 10 μm or smaller, the method comprising:
transferring an original filament comprising a thermoplastic polymer under a pressure P1
through an orifice and into a spray chamber under a pressure P2, wherein P1>P2;
irradiating the original filament that passed through the orifice in the spray chamber using an infrared beam; and
spraying the melted filament into microparticles using a gas flow generated by the pressure differential between P1 and P2, wherein the original filament has a degree of crystallization of at least 25% according to differential scanning calorimetric (DSC) measurements.

4. The method according to claim 1 , wherein the microparticles and the drawn filament obtained as a byproduct along with the microparticles are accumulated on a filter inside a vacuum chamber.

5. The method according to claim 4 , wherein the filter forms a conveyer that circulates the filter.

6. A method of manufacturing micro-beads comprising thermoplastic micro-particles with an average particle size of 10 μm or smaller, the method comprising:
transferring an original filament comprising a thermoplastic polymer under a pressure P1
through an orifice and into a spray chamber under a pressure P2, wherein P1>P2;
irradiating the original filament that passed through the orifice in the spray chamber using an infrared beam; and
spraying the melted filament into microparticles using a gas flow generated by the pressure differential between P1 and P2, wherein P1 is atmospheric pressure and P2 is reduced pressure.

7. The method to claim 1 , wherein the infrared beam is a carbon dioxide laser beam.

8. The method according to claim 1 , wherein the center of the infrared beam irradiates the original filament within 30 mm of the orifice exit.

9. The method according to claim 1 , wherein the infrared beam irradiates the original filament center within 4 mm along a filament axis direction.

10. The method according to claim 1 , comprising subjecting the micro-beads to a heat treatment at a temperature at or above a softening point of the micro-beads and yet at or below a melting point of the thermoplastic polymer.

Assignees

• Suzuki Akihiro
• Univ Yamanashi

Inventors

• Suzuki Akihiro

Classifications

• B29C2035/0822

  using IR radiation · CPC title

• B01J2/04 Primary

  in a gaseous medium {(if combined with suspending the material in a gas, e.g. fluidised beds B01J2/16)} · CPC title

• B29C35/045

  using gas or flames · CPC title

• B29B9/10 Primary

  by moulding the material, i.e. treating it in the molten state · CPC title

• B29B9/06

  in the form of filamentary material, e.g. combined with extrusion · CPC title