Ultra-high specific energy cathode materials for lithium-ion batteries and methods for producing the same
US-2024186483-A1 · Jun 6, 2024 · US
US9728827B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9728827-B2 |
| Application number | US-201314374109-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jan 21, 2013 |
| Priority date | Jan 27, 2012 |
| Publication date | Aug 8, 2017 |
| Grant date | Aug 8, 2017 |
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Each air battery stacked in a battery pack includes a cathode layer, an anode layer, an electrolyte layer and a frame member having electrical insulation properties and surrounding at least outer circumferences of the electrolyte layer and the cathode layer. The cathode layer includes a fluid-tight air-permeable member located at a cathode surface thereof and having, when viewed in plan, an outer circumferential edge portion situated outside of the outer circumference of the electrolyte layer. The frame member includes a holding portion located a cathode side thereof so as to hold the outer circumferential edge portion of the fluid-tight air-permeable member. The outer circumferential edge portion of the fluid-tight air-permeable member is adapted as a compressed region to which a compressive load is applied in a thickness direction thereof. By this structure, it is possible to achieve both of thickness reduction and high electrolyte sealing performance.
Opening claim text (preview).
The invention claimed is: 1. A battery pack comprising a plurality of air batteries stacked together, each of the plurality of air batteries comprising: a cathode layer, an anode layer, and an electrolyte layer interposed between the cathode layer and the anode layer, wherein the cathode layer includes a fluid-tight air-permeable member located at a cathode surface thereof and having, when viewed in plan, an outer circumferential edge portion situated outside of an outer circumference of the electrolyte layer, wherein the anode layer includes an anode collector; and a frame member having electrical insulation properties and surrounding at least outer circumferences of the electrolyte layer and the cathode layer, wherein the frame member includes a holding portion located on a cathode side thereof so as to hold the outer circumferential edge portion of the fluid-tight air-permeable member, wherein the fluid-tight air-permeable member is electrically conductive, wherein the holding portion of the frame member has a height slightly smaller than a thickness of the fluid-tight air-permeable member in a free state thereof so that, when the batteries are stacked, the outer circumferential edge portion of the fluid-tight air-permeable member is compressed in a thickness direction thereof and has one side held in direct contact with the holding portion of the frame member and the other side held in direct contact with the anode collector of the other adjacent battery so as to provide seal between the batteries. 2. The battery pack according to claim 1 , wherein the each of the plurality of air batteries has a protrusion on either the holding portion of the frame member or anode-side part of the air battery opposite the holding portion of the frame member. 3. The battery pack according to claim 1 , wherein the holding portion of the frame member has a surface inclined downward toward an inside of the frame member. 4. The battery pack according to claim 1 , wherein the anode collector is formed with a wavy cross section or a plurality of protrusions on an anode surface of the anode layer; and wherein the anode collector has a protrusion formed on a portion thereof opposite the holding portion of the frame member. 5. The battery pack according to claim 1 , wherein the fluid-tight air-permeable member includes a gas flow path forming part disposed at a surface thereof so as to form a gas flow path; and wherein the gas flow path forming part includes a press portion to apply the compressive load to the compressed region of the fluid-tight air-permeable member. 6. The battery pack according to claim 1 , wherein the fluid-tight air-permeable member contains a catalyst; and wherein an amount of the catalyst in the outer circumferential edge portion of the fluid-tight air-permeable member is smaller than an amount of the catalyst in a body portion of the fluid-tight air-permeable member. 7. The battery pack according to claim 1 , wherein the fluid-tight air-permeable member contains a catalyst; and wherein an amount of the catalyst in an outer part of the fluid-tight air-permeable member is smaller than an amount of the catalyst in an inner part of the fluid-tight air-permeable member with respect to a thickness direction. 8. The battery pack according to claim 1 , wherein the cathode layer of one of the plurality of air batteries is in direct contact with the anode layer of another one of the plurality of air batteries adjacent to said one of the plurality of air batteries. 9. The battery pack according to claim 1 , wherein the fluid-tight air-permeable member is formed of a conductive porous material. 10. The battery pack according to claim 1 , wherein the fluid-tight air-permeable member is formed in one piece.
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