Electrochemical sensor and method of using same

Patent metadata

Field	Value
Publication number	US-9726627-B2
Application number	US-201414166513-A
Country	US
Kind code	B2
Filing date	Jan 28, 2014
Priority date	Jan 28, 2014
Publication date	Aug 8, 2017
Grant date	Aug 8, 2017

Abstract

A chemical sensor may include an electrode array for electrically interfacing with a fluid sample. The sensor can apply an electrical potential to the sample in order to effect a current flow within the sample. The sensor can measure the resulting current through the sample and determine characteristics about the fluid sample from the current measurement. In one mode of operation of the sensor, the applied electrical potential can be controlled to cause desired electrochemical reactions, such as oxidation or reduction, to occur within the sample to determine the concentration of the oxidized or reduced sample constituent. In another mode of operation, the applied electrical potential causes a current to flow simply due to the conductivity of the sample. In various embodiments, the sensor comprises a controller and a switch for switching between various modes of operation and applying appropriate electric potentials to the sample.

First claim

The invention claimed is:

1. A fluid analysis system including a sensor, the sensor comprising:
a non-conductive housing;
first and second operational amplifier, each having an inverting input, a non-inverting input, and an output;
an electrode array for interfacing with a fluid sample and mounted in a first face of the non-conductive housing, the electrode array comprising:
a first electrode coupled to output of the first operational amplifier,
a second electrode coupled to the inverting input of the first operational amplifier,
a third electrode coupled to the inverting input of the second operational amplifier, and
a fourth electrode, the electrode array arranged in a line and configured such that the second electrode is between the first electrode and the fourth electrode, and the third electrode is between the second electrode and the fourth electrode;

a switch coupled to the output of the second operational amplifier and comprising a first position and a second position, such that
in the first position, the switch couples the output of the second operational amplifier to the fourth electrode; and
in the second position, the switch couples the output of the second operational amplifier to the third electrode;

a sense resistor coupled between either (a) the output of the first operational amplifier and the first electrode or (b) the output of the second operational amplifier and the switch;
a switching mechanism for (i) connecting the non-inverting input of one of the first operational amplifier and the second operational amplifier to a first voltage source, defining a powered amplifier, and (ii) connecting the non-inverting input of the other of the one of the first operational amplifier and the second operational amplifier to a second voltage source, defining a reference amplifier; and
a differential amplifier configured to output an electrical signal corresponding to a current flowing through the sense resistor.

2. The system of claim 1 , further comprising a temperature sensor disposed in and electrically isolated from one of the first electrode, the second electrode, the third electrode, or the fourth electrode for measuring the temperature of a sample proximate the one of the first, second, third and fourth electrodes.

3. The system of claim 2 , wherein the one of the first electrode, the second electrode, the third electrode, or the fourth electrode that contains the temperature sensor comprises a bore opposite the first face for receiving the temperature sensor.

4. The system of claim 3 , wherein the bore does not extend entirely through the one of the first electrode, the second electrode, the third electrode, or the fourth electrode that contains the temperature sensor, such that the temperature sensor, when disposed in the bore, is not exposed to the fluid sample when the first face of the sensor is disposed therein.

5. The system of claim 1 , wherein the separation distance between each pair of adjacent electrodes in the electrode array is substantially the same.

6. The system of claim 1 wherein the first, second, third and fourth electrodes are flush with the first face of the sensor housing.

7. The system of claim 1 , wherein the first, second, third and fourth electrodes comprise at least one of gold, platinum, stainless steel, boron-doped diamond, glassy carbon or graphite.

8. The system of claim 1 , further comprising a controller in communication with the sensor for determining at least one parameter of a fluid sample.

9. The system of claim 8 , wherein the controller is embedded in the sensor housing.

10. The system of claim 9 , wherein the controller is configured to:
(i) send control signals to the sensor defining the powered amplifier and the reference amplifier;
(ii) position the switch in either the first or second position;
(iii) set the output level of the voltage sources;
(iv) receive an output signal from the differential amplifier; and
(v) determine at least one parameter of the fluid sample from the received output signal.

11. The system of claim 10 , further comprising a user interface in communication with the controller.

12. The system of claim 1 , wherein the differential amplifier has a built-in output offset.

13. The system of claim 1 , wherein the sensor further includes an optical sensor; and
the first face of the non-conductive housing further comprises a lens for emitting light from and receiving light into the non-conductive housing of the sensor.

Assignees

• Ecolab Usa Inc

Inventors

• Banks Rodney H

Classifications

• G01N27/06

  of a liquid (involving electrolysis G01N27/26) · CPC title

• G01N25/00 Primary

  Investigating or analyzing materials by the use of thermal means (G01N3/00 - G01N23/00 take precedence) · CPC title

• C01B11/06

  Hypochlorites · CPC title

• G01N33/18

  Water · CPC title

• G01N27/30 Primary

  Electrodes, e.g. test electrodes; Half-cells (G01N27/414 takes precedence) · CPC title