Open and closed cell polyurea foams

Patent metadata

Field	Value
Publication number	US-9725897-B2
Application number	US-201514661757-A
Country	US
Kind code	B2
Filing date	Mar 18, 2015
Priority date	Mar 18, 2015
Publication date	Aug 8, 2017
Grant date	Aug 8, 2017

Abstract

An open cell spray polyurea foam for use in an insulation layer in a wall structure may include a polyurea. The polyurea may be a reaction product of an isocyanate compound and water. The open spray polyurea foam may also include a filler. The majority of the filler may exist in the spray foam formulation as an unreacted first fire retardant. The spray foam formulation may further comprise a second fire retardant, and the insulation layer may exhibit a fire retardancy sufficient to pass Appendix X and/or ASTM E-84.

First claim

What is claimed is:

1. An open cell spray polyurea foam for use in an insulation layer in a wall structure, the open cell spray polyurea foam comprising:
a polyurea, wherein the polyurea is a reaction product of an isocyanate compound and water; and
a fire retardant, wherein the fire retardant does not react with the isocyanate compound.

2. The open cell spray polyurea foam of claim 1 , wherein the fire retardant is a first fire retardant, and the open cell spray polyurea foam further comprises a second fire retardant.

3. The open cell spray polyurea foam of claim 1 , wherein the fire retardant is a first fire retardant, and the open cell spray polyurea foam further comprises a second fire retardant, wherein the second fire retardant reacts with the isocyanate compound.

4. The open cell spray polyurea foam of claim 3 , wherein the second fire retardant is a halogenated polyol.

5. The open cell spray polyurea foam of claim 1 , wherein the fire retardant is water soluble and does not react with isocyanate.

6. The open cell spray polyurea foam of claim 5 , wherein the fire retardant is a saccharide.

7. The open cell spray polyurea foam of claim 5 , wherein the fire retardant is sucrose.

8. The open cell spray polyurea foam of claim 7 , wherein in at least 80 weight percent of the sucrose exists in the open cell spray polyurea foam as an unreacted filler.

9. The open cell spray polyurea foam of claim 2 , wherein at least 80 weight percent of the first fire retardant and 80 weight percent of the second fire retardant exist in the open cell spray polyurea foams as unreacted fillers.

10. The open cell spray polyurea foam of claim 5 , wherein the fire retardant is high fructose corn syrup.

11. The open cell spray polyurea foam of claim 1 , wherein the fire retardant is insoluble in water and does not react with isocyanate.

12. The open cell spray polyurea foam of claim 11 , wherein the fire retardant is ammonium polyphosphate.

13. The open cell spray polyurea foam of claim 11 , wherein the fire retardant is melamine.

14. The open cell spray polyurea foam of claim 1 , wherein:
the fire retardant is a first fire retardant, and
the first fire retardant is water soluble and does not react with isocyanate, and
further comprising a second fire retardant, wherein the second fire retardant is insoluble in water and does not react with isocyanate.

15. The open cell spray polyurea foam of claim 1 , wherein the insulation layer exhibits a fire retardancy sufficient to pass a flame test in accordance with ASTM E-84.

16. The open cell spray polyurea foam of claim 1 , wherein the insulation layer has an insulative R value of 3.0 to 5.0 per inch and a density of between about 0.3 to about 0.7 pcf.

17. The open cell spray polyurea foam of claim 1 , wherein the insulation layer has a density of between about 0.7 to about 1.5 pcf.

18. The open cell spray polyurea foam of claim 6 , further comprising a non-halogenated fire retardant.

19. The open cell spray polyurea foam of claim 6 , further comprising a halogenated fire retardant.

20. The open cell spray polyurea foam of claim 19 , wherein the halogenated fire retardant is tris(1-chloro-2-propyl)phosphate.

21. The open cell spray polyurea foam of claim 19 , wherein the halogenated fire retardant comprises at least one of a brominated diol, a brominated triol, and chlorinated phosphate.

22. The open cell spray polyurea foam of claim 6 , wherein the fire retardant is a first fire retardant, and
further comprising a second fire retardant, wherein the second fire retardant comprises an organo phosphorous compound.

23. The open cell spray polyurea foam of claim 22 , wherein the organo phosphorous compound is selected from the group consisting of an organo-phosphate, an organo-phosphite, and an organo-phosphonate.

24. The open cell spray polyurea foam of claim 22 , wherein the organo phosphorous compound comprises triethyl phosphate.

25. The open cell spray polyurea foam of claim 22 , wherein the second fire retardant comprises a blend of butyl diphenyl phosphate, dibutyl phenyl phosphate, and triphenyl phosphate.

26. The open cell spray polyurea foam of claim 22 , wherein the organo phosphorous compound comprises diethyl hydroylmethyl phosphonate.

27. The open cell spray polyurea foam of claim 1 , further comprising a catalyst.

28. The open cell spray polyurea foam of claim 1 , wherein the open cell spray polyurea foam has a tensile strength is between about 3 psi and about 10 psi, and the open cell spray polyurea foam has a closed cell content is less than 10%.

29. An insulated structure, comprising:
a plurality of structural support members coupled together to form a frame;
a plurality of wall boards attached to an exterior side of the frame to form an exterior wall or surface of the structure, wherein the plurality of structural support members and the plurality of wall boards define a wall cavity of the structure; and
a spray foam insulation positioned within the wall cavity of the structure, the spray foam insulation comprising a spray foam made from a formulation that comprises:
polyurea, wherein the polyurea is a reaction product of an isocyanate compound and water,
a first fire retardant, wherein a majority of the first fire retardant exists in the spray foam insulation as an unreacted filler and the first fire retardant does not react with the isocyanate compound, and
a second fire retardant,

wherein the spray foam is an open cell spray foam.

30. The insulated structure of claim 29 , wherein the spray foam has an insulative R-value from 3.0 to 5.0 per inch and a density of between about 0.3 pcf and about 0.7 pcf.

31. A method of insulating a component of a building, comprising:
coupling a plurality of structural support members together to form a frame;
attaching a plurality of first wall boards to an exterior side of the frame to form an exterior wall or surface of the structure;
attaching a plurality of second wall boards to an interior side of the frame to form an interior wall or surface of the structure, wherein the structural support members, the first wall boards, and the second wall boards define a plurality of wall cavities; and
 positioning a spray insulation material within at least one of the wall cavities of the structure to insulate an interior space of the structure, wherein the spray insulation material comprises a spray foam made from a spray foam formulation that comprises:
polyurea, wherein the polyurea is a reaction product of an isocyanate compound and water;
a first fire retardant, wherein a majority of the first fire retardant exists in the spray foam formulation as an unreacted filler and the first fire retardant does not react with the isocyanate compound; and
a second fire retardant;
wherein the spray foam comprises an open cell spray foam.

32. The method of insulating a structure of claim 31 , wherein the spray foam has an insulative R value of 3.0 to 5.0 per inch and a density of between about 0.3 to about 0.7 pcf.

33. The insulated structure of claim 29 , wherein the insulation layer exhibits a fire retardancy sufficient to pass a flame test in accordance with ASTM E-84.

34. The method of insulating a structure of claim 31 , wherein the insulation laye

Assignees

• Johns Manville

Inventors

• Snider Scott
• Wang Lance
• Asrar Jawed

Classifications

• C08J2205/052

  Closed cells, i.e. more than 50% of the pores are closed · CPC title

• E04B1/7604 Primary

  fillings for cavity walls · CPC title

• C08G18/00

  Polymeric products of isocyanates or isothiocyanates · CPC title

• C08J2375/02

  Polyureas · CPC title

• C08J2207/04

  Aerosol, e.g. polyurethane foam spray · CPC title