Methods for incorporating ultraviolet light absorbing compounds into anodic oxides

Patent metadata

Field	Value
Publication number	US-9725819-B2
Application number	US-201414161482-A
Country	US
Kind code	B2
Filing date	Jan 22, 2014
Priority date	Sep 30, 2013
Publication date	Aug 8, 2017
Grant date	Aug 8, 2017

Abstract

The embodiments described herein relate to anodic oxides and methods for forming anodic oxides. The methods involve incorporating an ultraviolet (UV) light absorbing compounds into anodic oxides to prevent color fading of the anodic oxides caused by exposure to UV light. In some embodiments, the UV light absorbing compound includes para-aminobenzoic acid (PABA). The UV light absorbing compound can be incorporated within the anodic oxide during a sealing process. The UV light absorbing compound becomes infused within a seal layer, which is formed during the sealing process. The resultant anodic oxide has a UV light absorbing seal layer that can block UV light from reaching any underlying colorant existing within the anodic oxide.

First claim

What is claimed is:

1. A method of forming a part having a color fade resistant anodic oxide disposed over a substrate, the method comprising:
depositing a colorant within pores of the color fade resistant anodic oxide;
forming a first seal layer having an ultraviolet (UV) light absorbing compound incorporated within a metal oxide hydrate of the first seal layer, wherein the UV light absorbing compound comprises at least one of a para-aminobenzoic acid (PABA), a benzophenone, a benzotriazole, or a hindered amine compound; and
forming a second seal layer positioned on the first seal layer, wherein the second seal layer is free of the UV light absorbing compound.

2. The method as recited in claim 1 , wherein the second seal layer has an external surface corresponding to an external surface of the color fade resistant anodic oxide.

3. The method as recited in claim 1 , wherein the metal oxide hydrate has a nickel hydroxide precipitate incorporated therein.

4. The method as recited in claim 1 , wherein forming the second seal layer comprises exposing the anodic oxide to a solution comprising a metal salt.

5. The method as recited in claim 4 , wherein a metal hydroxide precipitate of the metal salt becomes infused within the second seal layer.

6. The method as recited in claim 1 , wherein the UV light absorbing compound is substantially transparent to visible wavelengths of light.

7. The method as recited in claim 1 , wherein the UV light absorbing compound does not substantially chemically react with the colorant.

8. The method as recited in claim 1 , wherein the UV light absorbing compound modifies light absorbing properties of the colorant.

9. The method as recited in claim 1 , wherein the UV light absorbing compound comprises para-aminobenzoic acid (PABA).

10. A part having a color fade resistant anodic oxide disposed over a substrate, the color fade resistant anodic oxide comprising:
a colorant deposited within pores of the color fade resistant anodic oxide;
a first seal layer having an ultraviolet (UV) light absorbing compound incorporated within a metal oxide hydrate of the first seal layer, wherein the UV light absorbing compound comprises at least one of a para-aminobenzoic acid (PABA), a benzophenone, a benzotriazole, or a hindered amine compound; and
a second seal layer positioned on the first seal layer, wherein the second seal layer is free of the UV light absorbing compound.

11. The part as recited in claim 10 , wherein the second seal layer has an exterior surface corresponding to an exterior surface of the part, wherein the at least a portion of the UV light absorbing compound is positioned more proximate to the exterior surface than the colorant, thereby blocking at least a portion of UV wavelengths of light incident the exterior surface from reaching the colorant.

12. The part as recited in claim 10 , wherein the UV light absorbing compound modifies light absorbing properties of the colorant.

13. The part as recited in claim 10 , wherein the metal oxide hydrate has a nickel hydroxide precipitate incorporated therein.

Assignees

• Apple Inc

Inventors

• Runge Jude Mary
• Wieler Patrick S
• Thornton Iii John Murray
• Maloney Max A

Classifications

• C25D11/26

  of refractory metals or alloys based thereon · CPC title

• C25D11/243 Primary

  using organic dyestuffs · CPC title

• C25D11/34

  of metals or alloys not provided for in groups C25D11/04 - C25D11/32 · CPC title

• C25D11/246

  for sealing layers · CPC title

• C25D11/30

  of magnesium or alloys based thereon · CPC title