Heterogeneous metal-free catalyst

Patent metadata

Field	Value
Publication number	US-9725395-B2
Application number	US-201314650537-A
Country	US
Kind code	B2
Filing date	Dec 6, 2013
Priority date	Dec 7, 2012
Publication date	Aug 8, 2017
Grant date	Aug 8, 2017

Abstract

The inventive concepts disclosed and/or claimed herein relate generally to catalysts and, more particularly, but not by way of limitation, to a heterogeneous, metal-free hydrogenation catalyst containing frustrated Lewis pairs. In one non-limiting embodiment, the heterogeneous, metal-free catalyst comprises hexagonal boron nitride (h-BN) having frustrated Lewis pairs therein.

First claim

What is claimed is:

1. A heterogeneous hydrogenation catalyst, wherein the catalyst is selected from the group consisting of hexagonal boron nitride, substitutionally doped graphite, substitutionally doped carbon nitride, and an inorganic-organic hybrid material, the catalyst having:
a solid surface substantially free of metals, the solid surface having at least one Lewis acid site and at least one Lewis base site; and
at least one defect frustrating at least one pair of Lewis acid and Lewis base sites, wherein the at least one frustrated pair of Lewis acid and Lewis base sites is catalytically active;

wherein the Lewis acids of the inorganic-organic hybrid material are selected from the group consisting of Group 13 elements in a trigonal planar configuration, halides of Group 15 elements, electron poor π-systems, and combinations thereof, and wherein the Lewis bases of the inorganic-organic hybrid material are selected from the group consisting of simple anions, Group 15 and Group 16 lone-pair-containing species, complex anions, electron rich π-systems, and combinations thereof.

2. A heterogeneous hydrogenation catalyst, wherein the catalyst is selected from the group consisting of hexagonal boron nitride, substitutionally doped graphite, substitutionally doped carbon nitride, and an inorganic-organic hybrid material, the catalyst having:
a solid surface having non-metallic Lewis acid moieties and non-metallic Lewis base moieties spaced a distance apart from one another such that (a) catalytic activity is present therebetween and (b) the formation of an acid-base adduct is prevented;

wherein the Lewis acid moieties of the inorganic-organic hybrid material are selected from the group consisting of Group 13 elements in a trigonal planar configuration, halides of Group 15 elements, electron poor π-systems, and combinations thereof, and wherein the Lewis base moieties of the inorganic-organic hybrid material are selected from the group consisting of simple anions, Group 15 and Group 16 lone-pair-containing species, complex anions, electron rich π-systems, and combinations thereof.

3. The heterogeneous hydrogenation catalyst of claim 2 , wherein the Lewis acid moiety is a Group 13 element in a trigonal planar configuration and the Lewis base moiety is a lone-pair containing species.

4. The heterogeneous hydrogenation catalyst of claim 2 , wherein the catalyst at least partially comprises hexagonal boron nitride.

5. A heterogeneous hydrogenation catalyst, wherein the catalyst is selected from the group consisting of hexagonal boron nitride, substitutionally doped graphite, substitutionally doped carbon nitride, and an inorganic-organic hybrid material, the catalyst having:
a sheet of catalytically active material substantially free of metals having unsatisfied Lewis acid-base pairs along a surface of the sheet;

wherein the Lewis acids of the inorganic-organic hybrid material are selected from the group consisting of Group 13 elements in a trigonal planar configuration, halides of Group 15 elements, electron poor π-systems, and combinations thereof, and wherein the Lewis bases of the inorganic-organic hybrid material are selected from the group consisting of simple anions, Group 15 and Group 16 lone-pair-containing species, complex anions, electron rich π-systems, and combinations thereof.

6. The heterogeneous hydrogenation catalyst of claim 5 , wherein the catalyst comprises hexagonal boron nitride having at least one catalytically active defect on a surface thereof, wherein the hexagonal boron nitride is substantially free of metals.

7. The heterogeneous hydrogenation catalyst of claim 6 , wherein the catalytically active defect is selected from the group consisting of Stone-Wales defects, B/N defects, boron substituted nitrogen, nitrogen substituted for boron, carbon substituted for nitrogen, carbon substituted for boron, boron vacancy, nitrogen vacancy, and combinations thereof.

8. The heterogeneous hydrogenation catalyst of claim 5 , wherein the catalyst is capable of catalytically hydrogenating an alkene.

9. A method of making a hydrogenation catalyst, comprising:
mechanically processing hexagonal boron nitride in the presence of an alkali metal element or hydrogen to produce a catalytically active defect on a surface of the hexagonal boron nitride.

10. The method of claim 9 , wherein the alkali metal element is lithium.

11. The method of claim 9 , wherein the mechanical process is selected from the group consisting of grinding, sonochemical processing, and combinations thereof.

12. A hydrogenation process comprising:
contacting a hydrogenatable compound with hydrogen gas and a catalyst in a reactor, wherein the catalyst is selected from the group consisting of hexagonal boron nitride, substitutionally doped graphite, substitutionally doped carbon nitride, and an inorganic-organic hybrid material having a solid material having frustrated Lewis acid-base pairs; and
catalytically hydrogenating the hydrogenatable compound;

wherein the Lewis acids of the inorganic-organic hybrid material are selected from the group consisting of Group 13 elements in a trigonal planar configuration, halides of Group 15 elements, electron poor π-systems, and combinations thereof, and wherein the Lewis bases of the inorganic-organic hybrid material are selected from the group consisting of simple anions, Group 15 and Group 16 lone-pair-containing species, complex anions, electron rich π-systems, and combinations thereof.

13. The process of claim 12 , wherein the hydrogenatable compound is a compound having functional groups selected from the group consisting of alkene, alkyne, aldehyde, ketone, ester, imine, amide, nitrile, nitro, and combinations thereof.

14. The process of claim 12 , further wherein the solid material having frustrated Lewis pairs comprises a solid surface substantially free of metals, the solid surface having at least one Lewis acid site and at least one Lewis base site, and at least one defect frustrating at least one pair of Lewis acid and Lewis base sites, wherein the at least one frustrated pair of Lewis acid and Lewis base sites is catalytically active.

15. The process of claim 12 , further wherein the solid material having frustrated Lewis pairs comprises a solid surface having non-metallic Lewis acid moieties and non-metallic Lewis base moieties spaced a distance apart from one another such that (a) catalytic activity is present therebetween and (b) the formation of an acid-base adduct therefrom is prevented.

16. The process of claim 15 , wherein the Lewis acid moiety is a Group 13 element in a trigonal planar configuration and the Lewis base moiety is a lone-pair containing species.

17. The process of claim 15 , wherein the catalyst at least partially comprises hexagonal boron nitride.

18. The process of claim 12 , further wherein the catalyst comprises a sheet of catalytically active material substantially free of metals having unsatisfied Lewis acid-base pairs along a surface of the sheet.

19. The process of claim 12 , wherein the catalyst comprises hexagonal boron nitride having a catalytically active defect on a surface thereof, wherein the hexagonal boron nitride is substantially free of metals.

20. The process of claim 19 , wherein the catalytically active defect is selected from the group consisting of Stone-Wales defects, B/N defects, boron substituted for nitrogen, nitrogen substituted for boron, carbon substituted for nitrogen, carbon substituted for boron, boron vacancy, nitrogen va

Assignees

• Univ Central Florida Res Found Inc
• Univ Of Central Florida Res Found

Inventors

• Blair Richard G

Classifications

• B01J2235/30

  Scanning electron microscopy; Transmission electron microscopy · CPC title

• B01J2235/00

  Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties · CPC title

• C07C253/00

  Preparation of carboxylic acid nitriles (of cyanogen or compounds thereof C01C3/00) · CPC title

• B01J2231/645

  of C=C or C-C triple bonds · CPC title

• C01P2002/85

  by XPS, EDX or EDAX data · CPC title