Composition for preparing terephthalic acid

Patent metadata

Field	Value
Publication number	US-9725394-B2
Application number	US-201414787764-A
Country	US
Kind code	B2
Filing date	Apr 17, 2014
Priority date	Apr 30, 2013
Publication date	Aug 8, 2017
Grant date	Aug 8, 2017

Abstract

The present disclosure provides a composition for preparing terephthalic acid; said composition comprises p-Toluic acid in an amount of 0.05% to 4% with respect to the total mass of the composition; at least one catalyst in an amount of 0.02% to 2.5% with respect to the total mass of the composition; at least one ionic liquid in an amount of 0.04% to 50% with respect to the total mass of the composition; at least one carboxylic acid solvent; and p-xylene. The present disclosure also provides a process for preparing terephthalic acid.

First claim

The invention claimed is:

1. A composition for preparing terephthalic acid; said composition consisting essentially of:
i. p-Toluic acid in an amount of 0.05% to 4% with respect to the total mass of the composition;
ii. at least one catalyst in an amount of 0.02% to 2.5% with respect to the total mass of the composition;
iii. at least one ionic liquid in an amount of 0.04% to 50% with respect to the total mass of the composition;
iv. at least one carboxylic acid solvent; and
v. p-xylene,
said composition when used in the preparation of terephthalic acid, results in the formation of less than 2000 ppm of 4-carboxy-benzaldehyde (4-CBA).

2. The composition as claimed in claim 1 , wherein the proportion of the ionic liquid to the carboxylic acid solvent ranges between 1:1 and 1:20.

3. The composition as claimed in claim 1 , wherein the ionic liquid is at least one selected from the group consisting of alkyl ionic liquids and aryl alkyl ionic liquids.

4. The composition as claimed in claim 1 , wherein the ionic liquid comprises an organic cation selected from the group consisting of quaternary ammonium, cholinium, sulfonium, phosphonium, guanidinium, imidazolium, pyridinium, pyrrolidinium, morpholinium, quinolinium, isoquinolium, pyrazolium and piperidinium; and an anion selected from the group consisting of chloride, bromide, fluoride, iodide, mesylate, tosylate, hydrogen sulfate, sulfate, alkyl sulfonate, phosphates, phosphonates, akyl phosphates, nitrates, nitrites, carbonates, acetates, bicarbonates, hydroxides and oxides.

5. The composition as claimed in claim 1 , wherein the ionic liquid comprises a combination of at least one alkyl ionic liquid and at least one aryl alkyl ionic liquid.

6. The composition as claimed in claim 1 , wherein the catalyst comprises at least one metal compound, the metal being selected from the group consisting of cobalt, magnesium, chromium, copper, nickel, vanadium, iron, molybdenum, tin, cerium, zirconium, cesium and titanium.

7. The composition as claimed in claim 1 , wherein the catalyst is at least one selected from the group consisting of cobalt acetate, manganese acetate, cerium acetate, potassium acetate, cesium acetate, zirconium acetate, copper acetate, cobalt oxalate, manganese oxalate, cerium oxalate, potassium oxalate, cesium oxalate, zirconium oxalate and copper oxalate.

8. The composition as claimed in claim 1 , wherein the carboxylic acid solvent is acetic acid.

9. A process for preparing terephthalic acid; said process consisting essentially of the following steps:
preparing a composition comprising p-Toluic acid in an amount of 0.05% to 4% with respect to the total mass of the composition; at least one catalyst in an amount of 0.02% to 2.5% with respect to the total mass of the composition; at least one ionic liquid in an amount of 0.04% to 50% with respect to the total mass of the composition; at least one carboxylic acid solvent and p-xylene; and
oxidizing said composition in the presence an oxidizing agent selected from the group consisting of oxygen and air, at a temperature of 100 to250° C. and at a pressure of 10 to 60 bar to obtain terephthalic acid,
the content of 4-carboxy-benzaldehyde (4-CBA) being less than 2000 ppm.

Assignees

• Reliance Ind Ltd

Inventors

• Jain Suresh Shantilal
• Aduri Pavankumar
• Uppara Parasu Veera
• TANGADE Prashant Sudhakar

Classifications

• C07C51/265 Primary

  having alkyl side chains which are oxidised to carboxyl groups · CPC title

• C07C63/26

  1,4 - Benzenedicarboxylic acid · CPC title