Catalytic dehydrogenation process

Patent metadata

Field	Value
Publication number	US-9725382-B2
Application number	US-201415034637-A
Country	US
Kind code	B2
Filing date	Oct 14, 2014
Priority date	Nov 12, 2013
Publication date	Aug 8, 2017
Grant date	Aug 8, 2017

Abstract

An improved catalytic dehydrogenation process which process comprises contacting an alkane or alkyl aromatic feedstream with a dehydrogenation catalyst under catalytic conditions in an up-flow fluidized reactor, wherein the fluidized reactor comprises one or more reactors, which catalytic conditions include a temperature within a range of from 500 to 800° C., a weight hourly space velocity within a range of from 0.1 to 1000, a gas residence time within a range of from 0.1 to 10 seconds, and, subsequent to the fluidized reactor, effecting separation of entrained catalyst from reactor effluent by use of a cyclonic separation system, wherein the improvement comprises interposing a cooling means between an up-flow fluidized reactor and the cyclonic separation system to substantially halt thermal reactions, thereby effectively increasing overall molar selectivity to alkene product is provided.

First claim

We claim:

1. An improved catalytic dehydrogenation process which process comprises contacting an alkane or alkyl aromatic feedstream with a dehydrogenation catalyst which comprises gallium and platinum and carried by a alumina or alumina silica support, under catalytic conditions in an up-flow fluidized reactor, wherein the fluidized reactor comprises one or more reactors selected from the group consisting of bubbling bed reactors, turbulent bed reactors, fast fluidized reactors, and riser reactors, which catalytic conditions include a temperature within a range of from 500 to 800° C., a weight hourly space velocity within a range of from 0.1 to 1000, a gas residence time within a range of from 0.1 to 10 seconds, and, subsequent to the fluidized reactor, effecting separation of entrained catalyst from reactor effluent by use of a cyclonic separation system, wherein the improvement comprises cooling the entrained catalyst and the reactor effluent before effecting separation of the entrained catalyst from the reactor effluent, wherein cooling the entrained catalyst and the reactor effluent substantially halts thermal reactions, thereby effectively increasing overall molar selectivity to alkene product.

2. The catalytic dehydrogenation process of claim 1 , wherein the thermal conversion is no more than 20% of the total conversion at reaction temperatures.

3. The catalytic dehydrogenation process of claim 1 , wherein cooling the entrained catalyst and the reactor effluent comprises at least one of (i) passing the entrained catalyst and the reactor effluent through a quench exchanger situated between the fluidized reactor and the cyclonic separation system; and (ii) injecting a cooling medium into a zone between the fluidized reactor and the cyclonic separation system.

4. The catalytic dehydrogenation process of claim 3 , wherein the alkane and/or alkyl aromatic is selected from propane and/or ethylbenzene and the mole ratio of thermal reaction product to catalytic reaction product is greater than 0:1 and less than or equal to 0.1:1.

5. The catalytic dehydrogenation process of claim 1 , wherein cooling the entrained catalyst and the reactor effluent comprises injecting a cooling medium into a zone between a reaction zone of the fluidized reactor and a riser, wherein the cooling medium comprises at least one of steam, liquid water, cold catalyst, liquid hydrocarbon, cooled product gas, fuel, and filler particles.

6. The catalytic dehydrogenation process of claim 1 , wherein the overall selectivity is improved by at least 0.5 mole % compared to a process having equivalent overall conversion but not including cooling the entrained catalyst and the reactor effluent.

7. The catalytic dehydrogenation process of claim 5 , wherein the cooling medium comprises at least one of steam and liquid water.

Assignees

• Dow Global Technologies Llc

Inventors

• Pretz Matthew T
• Stewart Mark W

Classifications

• C07C11/06

  Propene · CPC title

• C07C2521/04

  Alumina · CPC title

• C07C5/3337 Primary

  of the platinum group · CPC title

• C07C2523/62

  with gallium, indium, thallium, germanium, tin or lead · CPC title

• C07C2523/08

  of gallium, indium or thallium · CPC title