Gas separation membrane

Patent metadata

Field	Value
Publication number	US-9724900-B2
Application number	US-201414570990-A
Country	US
Kind code	B2
Filing date	Dec 15, 2014
Priority date	May 1, 2012
Publication date	Aug 8, 2017
Grant date	Aug 8, 2017

Abstract

A method of fabricating a gas separation membrane includes providing a coextruded multilayer film that includes a first polymer layer formed of a first polymer material and a second polymer layer formed of a second polymer material, the first polymer material having a first gas permeability. The coextruded multilayer film is axially oriented such that the second polymer layer has a second gas permeability that is greater than the first gas permeability.

First claim

Having described the invention, the following is claimed:

1. A food packaging membrane comprising:
an axially oriented, coextruded multilayer film that has a flux of at least about 10 GPU, the axially oriented, coextruded multilayer film including at least one axially oriented, coextruded first polymer layer of a first polymer material and at least one axially oriented, coextruded second polymer layer of a second polymer material, the at least one axially oriented, coextruded first polymer layer having a first permeability (P 1 ) prior to axial orientation and a second permeability (P 2 ) after axially orientation less than or equal to the first permeability (P 1 ), the at least one axially oriented, coextruded second polymer layer having a first permeability (P 1a ) prior to axial orientation and a second permeability (P 2a ) after axial orientation that is substantially greater than the first permeability (P 1a ) and the second permeability (P 2 ), the axially oriented, coextruded first polymer layer having a thickness and the combined thicknesses of all the axially oriented, coextruded first polymer layers of the axially oriented, coextruded multilayer film being less than about 1 μm.

2. The food packaging membrane of claim 1 , wherein the axially oriented, coextruded multilayer film having a CO 2 /O 2 selectivity of at least about 4.

3. The food packaging membrane of claim 1 , wherein the axially oriented, coextruded first polymer layers having a CO 2 /O 2 selectivity of at least about 4.

4. The food packaging membrane of claim 1 , wherein the axially oriented, coextruded multilayer film having a flux of at least about 30 GPU.

5. The food packaging membrane of claim 1 , wherein the first polymer material comprises a poly(ether block amide).

6. The food packaging membrane of claim 5 , wherein the first polymer material comprises poly(ether block amide) that includes from about 15% to about 80% of a polyether by molecular weight.

7. The food packaging membrane of claim 1 , wherein the second material comprises polypropylene.

8. The food packaging membrane of claim 7 , wherein the second polymer material further comprises CaCO 3 or a beta-nucleation agent.

9. The food packaging membrane of claim 1 , wherein the axially oriented, coextruded multilayer film comprises a plurality of axially oriented, coextruded alternating first polymer layers and second polymer layers.

10. A method of fabricating a food packaging membrane comprising:
coextruding a first polymer material and a second polymer material to form a multilayer film that includes at least one coextruded first polymer layer and at least one coextruded second polymer layer, the at least one first polymer layer having a first permeability (P 1 ); and
axially orienting the coextruded multilayer film, the at least one axially oriented, coextruded first polymer layer having a second permeability (P 2 ) after axial orientation less than or equal to the first permeability (P 1 ), the at least one axially oriented, coextruded second polymer layer having a first permeability (P 1a ) prior to axial orientation and a second permeability (P 2a ) after axial orientation that is substantially greater than the first permeability (P 1a ) and the second permeability (P 2 ), wherein the axially oriented, coextruded multilayer film has a flux of at least about 10 GPU, the axially oriented, coextruded first polymer layer having a thickness and the combined thicknesses of all the axially oriented, coextruded first polymer layers of the axially oriented, coextruded multilayer film being less than about 1 μm.

11. The method of claim 10 , wherein the multilayer film is axially oriented at a temperature below the melting temperature (T m ) of the second polymer material.

12. The method of claim 10 , wherein the multilayer film is uniaxially stretched.

13. The method of claim 10 , wherein the at least one first polymer layer having a CO 2 /O 2 selectivity of at least about 4 and the axially oriented, coextruded multilayer film having a CO 2 /O 2 selectivity of at least about 4.

14. The method of claim 10 , wherein the first polymer material comprises a poly(ether block amide).

15. The method of claim 14 , wherein the first polymer material comprises poly(ether block amide) that includes from about 15% to about 80% of a polyether by volume.

16. The method of claim 10 , wherein the second polymer material comprises polypropylene.

17. The method of claim 16 , wherein the second polymer material further comprises CaCO 3 or a beta-nucleation agent.

18. The method of claim 10 , wherein the axially oriented, coextruded multilayer film comprises a plurality of axially oriented, coextruded alternating first polymer layers and second polymer layers.

19. The method of claim 10 , wherein the multilayer film is formed in a solventless process.

20. The method of claim 10 , wherein the multilayer film is axially stretched from about 100% to about 400%.

21. The method of claim 10 , further comprising heat treating the multilayer film at a temperature and for a time to increase the gas permeability of the at least one axially oriented, coextruded first polymer layer.

22. The method of claim 21 , wherein axially orienting the at least one first polymer layer causes strain-induced crystallization in the at least one first polymer layer and the heat treating at least partially reversing crystallization in the at least one first polymer layer to increase the gas permeability of the at least one first polymer layer.

Assignees

• Univ Case Western Reserve
• The Univ Of Texas At Austin

Inventors

• Baer Eric
• Armstrong Shannon
• Freeman Benny D
• Paul Donald R
• Offord Grant

Classifications

• B01D71/56

  Polyamides, e.g. polyester-amides · CPC title

• B01D69/148

  Organic/inorganic mixed matrix membranes · CPC title

• B29C48/18

  the components being layers · CPC title

• B29K2023/12

  PP, i.e. polypropylene · CPC title

• B29C48/904

  using dry calibration, i.e. no quenching tank, e.g. with water spray for cooling or lubrication · CPC title