Apparatus for producing trichlorosilane and method for producing trichlorosilane

Patent metadata

Field	Value
Publication number	US-9724665-B2
Application number	US-201213414083-A
Country	US
Kind code	B2
Filing date	Mar 7, 2012
Priority date	Jan 20, 2009
Publication date	Aug 8, 2017
Grant date	Aug 8, 2017

Abstract

An apparatus for producing trichlorosilane in which metallurgical grade silicon powder supplied to a reactor is reacted with hydrogen chloride gas while being fluidized by the hydrogen chloride gas, thereby discharging trichlorosilane generated by the reaction from the reactor, includes: a plurality of gas flow controlling members which are installed along a vertical direction in an annular shape R from an inner peripheral wall of the reactor in an internal space of the reactor; and a heat transfer tube which is installed along the vertical direction in the annular space R and through which a heating medium passes.

First claim

What is claimed is:

1. A method for producing trichlorosilane comprising:
a step of providing an apparatus for producing trichlorosilane comprising:
a reactor;
a raw material supply device that supplies metallurgical grade silicon powder as raw material to the reactor;
a gas introduction device that introduces hydrogen chloride gas to the reactor so that the hydrogen chloride gas reacts with the metallurgical grade silicon powder while the metallurgical grade silicon powder is fluidized by the hydrogen chloride gas;
a gas discharge device that discharges generated gas containing trichlorosilane from the reactor;
a plurality of gas flow controlling members each having on an upper portion an upper diameter-enlarged portion and each having on a lower portion a lower diameter-enlarged portion and each of the plurality of gas flow controlling members being suspended in a central space of the reactor along the vertical direction;
a first member connected to the reactor for suspending the plurality of gas flow controlling members at the upper diameter-enlarged portion;
a second member connected to the reactor for detachably disposing thereon the lower diameter-enlarged portion of the plurality of gas flow controlling members; and
a heat transfer tube which is installed vertically in an annular space enclosing the central space of the reactor and through which a heating medium passes,

a step of introducing metallurgical grade silicon powder to the reactor using the raw material supply device;
a step of introducing hydrogen chloride gas to the reactor from below using the gas introduction device;
a step of passing the heating medium through the heat transfer tube;
a step of reacting the metallurgical grade silicon powder with the hydrogen chloride gas while the metallurgical grade silicon powder is fluidized by the hydrogen chloride gas and the metallurgical grade silicon powder and hydrogen chloride gas flow upward between the gas flow controlling members; and
a step of discharging a reacted fluid containing trichlorosilane and the metallurgical grade silicon from a top part of the reactor into the gas discharge device.

2. The method according to claim 1 , wherein the heating medium accelerates the reaction between the metallurgical grade silicon powder and the hydrogen chloride gas.

3. The method according to claim 1 , wherein the heating medium is dibenzyltoluene.

4. The method according to claim 1 , wherein the heating medium is at a temperature range of −30° C. to 350° C.

5. The method according to claim 1 , wherein the first member is an upper holed guide and the second member is a lower holed guide and an inner diameter of through-holes of the upper holed guide member is smaller than an outer diameter of the upper diameter-enlarged portion of the gas flow controlling member, but is larger than an outer diameter of the lower diameter-enlarged portion, and the inner diameter of the through-holes of the lower holed guide member is smaller than the outer diameter of the lower diameter-enlarged portion of the gas flow controlling member.

6. The method according to claim 1 , wherein the gas flow controlling member is formed by closing both ends of an internal flow tube.

7. The method according to claim 1 , wherein in the step of passing the heating medium through the heat transfer tube, a temperature of a lower part of the reactor is measured by a thermometer set at a lower part of the reactor in order to control a temperature of the heat medium passing through the heat transfer tube.

Assignees

• Narukawa Mitsutoshi
• Mitsubishi Materials Corp

Inventors

• Narukawa Mitsutoshi

Classifications

• B01J8/1872

  Details of the fluidised bed reactor (B01J8/1836 takes precedence) · CPC title

• B01J2208/00061

  of the reactants · CPC title

• B01J8/0055

  using cyclones · CPC title

• B01J2208/00132

  Tubes · CPC title

• B01J2208/0084

  inside the bed, e.g. baffles · CPC title