Liquid electrolyte for batteries, method for producing the same, and battery comprising the same

Patent metadata

Field	Value
Publication number	US-9722288-B2
Application number	US-201214241224-A
Country	US
Kind code	B2
Filing date	Aug 28, 2012
Priority date	Aug 30, 2011
Publication date	Aug 1, 2017
Grant date	Aug 1, 2017

Abstract

An object of the present invention is to provide a liquid electrolyte for batteries, which has excellent ion conductivity, a method for producing the liquid electrolyte and a battery including the liquid electrolyte. Disclosed is a liquid electrolyte for batteries, comprising a mesoionic compound represented by the following general formula (1):

wherein R1 and R2 are each independently an alkyl group having 1 to 3 carbon atoms.

First claim

The invention claimed is:

1. A liquid electrolyte for batteries, comprising a mesoionic compound represented by the following general formula (1) and a lithium salt at a concentration of 0.5 to 1.4 mol/kg:

wherein R 1 and R 2 are each independently an alkyl group having 1 to 3 carbon atoms, and
wherein a molar ratio between a lithium ion of the lithium salt and mesoionic compound molecules (lithium ion: mesoionic compound molecules) in the liquid electrolyte is from 1:12.5 to 1:5.2.

2. The liquid electrolyte according to claim 1 , being a liquid electrolyte for lithium-air batteries.

3. A battery comprising at least a cathode, an anode and an electrolyte, the electrolyte being present between the cathode and anode,
wherein at least one of the cathode, the anode and the electrolyte comprises the liquid electrolyte defined by claim 1 .

4. A method for producing a liquid electrolyte for batteries, comprising the steps of:
preparing a lithium salt and a mesoionic compound represented by the following general formula (1):

wherein R 1 and R 2 are each independently an alkyl group having 1 to 3 carbon atoms, and
preparing a liquid electrolyte having a water concentration of 200 ppm or less, a lithium salt concentration of 0.5 to 1.4 mol/kg, and a molar ratio between a lithium ion of the lithium salt and mesoionic compound molecules (lithium ion: mesoionic compound molecules) of from 1:12.5 to 1:5.2, by mixing at least the lithium salt and the mesoionic compound.

5. The method according to claim 4 , being a method for producing a liquid electrolyte for lithium-air batteries.

6. The method according to claim 4 , wherein the mesoionic compound is synthesized under a basic condition.

7. The liquid electrolyte according to claim 1 , wherein a lithium ion conductivity at 60° C. obtained by the following Equation (f) is 0.69 to 0.81 mS/cm:
lithium ion conductivity=ion conductivity×lithium ion transport number (t Li ),  Equation (f)

wherein the lithium ion transport number (t Li ) is determined by the following Equation (d):
t Li =D Li /( D Li +D F ),  Equation (d)

wherein the diffusion coefficients D Li and D F are each calculated via NMR by the following Equation (c):

E
=

S

S
0

=

exp
⁡

(

-

γ
2

⁢

g
2

⁢

δ
2

⁢

D
⁡

(

Δ
-

δ
3

)

)

,

Equation
⁢

⁢

(
c
)

wherein
E is the peak intensity ratio,
S is the peak intensity,
S 0 is the peak intensity measured when there is no magnetic field gradient,
γ is the gyromagnetic ratio of nuclear spin,
g is the magnetic field gradient intensity,
δ is the magnetic field gradient irradiation time,
D is the diffusion coefficient D Li or D F , and
Δ is the time interval between magnetic field irradiations.

Assignees

• Hirashita Tsunehisa
• Araki Shuki
• Kagami Katsuyuki
• Nakamoto Hirofumi
• Shiotsuki Taishi
• Nagoya Inst Technology
• Toyota Motor Co Ltd

Inventors

• Hirashita Tsunehisa
• Araki Shuki
• Kagami Katsuyuki
• Nakamoto Hirofumi
• Shiotsuki Taishi

Classifications

• Y02E60/10

  Energy storage using batteries · CPC title

• H01M12/08 Primary

  composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type · CPC title

• Y02E60/128

  Cross-Sectional Technologies · mapped topic

• H01M12/06

  with one metallic and one gaseous electrode · CPC title

• H01M10/0567

  characterised by the additives · CPC title