Graphene-nanomaterial composite, electrode and electric device including the same, and method of manufacturing the graphene-nanomaterial composite

Patent metadata

Field	Value
Publication number	US-9721734-B2
Application number	US-201414186052-A
Country	US
Kind code	B2
Filing date	Feb 21, 2014
Priority date	Feb 22, 2013
Publication date	Aug 1, 2017
Grant date	Aug 1, 2017

Abstract

A graphene-nanomaterial composite, an electrode and an electric device including the graphene-nanomaterial composite and a method of manufacturing the graphene-nanomaterial composite include a graphene stacked structure including a plurality of graphene films stacked on one another; and a nanomaterial between the plurality of graphene films and bonded to at least one of the plurality of graphene films by a chemical bond.

First claim

What is claimed is:

1. A graphene-nanomaterial composite, comprising:
a graphene stacked structure including a plurality of graphene films stacked on one another in a planar form; and
a nanomaterial between the plurality of graphene films and bonded to at least one of the plurality of graphene films by a chemical bond,
wherein the chemical bond is a covalent bond or an ionic bond, and
wherein the covalent bond includes at least one selected from an ether group, a carbonate anhydride group; and an acid anhydride group.

2. The graphene-nanomaterial composite of claim 1 , wherein the ionic bond includes at least one selected from a carboxylic acid ion, an ammonium ion, and an acyl cation group.

3. The graphene-nanomaterial composite of claim 1 , wherein an average thickness of the plurality of graphene films is about 100 nm or less.

4. The graphene-nanomaterial composite of claim 1 , wherein the plurality of graphene films are porous.

5. The graphene-nanomaterial composite of claim 1 , wherein the nanomaterial is shaped in the form of a particle, a tube, a wire, a rod, a fiber, an arbitrary bulk, or a combined shape thereof.

6. The graphene-nanomaterial composite of claim 1 , wherein an average diameter of the nanomaterial is in a range of about 1 nm to about 200 nm.

7. The graphene-nanomaterial composite of claim 1 , wherein the nanomaterial is at least one selected from a carbon-based nanomaterial, a metal-based nanomaterial, a metal compound-based nanomaterial, a polymer-based nanomaterial, and a combination thereof.

8. The graphene-nanomaterial composite of claim 7 , wherein the carbon-based nanomaterial includes at least one selected from carbon nanotubes, carbon nanoparticles, carbon nanowires, carbon nanofibers, fullerene, graphite, activated carbon, soft carbon including carbon calcined at a low temperature, hard carbon including carbon calcined at a high temperature, pitch carbide, mesophase pitch carbide, and calcined cokes.

9. The graphene-nanomaterial composite of claim 7 , wherein the metal-based nanomaterial includes at least one selected from lithium, sodium, potassium, rubidium, cesium, iridium, nickel, manganese, vanadium, titanium, chromium, silver, molybdenum, tungsten, gold, iron, lead, tin, copper, strontium, zirconium, magnesium, barium, an alloy thereof and a mixture thereof.

10. The graphene-nanomaterial composite of claim 7 , wherein the metal compound-based nanomaterial includes at least one selected from a metal oxide, a metal nitride, a metal sulfide, a metal carbide, and a metal halide.

11. The graphene-nanomaterial composite of claim 7 , wherein the polymer-based nanomaterial includes at least one selected from polystyrene, polyimide, polyamide, polyvinyl pyrrolidone, polyvinyl, polyvinyl alcohol, polyethyleneoxide, polyurethane, polymethyl methacrylate, and polypropylene.

12. The graphene-nanomaterial composite of claim 7 , wherein a content of the nanomaterial is in a range of about 1 wt % to about 50 wt % based on a total weight of the nanomaterial and one of the plurality of graphene films.

13. The graphene-nanomaterial composite of claim 1 , wherein a thickness of the graphene-nanomaterial composite is in a range of about 10 nm to about 1000 μm.

14. The graphene-nanomaterial composite of claim 1 , wherein a density of the graphene-nanomaterial composite is in a range of about 0.1 g/cc to about 10.0 g/cc.

15. An electrode, comprising:
a current collector; and
the graphene-nanomaterial composite according to claim 1 on the current collector.

16. An electric device, comprising:
the electrode according to claim 15 .

17. The electric device of claim 16 , wherein the electric device is me selected from the group consisting of a supercapacitor, a secondary battery, a fuel cell, and a solar cell.

18. A graphene-nanomaterial composite, comprising:
a first graphene layer over a second graphene layer in a planar form; and
a nanomaterial between the first and second graphene layers,
wherein the nanomaterial is attached to at least one of the first and second graphene layers via a chemical moiety,
wherein the chemical moiety is a covalent moiety or an ionic moiety, and
wherein the covalent moiety includes at least one selected from a carbonate anhydride group; and an acid anhydride group.

19. The graphene-nanomaterial composite of claim 18 , wherein the nanomaterial is attached to a surface of the at least one of the first and second graphene layers via the chemical moiety.

20. The graphene-nanomaterial composite of claim 18 , wherein the nanomaterial is attached to a surface of the first graphene layer via a first chemical moiety and a surface of the second graphene layer via a second chemical moiety.

21. The graphene-nanomaterial composite of claim 18 , wherein the chemical moiety is a part of a functional group.

22. The graphene-nanomaterial composite of claim 18 , wherein the first and second graphene layers each have electrolyte-permeable pores.

Assignees

• Samsung Electronics Co Ltd
• Corning Prec Materials Co Ltd

Inventors

• Ryu Chong-Joon
• Jung Nae-Young
• Kwon Soon-Geun
• Choi Jae-Young

Classifications

• H01M4/96

  Carbon-based electrodes · CPC title

• H01M4/583

  Carbonaceous material, e.g. graphite-intercalation compounds or CFx · CPC title

• B32B9/04

  comprising such {particular} substance as the main or only constituent of a layer, {which is} next to another layer of {the same or of} a {different material (next to a glass layer B32B17/06; layered products with at least two ceramic layers composed mainly of ceramic B32B18/00)} · CPC title

• H01M4/366

  as layered products · CPC title

• C01B31/0484

  Chemistry & Metallurgy · mapped topic