Thermoplastic molding composition

Patent metadata

Field	Value
Publication number	US-9721695-B2
Application number	US-201113332424-A
Country	US
Kind code	B2
Filing date	Dec 21, 2011
Priority date	Dec 21, 2010
Publication date	Aug 1, 2017
Grant date	Aug 1, 2017

Abstract

The thermoplastic molding composition comprises, based on the thermoplastic molding composition,
a) at least one polyamide, copolyamide or a polyamide-comprising polymer blend as component A, b) from 0.1 to 10% by weight of carbon nanotubes, graphenes or mixtures thereof as component B, c) from 0.1 to 3% by weight of ionic liquids as component C,

wherein the thermoplastic molding composition does not comprise any polyamide-12 units.

First claim

The invention claimed is:

1. A thermoplastic molding composition consisting of:
a) at least one polyamide or copolyamide as component A,
b) from 0.5 to 4% by weight of carbon nanotubes having a diameter in the range of 4 to 20 nm and a specific surface area, determined by the BET method, in the range from 50 to 2000 m 2 /g, graphenes or mixtures thereof as component B,
c) from 0.3 to 1.2% by weight of ionic liquids as component C,
wherein percentages are based on the thermoplastic molding composition, the thermoplastic molding composition does not have any polyamide-12 units, and
wherein the polyamide or copolyamide is prepared by reaction of starting monomers consisting of monomers selected from the group consisting of dicarboxylic acids and diamines or salts of the dicarboxylic acids and diamines, amino-carboxylic acids, aminonitriles, lactams, and mixtures thereof;

wherein component A is selected from the group consisting of polyamide 6, polyamide 66, and MXD6-polyamide.

2. The thermoplastic molding composition according to claim 1 , wherein the ionic liquid having a cation selected from the group consisting of:
quaternary ammonium cations,
phosphonium cations,
imidazolium cations,
H-pyrazolium cations,
pyridazinium ions,
pyrimidinium ions,
pyrazinium ions,
pyrrolidinium cations,
guanidinium cations,
5- to at least 6-membered cations comprising at least one phosphorus or sulfur atom,
1,8-diazabicyclo[5.4.0]undec-7-enium cation,
1,8-diazabicyclo[4.3.0]non-5-inium cation, and
oligomers and polymers comprising these cations.

3. The thermoplastic molding composition according to claim 1 , wherein the ionic liquid having an anion selected from the group consisting of halide, optionally substituted C 1-4 -carboxylate, phosphate, C 1-4 -alkylphosphate, di-C 1-4 -alkylphosphate, C 1-4 -alkylsulfate, C 1-4 -alkylsulfonate, hydrogensulfate, triflimide, tetrafluoroborate, triflate and mixtures thereof.

4. The thermoplastic molding composition according to claim 1 , wherein the carbon nanotubes have a diameter in the range of 5 to 10 nm.

5. The thermoplastic molding composition according to claim 1 , wherein the carbon nanotubes have a specific surface area, determined by the BET method, in the range from 200 to 1200 m 2 /g.

6. The thermoplastic molding composition according to claim 1 , wherein the carbon nanotubes are multiwalled nanotubes in which a plurality of graphite tubes are nested within one another.

7. A molding comprising the thermoplastic molding composition according to claim 1 .

8. A process for producing thermoplastic molding compositions according to claim 1 , comprising introducing components B and C into component A in a corotating twin-screw extruder.

9. The process according to claim 8 , wherein extrusion is carried out at a temperature in the range from 170 to 350° C.

Assignees

• Gibon Cecile
• Yang Xin
• Kujat Christof
• Weber Martin
• Szarvas Laszlo
• Klein Daniel
• Poetschke Petra
• Krause Beate
• Basf Se

Inventors

• Gibon Cecile
• Yang Xin
• Kujat Christof
• Weber Martin
• Szarvas Laszlo
• Klein Daniel
• Poetschke Petra
• Krause Beate

Classifications

• H01B1/24 Primary

  the conductive material comprising carbon-silicon compounds, carbon or silicon · CPC title

• B82Y30/00

  Nanotechnology for materials or surface science, e.g. nanocomposites · CPC title