Multilayered articles with low optical retardation

Patent metadata

Field	Value
Publication number	US-9720155-B2
Application number	US-201515124882-A
Country	US
Kind code	B2
Filing date	May 1, 2015
Priority date	May 2, 2014
Publication date	Aug 1, 2017
Grant date	Aug 1, 2017

Abstract

A coextruded multilayered thermoplastic article including: a first layer with a first surface texture, wherein the first layer comprises a first transparent thermoplastic polymer having a first stress optical coefficient (C m1 ) measured at 20° C. above the glass transition temperature of the first polymer; a second layer located comprising a second transparent thermoplastic polymer having a second stress optical coefficient (C m2 ) measured at 20° C. above the glass transition temperature of the second matrix; wherein a relation between the first stress optical coefficient and the second stress optical coefficient is C m2 >4(C m1 ) (Formula A) wherein the thickness of the first layer measured from the highest peaks of the first surface texture to the second side of the first layer is greater than 1.5 times Rz of the first surface texture but less than or equal to 75% of the total thickness of the article.

First claim

The invention claimed is:

1. A coextruded multilayered thermoplastic article, comprising:
a first layer with a first side and a second side and with a first surface texture on the first side, wherein the first layer comprises a first transparent thermoplastic polymer having a first stress optical coefficient (C m1 ) measured at 20° C. above the glass transition temperature of the first polymer;
a second layer located adjacent the second side and comprising a second transparent thermoplastic polymer having a second stress optical coefficient (C m2 ) measured at 20° C. above the glass transition temperature of the second matrix;
wherein a relation between the first stress optical coefficient and the second stress optical coefficient is Formula (A)
C m2 >4( C m1 )  (Formula A)

wherein the thickness of the first layer measured from the highest peaks of the first surface texture to the second side of the first layer is greater than 1.5 times Rz of the first surface texture but less than or equal to 75% of the total thickness of the article;
wherein the second layer has a second layer thickness that is greater than or equal to 25% of the total thickness of the article; and
wherein the optical retardation of the article is less than or equal to 150 nm.

2. The coextruded multilayer article of claim 1 , wherein Rz of the first surface texture is greater or equal to 5 micrometers.

3. The coextruded multilayered article of claim 1 , wherein the first transparent thermoplastic polymer is selected from a polymer of methyl methacrylate (PMMA) with or without comonomers, cyclic olefin copolymers; polyester copolymers with inherent low birefringence, or a blend of a styrene acrylonitrile copolymer and a PMMA with or without comonomers, or a combination comprising at least one of the foregoing.

4. The coextruded multilayered article of claim 1 , wherein the second transparent thermoplastic polymer is selected from polycarbonates, polyester copolymers, a blend of polycarbonates and polyester copolymers, or a combination comprising at least one of the foregoing.

5. The coextruded multilayered article of claim 4 , wherein the second polymer comprises Bisphenol-A polycarbonate, copolymers of Bisphenol-A polycarbonate, or a combination comprising at least one of the foregoing.

6. The coextruded multilayered article of claim 1 , further comprising a third layer that comprises a third transparent thermoplastic polymer having a third stress optical coefficient (C m3 ) measured at 20° C. above the glass transition temperature of the third matrix;
wherein the second layer is located between the first layer and the third layer;
wherein a relation between the third stress optical coefficient and the second stress optical coefficient is Formula (B)
C m2 >4( C m3 )  (Formula B).

7. The coextruded multilayered article of claim 6 , wherein the third layer comprises a second surface texture on an outermost side that is away from the second layer.

8. The coextruded multilayered article of claim 1 , wherein the total optical retardation of the article is less than or equal to 80 nm.

9. The coextruded multilayered article of claim 1 , wherein the total optical retardation of the article is less than or equal to 20 nm.

10. The coextruded multilayered article of claim 1 , wherein the first surface texture comprises protruded additive particles at least partially embedded the first layer.

11. The coextruded multilayered article of claim 1 , comprising an optical haze of greater than or equal to 30% as measured according to ASTM D1003-00, Procedure A, with D65 illuminant and 10 degree observer angle, on a 1 mm thick sample.

12. The coextruded multilayered article of claim 1 , wherein the surface on the first side of the first layer is an outermost surface of the article.

13. The coextruded multilayered article of claim 1 , comprising no layers adjacent to the first surface of the first layer.

14. The coextruded multilayered article of claim 1 , comprising no non-thermoplastic layer.

15. The coextruded multilayered article of claim 1 , wherein the first surface texture comprises a plurality of microstructures comprising at least one of microlenses, prisms, lenticular, or randomized peaks and valleys, and combinations comprising at least one of the foregoing.

16. The coextruded multilayered article of claim 15 , wherein the average aspect ratio of the microstructure is greater than 0.05.

17. The coextruded multilayered article of claim 1 , wherein the first surface texture has average roughness Ra of less than or equal to 1.2 micrometers, and wherein the optical retardation of the article is less than or equal to 15 nm.

18. A multilayer reflective polarizer comprising a reflective polarizing film as core film and a multilayered film of claim 1 adjacent to the core film.

19. A method of forming the coextruded multilayered article of claim 1 , comprising:
coextruding the first and the second layer;
cooling the layers between two calendering rollers;
wherein at least one of the rollers comprises a textured surface to impart a surface texture to at least the first layer.

20. The method of claim 19 , wherein the calendering rolls are two rollers with no compliant outer surface.

Assignees

• Sabic Global Technologies Bv
• Sabic Global Tech

Inventors

• Zhou Jian
• Bastawros Adel
• Feng Wei
• Wang Zhi
• Zhou Yuan

Classifications

• B29C47/065

  Operations & Transport · mapped topic

• B29L2011/0066

  Optical filters · CPC title

• B32B27/365

  comprising polycarbonates · CPC title

• B32B27/325

  comprising polycycloolefins · CPC title

• G02F1/133504

  Diffusing, scattering, diffracting elements (associated to illuminating devices G02F1/133606) · CPC title