Gas sensor element and gas sensor

Patent metadata

Field	Value
Publication number	US-9719957-B2
Application number	US-201414146999-A
Country	US
Kind code	B2
Filing date	Jan 3, 2014
Priority date	Jan 8, 2013
Publication date	Aug 1, 2017
Grant date	Aug 1, 2017

Abstract

A first electrode ( 133 ) has an exposure portion ( 133 b ) exposed to a second measuring chamber ( 160 ), and a connection portion ( 133 d ) which is disposed at a position not exposed to the second measuring chamber ( 160 ) and is connected to the first lead ( 137 ) and which is a portion of the first electrode ( 133 ) located most distant from the second measuring chamber ( 160 ). The entire connection portion ( 133 d ) is located in a region A 1 which extends from the second measuring chamber ( 160 ) over a distance of 1.0 mm or less.

First claim

The invention claimed is:

1. A gas sensor element comprising:
a plate-like first solid electrolyte body having oxygen ion conductivity;
an oxygen-permeable first electrode provided on a front or back surface of the first solid electrolyte body;
an oxygen-impermeable first lead connected to the first electrode;
an oxygen-permeable second electrode provided on the front or back surface of the first solid electrolyte body; and
a first measuring chamber which is disposed in opposition to the first electrode and into which gas to be measured is introduced; and
configured such that oxygen ions stemming from NOx contained in the gas-to-be-measured introduced into the first measuring chamber move from the first measuring chamber to a destination located externally of the measuring chamber through the first solid electrolyte body, whereby a current corresponding to the concentration of oxygen stemming from the NOx flows between the first electrode and the second electrode; wherein
the first electrode has an exposure portion exposed to the first measuring chamber, and a connection portion which is disposed at a position not exposed to the first measuring chamber and is connected to the first lead and which is a portion of the first electrode located most distant from the first measuring chamber, and
the entire connection portion is located in a region which extends from the first measuring chamber over a distance of 1.0 mm or less.

2. A gas sensor element as claimed in claim 1 , further comprising a reference oxygen chamber disposed in opposition to the second electrode, wherein the destination located externally of the first measuring chamber is the reference oxygen chamber.

3. A gas sensor element as claimed in claim 1 , further comprising an insulation layer formed on the front or back surface of the first solid electrolyte body, wherein
the first lead and a portion of the first electrode are formed on the insulation layer;
the exposure portion of the first electrode includes a contact portion which is in contact with the solid electrolyte body through a through hole extending through the insulation layer; and
the connection portion of the first electrode is connected to the first lead on the insulation layer.

4. A gas sensor element comprising:
a plate-like first solid electrolyte body having oxygen ion conductivity;
an oxygen-permeable first electrode provided on a front or back surface of the first solid electrolyte body;
an oxygen-impermeable first lead connected to the first electrode;
an oxygen-permeable second electrode provided on the front or back surface of the first solid electrolyte body; and
a first measuring chamber which is disposed in opposition to the first electrode and into which gas to be measured is introduced; and
configured such that oxygen ions stemming from NOx contained in the gas-to-be-measured introduced into the first measuring chamber move from the first measuring chamber to a destination located externally of the first measuring chamber through the first solid electrolyte body, whereby a current corresponding to the concentration of oxygen stemming from the NOx flows between the first electrode and the second electrode; wherein
the first electrode is disposed within the first measuring chamber;
the gas sensor element further comprises an insulation layer formed on the front or back surface of the first solid electrolyte body;
the first lead and a portion of the first electrode are formed on the insulation layer;
the first electrode has a contact portion which is in contact with the first solid electrolyte body through a through hole extending through the insulation layer, and a connection portion connected to the first lead on the insulation layer within the measuring chamber;
the first electrode is directly provided on the first solid electrolyte body;
the first lead is electrically connected to the first electrode;
the second electrode is directly provided on the first solid electrolyte body; and
the first lead and the first electrode are both provided on the same surface.

5. A gas sensor element as claimed in claim 4 , further comprising a reference oxygen chamber disposed in opposition to the second electrode, wherein the destination located externally of the first measuring chamber is the reference oxygen chamber.

6. A gas sensor comprising a gas sensor element as claimed in claim 1 .

7. A gas sensor comprising a gas sensor element as claimed in claim 4 .

8. A gas sensor element as claimed in claim 1 , further comprising a second measuring chamber and an oxygen pumping cell, the oxygen pumping cell is arranged above and on a side of the first measuring chamber that is opposite the first solid electrolyte body, the oxygen pumping cell is constituted by a second solid electrolyte body and third and fourth electrodes arranged on opposite surfaces of the second solid electrolyte body, the second measuring chamber is arranged below the first measuring chamber, one of said third and fourth electrodes is exposed to the second measuring chamber, and a part of the first measuring chamber is contiguous with the first solid electrolyte body having thereon the first and second electrodes.

9. A gas sensor element as claimed in claim 4 , further comprising a second measuring chamber and an oxygen pumping cell, the oxygen pumping cell is arranged above and on a side of the first measuring chamber that is opposite the first solid electrolyte body, the oxygen pumping cell is constituted by a second solid electrolyte body and third and fourth electrodes arranged on opposite surfaces of the second solid electrolyte body, the second measuring chamber is arranged below the first measuring chamber, one of said third and fourth electrodes is exposed to the second measuring chamber, and a part of the first measuring chamber is contiguous with the first solid electrolyte body having thereon the first and second electrodes.

Assignees

• Ngk Spark Plug Co

Inventors

• Kamada Kentaro
• Nakagawa Masaki
• Shiotani Koji

Classifications

• G01N27/4072

  characterized by the diffusion barrier · CPC title

• G01N27/4071 Primary

  using sensor elements of laminated structure · CPC title

• G01N27/4078

  Means for sealing the sensor element in a housing · CPC title

• G01N33/0037

  NOx · CPC title

• G01N27/4077

  Means for protecting the electrolyte or the electrodes · CPC title