Continuous method for the precipitation of lignin from black liquor

Patent metadata

Field	Value
Publication number	US-9719210-B2
Application number	US-201514825363-A
Country	US
Kind code	B2
Filing date	Aug 13, 2015
Priority date	Oct 15, 2010
Publication date	Aug 1, 2017
Grant date	Aug 1, 2017

Abstract

In a method for the continuous precipitation of lignin from black liquor black liquor is provided so as to flow as a pressurized flow in a reactor with a dwell time of less than 300 s. An acidifying agent selected from the group of carbon dioxide, acid and their combinations is led to the flow at one or more feeding sites to lower the pH of black liquor. The pH is allowed to decrease by the effect of the acidifying agent in the pressurized flow to the precipitation point of lignin, the pressure of the pressurized flow is abruptly released, and lignin particles are separated from black liquor.

First claim

The invention claimed is:

1. An apparatus for the continuous precipitation of lignin from black liquor, the apparatus comprising:
a flow-through reactor and a feeding device leading an acidifying agent into the reactor, wherein the flow-through reactor is a continuous flow-through reactor that includes a pressurized portion wherein black liquor is arranged to flow as a pressurized flow, the pressurized portion includes one or more acidifying agent feeding sites that are connected to a source of acidifying agent to lead the acidifying agent to the pressurized flow at said one or more acidifying agent feeding sites, and the pressurized portion ends at a pressure release valve that is configured to cause an abrupt release of pressure of the pressurized flow such that the black liquor is intensively mixed upon release of the pressure.

2. The apparatus according to claim 1 , wherein, disposed after the one or more acidifying agent feeding sites, there is a static mixer that is arranged to provide turbulent mixing of the flow.

3. The apparatus according to claim 1 , wherein the acidifying agent and/or a secondary flow separated from the pressurized flow are arranged to be led to the pressurized flow at the feeding site at such a pressure as to provide turbulent mixing of the flow.

4. The apparatus according to claim 1 , wherein the apparatus comprises a filter that is arranged to separate lignin particles from black liquor.

5. The apparatus according to claim 4 , wherein the filter is a pressure filter.

6. The apparatus according to claim 4 wherein, before the filter, there is a concentration device that is arranged to raise the proportion of lignin particles in the black liquor.

7. The apparatus according to claim 1 , wherein the apparatus comprises a cooling device for cooling the black liquor containing lignin, and the cooling device is disposed after the pressure release valve.

8. The apparatus according to claim 7 , wherein the employed cooling device is a heat exchanger.

9. The apparatus of claim 6 , wherein the concentration device is a centrifuge.

10. The apparatus of claim 1 , wherein the flow-through reactor includes a plurality of tubes to facilitate flow of the black liquor through the flow-through reactor, a diameter of a first tube after the pressure release valve being larger than a diameter of a second tube before the pressure release valve.

11. The apparatus of claim 1 , wherein the reactor is configured to facilitate volumetric flow of the black liquor therethrough such that a dwell time of about 1 second to about 300 seconds may be achieved.

12. The apparatus of claim 11 , wherein the dwell time is from about 10 seconds to about 100 seconds.

Assignees

• Upm Kymmene Corp

Inventors

• Miettinen Mauno

Classifications

• D21C11/0007 Primary

  Recovery of by-products, i.e. compounds other than those necessary for pulping, for multiple uses or not otherwise provided for (volatile compounds obtained by decomposition of spent liquors in order to regenerate them D21C11/125; compounds obtained by fractionating the liquors in order to regenerate them D21C11/0042) · CPC title

• D21C11/10 Primary

  Concentrating spent liquor by evaporation (evaporators B01D) · CPC title

• B01J3/02

  Feed or outlet devices therefor · CPC title

• C07G1/00

  Low-molecular-weight derivatives of lignin (high-molecular-weight derivatives of lignin {C08H6/00}) · CPC title

• B01J3/00

  Processes of utilising sub-atmospheric or super-atmospheric pressure to effect chemical or physical change of matter; Apparatus therefor (pressure vessels for containing or storing compressed, liquefied or solidified gases F17C) · CPC title