Fragrant oil encapsulation

Patent metadata

Field	Value
Publication number	US-9719058-B2
Application number	US-201314416212-A
Country	US
Kind code	B2
Filing date	Jul 25, 2013
Priority date	Jul 26, 2012
Publication date	Aug 1, 2017
Grant date	Aug 1, 2017

Abstract

The invention relates to microcapsules having a particle size distribution that has at least two maxima, wherein the main maximum of the particle size lies in the range of 5 to 100 μm and wherein the volume assumed by the microcapsules that have a particle size less than ¼ of the particle size of the main maximum is greater than approximately 20% of the total volume of the microcapsules.

First claim

The invention claimed is:

1. Microcapsules with a particle size distribution which has at least two maxima, wherein the main maximum of the particle size distribution lies in the range of 10 to 50 μm, and a secondary maximum of the particle size distribution lies in the range of 1 to 6 μm, and wherein the volume occupied by the microcapsules which have a particle size ≦¼ of the particle size of the main maximum is ≧approximately 20% of the total volume of the microcapsules.

2. Microcapsules according to claim 1 , wherein the volume occupied by the microcapsules which have a particle size of ≦¼ the particle size of the main maximum is ≧approximately 22% of the total volume of the microcapsules.

3. Microcapsules according to claim 1 , wherein the volume occupied by the microcapsules which have a particle size of ≦6 micrometers is ≧approximately 20% of the total volume of the microcapsules.

4. Microcapsules according to, wherein the microcapsules have a capsule wall made of an aminoplast.

5. Microcapsules according to, wherein the microcapsules have a capsule wall made of a methylated melamine-formaldehyde resin and/or urea-formaldehyde resin and/or reaction products of aldehydes with thiourea, N-alkylurea, guanidine, acetoguanamine, benzoguanamine, capronoguanamine, cyanamine, dicyandiamide and/or alkyl-/arylsulphonamide.

6. Microcapsules according to claim 1 , wherein the microcapsules have a core material made of at least one substantially water-insoluble material.

7. Microcapsules according to claim 1 , wherein the microcapsules have a core material which comprises a hydrophobic fragrant oil, a pesticide, a biocide, an insecticide, a substance from the group of repellents, a cosmetic active substance, a dye or mixtures of dyes, fluorescent colours, optical brighteners, solvents, waxes, silicone oils, lubricants, monomers for polymerisations or polycondensations, reactive synthetic materials, for example adhesives for single or multiple components, paint ingredients, flame retardants, pigment dispersions in organic solvents, aromatic substances and/or agrochemicals.

8. Microcapsules according to claim 1 , wherein the microcapsules have a weight ratio of core material to capsule wall material which is approximately 50-90 to 50-10.

9. A suspension of microcapsules according to claim 1 in a liquid.

10. The suspension of microcapsules according to claim 9 , wherein the proportion by weight of the microcapsules is approximately 20 to 60% by weight.

11. The suspension according to claim 9 , wherein the suspension has a viscosity in the range from 12 to 1500 mPas.

12. A product comprising microcapsules according to claim 1 .

13. A product comprising microcapsules obtained from the suspension of microcapsules according to claim 9 with prior removal of the liquid therefrom.

14. The microcapsules according to claim 1 , wherein the volume occupied by the microcapsules which have a particle size of ≦¼ of the particle size of the main maximum is approximately ≧25% of the total volume of the microcapsules.

15. The microcapsules according to claim 1 , wherein the main maximum of the particle size distribution is 10 μm to 50 μm and a secondary maximum of the particle size distribution is 1.5 μm to 4 μm.

16. The microcapsules according to claim 1 , wherein the main maximum of the particle size distribution is 10.mu.m to 50.mu.m and a secondary maximum of the particle size distribution is 2.mu.m to 3.5.mu.m.

17. The microcapsules according to claim 1 , wherein the main maximum of the particle size distribution is 15 μm to 40 μm and a secondary maximum of the particle size distribution is 1 μm to 6 μm.

18. The microcapsules according to claim 1 , wherein the main maximum of the particle size distribution is 15 μm to 40 μm and a secondary maximum of the particle size distribution is 1.5 μm to 4 μm.

19. The microcapsules according to claim 1 , wherein the main maximum of the particle size distribution is 15 μm to 40 μm and a secondary maximum of the particle size distribution is 2 μm to 3.5 μm.

20. The microcapsules according to claim 1 , wherein the volume occupied by the microcapsules which have a particle size of ≦6 micrometers is ≧approximately 22% of the total volume of the microcapsules.

21. The microcapsules according to claim 1 , wherein the microcapsules have a weight ratio of core material to capsule wall material which is approximately 70-80 to 30-20.

22. The suspension of microcapsules according to claim 9 , wherein the proportion by weight of the microcapsules is approximately 25 to 50% by weight.

23. The suspension of microcapsules according to claim 9 , wherein the proportion by weight of the microcapsules is approximately 30 to 35% by weight.

24. The product of claim 12 , wherein the product is selected from the group consisting of liquid laundry detergent, fabric softeners, cleaning agents, washing powders, shower gels, shampoos, deodorants and body lotions.

25. The product of claim 13 , wherein the product is selected from the group consisting of liquid laundry detergent, fabric softeners, cleaning agents, washing powders, shower gels, shampoos, deodorants and body lotions.

Assignees

• Koehler August Papierfab
• Symrise Ag
• Koehler Se August Papierfabrik

Inventors

• Bertram Ralf
• Ott Patrick
• Kühne Lutz
• Meier Claudia
• Schroeder Julien
• Mahler Stephan
• Jurisch Claus

Classifications

• C09B67/0097

  Dye preparations of special physical nature; Tablets, films, extrusion, microcapsules, sheets, pads, bags with dyes · CPC title

• A61Q19/00

  Preparations for care of the skin · CPC title

• A61Q19/10

  Washing or bathing preparations · CPC title

• A61Q15/00

  Anti-perspirants or body deodorants (deodorisation of air A61L9/00) · CPC title

• B01J13/08

  Simple coacervation, i.e. addition of highly hydrophilic material {(combined with spraying B01J13/043; combined with mechanical division B01J13/04)} · CPC title